八面体配合物中Ni<sup>2+</sup>离子的光谱性质

BRIK Mikhail G; KURBONIYON Mekhrdod S; 马崇庚

doi:10.37188/CJL.20220243

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八面体配合物中Ni²⁺离子的光谱性质

特邀报告 | 更新时间：2023-02-13

- 八面体配合物中Ni²⁺离子的光谱性质
  增强出版
- Spectroscopic Properties of Ni²⁺Ions in Octahedral Complexes
- 发光学报 2022年43卷第9期页码：1459-1467
- 作者机构：
  
  1.重庆邮电大学光电工程学院 & “重庆邮电大学⁃伦敦布鲁内尔大学”交叉创新研究院，重庆　400065
  2.塔尔图大学物理研究所，爱沙尼亚塔尔图　50411
  3.琴斯托霍瓦师范大学科学与技术学院，波兰琴斯托霍瓦　42200
  4.罗马尼亚国家科学院，罗马尼亚布加勒斯特　050044
- 作者简介：
  
  [ "BRIK Mikhail G (1969 - ), received his PhD from Kuban State University (Russia) in 1995 and his DSc (habilitation) from the Institute of Physics, Polish Academy of Sciences (Poland) in 2012. Since 2007 he is a professor at the Institute of Physics, University of Tartu, Estonia. Before that, he worked at Kyoto University (Japan) from 2003 to 2007, Weizmann Institute of Science (Israel) in 2002, Asmara University (Eritrea) from 2000 to 2001, and Kuban State University from 1995 to 2000. He is also a distinguished visiting professor at Chongqing University of Posts and Telecommunications (China) and Professor at Jan Długosz University (Poland). Since 2015 he serves as one of the editors of Optical Materials (Elsevier). Prof. Brik’s scientific interests cover theoretical spectroscopy of transition metal and rare earth ions in optical materials, crystal field theory, and ab initio calculations of the physical properties of pure and doped functional compounds. He is a coeditor of two books and author of 12 book chapters and about 410 papers in international journals. According to Google Scholar (June 2020), he has more than 8 500 citations with h index 45. He received the Dragomir Hurmuzescu Award of Romanian Academy in 2006 and the State Prize of the Republic of Estonia in the field of exact sciences in 2013. In 2018 he received the state professor title from the President of Poland." ]
  [ "MA Chong⁃geng g（1980-）, received his PhD from University of Science and Technology of China in 2008. He spent three years（2010—2013）as a post⁃doctor in University of Tartu with the financial support of Eu⁃ropean Social Fund. He was also a visiting professor at University of Verona in 2017. His area of scientific interests covers the first ⁃ principles and crystal-field design of luminescent materials. He has published one book and more than 100 papers in international journals, which attracted more than 2 500 citations（hindex=27）. Currently he is a full professor and the director of CQUPT ⁃BUL Innovation Institute at Chong ⁃qing University of Posts and Telecommunications.Email: macg@cqupt.edu.cn" ]
- 基金信息：
  
  National Foreign Experts Program for “Belt and Road Initiative” Innovative Talent Exchange(DL2021035001L);2021 Chongqing Postdoctoral International Exchange Program of China Postdoctoral Science Foundation;National Natural Science Foundation of China(52161135110)
- DOI：10.37188/CJL.20220243
  中图分类号： O482.31
- 纸质出版日期：2022-09-05，
  
  收稿日期：2022-06-06，
  
  修回日期：2022-07-04，
扫描看全文
BRIK Mikhail G,KURBONIYON Mekhrdod S,马崇庚.八面体配合物中Ni²⁺离子的光谱性质[J].发光学报,2022,43(09):1459-1468.

G BRIK Mikhail,S KURBONIYON Mekhrdod,MA Chong-geng.Spectroscopic Properties of Ni²⁺Ions in Octahedral Complexes[J].Chinese Journal of Luminescence,2022,43(09):1459-1468.
BRIK Mikhail G,KURBONIYON Mekhrdod S,马崇庚.八面体配合物中Ni²⁺离子的光谱性质[J].发光学报,2022,43(09):1459-1468. DOI： 10.37188/CJL.20220243.

