八面体配合物中Ni<sup>2+</sup>离子的光谱性质

BRIK Mikhail G; KURBONIYON Mekhrdod S; 马崇庚

doi:10.37188/CJL.20220243

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八面体配合物中Ni²⁺离子的光谱性质

特邀报告 | 更新时间：2023-02-13

- 八面体配合物中Ni²⁺离子的光谱性质
  增强出版
- Spectroscopic Properties of Ni²⁺Ions in Octahedral Complexes
- 发光学报 2022年43卷第9期页码：1459-1467
- 作者机构：
  
  1.重庆邮电大学光电工程学院 & “重庆邮电大学⁃伦敦布鲁内尔大学”交叉创新研究院，重庆　400065
  2.塔尔图大学物理研究所，爱沙尼亚塔尔图　50411
  3.琴斯托霍瓦师范大学科学与技术学院，波兰琴斯托霍瓦　42200
  4.罗马尼亚国家科学院，罗马尼亚布加勒斯特　050044
- 作者简介：
  
  [ "BRIK Mikhail G (1969 - ), received his PhD from Kuban State University (Russia) in 1995 and his DSc (habilitation) from the Institute of Physics, Polish Academy of Sciences (Poland) in 2012. Since 2007 he is a professor at the Institute of Physics, University of Tartu, Estonia. Before that, he worked at Kyoto University (Japan) from 2003 to 2007, Weizmann Institute of Science (Israel) in 2002, Asmara University (Eritrea) from 2000 to 2001, and Kuban State University from 1995 to 2000. He is also a distinguished visiting professor at Chongqing University of Posts and Telecommunications (China) and Professor at Jan Długosz University (Poland). Since 2015 he serves as one of the editors of Optical Materials (Elsevier). Prof. Brik’s scientific interests cover theoretical spectroscopy of transition metal and rare earth ions in optical materials, crystal field theory, and ab initio calculations of the physical properties of pure and doped functional compounds. He is a coeditor of two books and author of 12 book chapters and about 410 papers in international journals. According to Google Scholar (June 2020), he has more than 8 500 citations with h index 45. He received the Dragomir Hurmuzescu Award of Romanian Academy in 2006 and the State Prize of the Republic of Estonia in the field of exact sciences in 2013. In 2018 he received the state professor title from the President of Poland." ]
  [ "MA Chong⁃geng g（1980-）, received his PhD from University of Science and Technology of China in 2008. He spent three years（2010—2013）as a post⁃doctor in University of Tartu with the financial support of Eu⁃ropean Social Fund. He was also a visiting professor at University of Verona in 2017. His area of scientific interests covers the first ⁃ principles and crystal-field design of luminescent materials. He has published one book and more than 100 papers in international journals, which attracted more than 2 500 citations（hindex=27）. Currently he is a full professor and the director of CQUPT ⁃BUL Innovation Institute at Chong ⁃qing University of Posts and Telecommunications.Email: macg@cqupt.edu.cn" ]
- 基金信息：
  
  National Foreign Experts Program for “Belt and Road Initiative” Innovative Talent Exchange(DL2021035001L);2021 Chongqing Postdoctoral International Exchange Program of China Postdoctoral Science Foundation;National Natural Science Foundation of China(52161135110)
- DOI：10.37188/CJL.20220243
  中图分类号：
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BRIK Mikhail G, KURBONIYON Mekhrdod S, 马崇庚. 八面体配合物中Ni²⁺离子的光谱性质[J]. 发光学报, 2022,43(9):1459-1467.

BRIK Mikhail G, KURBONIYON Mekhrdod S, MA Chong-geng. Spectroscopic Properties of Ni²⁺Ions in Octahedral Complexes[J]. Chinese Journal of Luminescence, 2022,43(9):1459-1467.
BRIK Mikhail G, KURBONIYON Mekhrdod S, 马崇庚. 八面体配合物中Ni²⁺离子的光谱性质[J]. 发光学报, 2022,43(9):1459-1467. DOI： 10.37188/CJL.20220243.

BRIK Mikhail G, KURBONIYON Mekhrdod S, MA Chong-geng. Spectroscopic Properties of Ni²⁺Ions in Octahedral Complexes[J]. Chinese Journal of Luminescence, 2022,43(9):1459-1467. DOI： 10.37188/CJL.20220243.

摘要

基于最新的文献数据，我们研究了八面体配位下Ni,2+ ,离子自旋禁止跃迁,3,A,2,⁃,1,E的能量与新的电子云膨胀效应参数, $β_{1} = \sqrt[]{{(B / B_{0})}^{2} + {(C / C_{0})}^{2}}$ ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822410&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822406&type=,35.81399918,6.68866634,之间的经验关系，其中（,B,、,C,）和（,B,0,、,C,0,）分别是Ni,2+ ,离子在晶体中和自由离子状态下描述3d电子间库仑作用的拉卡参数。研究结果表明，Ni,2+,离子,1,E态的能量是, $β_{1}$ ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822417&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822415&type=,2.96333337,3.80999994,参数的线性函数。这样的发现确认了完全处理电子云膨胀效应需要同时考虑两个拉卡参数,B, 和 ,C,约减贡献的重要事实。通常使用的电子云膨胀效应参数, $β = B / B_{0}$ ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822423&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822421&type=,12.61533356,3.30200005,由于完全忽略了拉卡参数,C, 的约减贡献，在估计,1,E态能级位置上是不准确的。相比而言，我们构建的理论方法则更好。本文所收集的实验数据以及实施的理论分析均将会对Ni,2+,离子掺杂材料的光谱学研究有一定的参考价值。

Abstract

Based on an up-do-date literature data， we consider an empirical trend between the energy of the spin-forbidden ,3,A,2,-,1,E transition of the octahedrally coordinated Ni,2+, ions and a new nephelauxetic parameter, $β_{1} = \sqrt[]{{(B / B_{0})}^{2} + {(C / C_{0})}^{2}}$ ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822390&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822387&type=,36.83000183,6.68866634, （,B,， ,C, （,B,0,， ,C,0,） are the Racah parameters of Ni,2+, ions in a crystal（free state）， respectively）. It is demonstrated that the energy of the Ni,2+ 1,E state is a linear function of the , $β_{1}$ ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822396&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822394&type=,2.96333337,3.80999994, parameter. These findings prove importance of a simultaneous consideration of reduction of both Racah parameters ,B, and ,C, due to the nephelauxetic effect. Such an approach is more accurate in estimating the energy position of the ,1,E level. The commonly used nephelauxetic ratio , $β = B / B_{0}$ ,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822402&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822401&type=,12.61533356,3.30200005,， which completely ignores the reduction in the values of the Racah parameter ,C,， is not accurate enough for this purpose. The collected in the present paper experimental data and their analysis can be useful for researchers working with the crystalline materials doped with Ni,2+, ions.

关键词

Ni2+自旋禁戒跃迁共价性

Keywords

Ni2+spin-forbidden transitionscovalency

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八面体配合物中Ni2+离子的光谱性质

Spectroscopic Properties of Ni2+ Ions in Octahedral Complexes

DOI：10.37188/CJL.20220243

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八面体配合物中Ni²⁺离子的光谱性质

Spectroscopic Properties of Ni²⁺Ions in Octahedral Complexes