G BRIK Mikhail,S KURBONIYON Mekhrdod,MA Chong-geng.Spectroscopic Properties of Ni²⁺Ions in Octahedral Complexes[J].Chinese Journal of Luminescence,2022,43(09):1459-1468. DOI： 10.37188/CJL.20220243.

摘要

基于最新的文献数据，我们研究了八面体配位下Ni

离子自旋禁止跃迁

⁃

E的能量与新的电子云膨胀效应参数

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822410&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822406&type=

35.81399918

6.68866634

之间的经验关系，其中（

、

）和（

、

）分别是Ni

离子在晶体中和自由离子状态下描述3d电子间库仑作用的拉卡参数。研究结果表明，Ni

离子

E态的能量是

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822417&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822415&type=

2.96333337

3.80999994

参数的线性函数。这样的发现确认了完全处理电子云膨胀效应需要同时考虑两个拉卡参数

和

约减贡献的重要事实。通常使用的电子云膨胀效应参数

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822423&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822421&type=

12.61533356

3.30200005

由于完全忽略了拉卡参数

的约减贡献，在估计

E态能级位置上是不准确的。相比而言，我们构建的理论方法则更好。本文所收集的实验数据以及实施的理论分析均将会对Ni

离子掺杂材料的光谱学研究有一定的参考价值。

Abstract

Based on an up-do-date literature data， we consider an empirical trend between the energy of the spin-forbidden

E transition of the octahedrally coordinated Ni

ions and a new nephelauxetic parameter

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822390&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822387&type=

36.83000183

6.68866634

（

，

（

，

） are the Racah parameters of Ni

ions in a crystal（free state）， respectively）. It is demonstrated that the energy of the Ni

2+ 1

E state is a linear function of the

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822396&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822394&type=

2.96333337

3.80999994

parameter. These findings prove importance of a simultaneous consideration of reduction of both Racah parameters

and

due to the nephelauxetic effect. Such an approach is more accurate in estimating the energy position of the

E level. The commonly used nephelauxetic ratio

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822402&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=39822401&type=

12.61533356

3.30200005

， which completely ignores the reduction in the values of the Racah parameter

， is not accurate enough for this purpose. The collected in the present paper experimental data and their analysis can be useful for researchers working with the crystalline materials doped with Ni

ions.

关键词

Ni2+自旋禁戒跃迁共价性

Keywords

Ni2+spin-forbidden transitionscovalency

references

POWELL R C. Physics of Solid⁃state Laser Materials ［M］. New York： Springer， 1998. doi: 10.1007/978-1-4612-0643-9http://dx.doi.org/10.1007/978-1-4612-0643-9

AVRAM N M， BRIK M G. Optical Properties of 3d⁃ions in Crystals： Spectroscopy and Crystal Field Analysis ［M］. Beijing： Tsinghua University Press， 2013.

BRIK M G， MA C G. Theoretical Spectroscopy of Transition Metal and Rare Earth Ions： From Free State to Crystal Field ［M］. New York： Jenny Stanford Publishing， 2020.

KÜCK S. Laser-related spectroscopy of ion-doped crystals for tunable solid-state lasers ［J］. Appl. Phys. B， 2001， 72（5）： 515-562. doi: 10.1007/s003400100540http://dx.doi.org/10.1007/s003400100540

LIU R S， WANG X J. Phosphor Handbook： Experimental Methods for Phosphor Evaluation and Characterization ［M］. 3rd ed. London： CRC Press， 2022.

SETLUR A A， RADKOV E V， HENDERSON C S， et al. Energy-efficient， high-color-rendering LED lamps using oxyfluoride and fluoride phosphors ［J］. Chem. Mater.， 2010， 22（13）： 4076-4082. doi: 10.1021/cm100960ghttp://dx.doi.org/10.1021/cm100960g

SRIVASTAVA A M， SOULES T F. Luminescent materials （Phosphors）［M］. Kirk-Othmer Eds. Kirk-Othmer Encyclopedia of Chemical Technology. 4th ed. Vol.15. New York： John Wiley & Sons， 1995.

ZHOU Q， DOLGOV L， SRIVASTAVA A M， et al. Mn2+ and Mn4+ red phosphors： synthesis， luminescence and applications in WLEDs. A review ［J］. J. Mater. Chem. C， 2018， 6（11）： 2652-2671. doi: 10.1039/c8tc00251ghttp://dx.doi.org/10.1039/c8tc00251g

NIE J M， LI Y， LIU S S， et al. Tunable long persistent luminescence in the second near-infrared window via crystal field control ［J］. Sci. Rep.， 2017， 7（1）： 12392-1-7. doi: 10.1038/s41598-017-12591-1http://dx.doi.org/10.1038/s41598-017-12591-1

MATUSZEWSKA C， MARCINIAK L. The influence of host material on NIR Ⅱ and NIR Ⅲ emitting Ni2+ based luminescent thermometers in ATiO3∶Ni2+ （A=Sr， Ca， Mg， Ba） nanocrystals ［J］. J. Lumin.， 2020， 223： 117221-1-9. doi: 10.1016/j.jlumin.2020.117221http://dx.doi.org/10.1016/j.jlumin.2020.117221

GAO Y， WANG B N， LIU L， et al. Near-infrared engineering for broad-band wavelength-tunable in biological window of NIR-Ⅱ and -Ⅲ： a solid solution phosphor of Sr1-xCaxTiO3∶Ni2+ ［J］. J. Lumin.， 2021， 238： 118235-1-7. doi: 10.1016/j.jlumin.2021.118235http://dx.doi.org/10.1016/j.jlumin.2021.118235

SUGANO S， TANABE Y， KAMIMURA H. Multiplets of Transition⁃metal Ions in Crystals ［M］. New York： Academic Press， 1970.

FIGGIS B N， HITCHMAN M A. Ligand Field Theory and Its Applications ［M］. New York： Wiley-VCH， 2000.

BRIK M G， SRIVASTAVA A M. Electronic energy levels of the Mn4+ Ion in the perovskite， CaZrO3 ［J］. ECS J. Solid State Sci. Technol.， 2013， 2（7）： R148-R152. doi: 10.1149/2.020307jsshttp://dx.doi.org/10.1149/2.020307jss

SRIVASTAVA A M， BRIK M G. Crystal field studies of the Mn4+ energy levels in the perovskite， LaAlO3 ［J］. Opt. Mater.， 2013， 35（8）： 1544-1548. doi: 10.1016/j.optmat.2013.03.021http://dx.doi.org/10.1016/j.optmat.2013.03.021

BRIK M G， SRIVASTAVA A M， AVRAM N M， et al. Empirical relation between covalence and the energy position of the Ni2+ 1E state in octahedral complexes ［J］. J. Lumin.， 2014， 148： 338-341. doi: 10.1016/j.jlumin.2013.12.052http://dx.doi.org/10.1016/j.jlumin.2013.12.052

BRIK M G， CAMARDELLO S J， SRIVASTAVA A M. Influence of covalency on the Mn4+ 2Eg→4A2g emission energy in crystals ［J］. ECS J. Solid State Sci. Technol.， 2015， 4（3）： R39-R43. doi: 10.1149/2.0031503jsshttp://dx.doi.org/10.1149/2.0031503jss

BRIK M G， CAMARDELLO S J， SRIVASTAVA A M， et al. Spin-forbidden transitions in the spectra of transition metal ions and nephelauxetic effect ［J］. ECS J. Solid State Sci. Technol.， 2016， 5（1）： R3067-R3077. doi: 10.1149/2.0091601jsshttp://dx.doi.org/10.1149/2.0091601jss

MA C G， WANG Y， LIU D X， et al. Origin of the β1 parameter describing the nephelauxetic effect in transition metal ions with spin-forbidden emissions ［J］. J. Lumin.， 2018， 197： 142-146. doi: 10.1016/j.jlumin.2018.01.036http://dx.doi.org/10.1016/j.jlumin.2018.01.036

BRIK Mikhail G，马崇庚， SRIVASTAVA Alok M，等. 用于固态照明的Mn4+离子光谱学［J］. 发光学报， 2020， 41（9）： 1011-1029. doi: 10.1016/j.jlumin.2019.116834http://dx.doi.org/10.1016/j.jlumin.2019.116834

BRIK M G， MA C G， SRIVASTAVA A M， et al. Mn4+ ions for solid state lighting ［J］. Chin. J. Lumin.， 2020， 41（9）： 1011-1029. （in English）. doi: 10.1016/j.jlumin.2019.116834http://dx.doi.org/10.1016/j.jlumin.2019.116834

UYLINGS P H M， RAASSEN A J J， WYART J F. Energies of N equivalent electrons expressed in terms of two-electron energies and independent three-electron parameters： a new complete set of orthogonal operators： Ⅱ. Application to 3dN configurations ［J］. J. Phys. B： At. Mol. Phys.， 1984， 17（20）： 4103-4126. doi: 10.1088/0022-3700/17/20/010http://dx.doi.org/10.1088/0022-3700/17/20/010

WANG H Q， KUANG X Y， LI H F. EPR and optical spectra of Ni2+-VAg in silver chloride and silver bromide ［J］. Mol. Phys.， 2009， 107（7）： 621-627. doi: 10.1080/00268970902845271http://dx.doi.org/10.1080/00268970902845271

BRIK M G， AVRAM C N， AVRAM N M. Comparative study of crystal field effects for Ni2+ ion in LiGa5O8， MgF2 and AgCl crystals ［J］. J. Phys. Chem. Solids， 2008， 69（7）： 1796-1801. doi: 10.1016/j.jpcs.2008.01.004http://dx.doi.org/10.1016/j.jpcs.2008.01.004

FANG W， WANG Q W， YANG W Y， et al. Theoretical studies of EPR parameters and defect structures for Ni2+ ions in corundum ［J］. Phys. B Condens. Matter， 2013， 408： 169-174. doi: 10.1016/j.physb.2012.09.031http://dx.doi.org/10.1016/j.physb.2012.09.031

REDDY V， KRISHNA R， RAO T R， et al. Synthesis and optical properties of Co2+ and Ni2+ ions doped β-BaB2O4 nanopowders ［J］. J. Lumin.， 2012， 132（9）： 2325-2329. doi: 10.1016/j.jlumin.2012.04.024http://dx.doi.org/10.1016/j.jlumin.2012.04.024

ANDREICI E L， AVRAM N M. Fine structure of optical energy levels scheme for Ni2+ doped in inverted perovskite BaLiF3 ［J］. AIP Conf. Proc.， 2011， 1387： 155-159. doi: 10.1063/1.3647067http://dx.doi.org/10.1063/1.3647067

BRIK M G. Crystal field analysis of the absorption spectra and electron-phonon interaction in Ca3Sc2Ge3O12∶Ni2+ ［J］. J. Phys. Chem. Solids， 2006， 67（4）： 738-744. doi: 10.1016/j.jpcs.2005.11.005http://dx.doi.org/10.1016/j.jpcs.2005.11.005

ACKERMAN J， FOUASSIER C， HOLT E M， et al. 5.deg. Crystal spectra of nickel（Ⅱ） chloride and nickel（Ⅱ） bromide ［J］. Inorg. Chem.， 1972， 11（12）： 3118-3122. doi: 10.1021/ic50118a052http://dx.doi.org/10.1021/ic50118a052

BRIK M G， KITYK I V， OZGA K， et al. Structural， electronic and optical properties of pure and Ni2+-doped CdI2 layered crystals as explored by ab initio and crystal field calculations ［J］. Phys. B Condens. Matter， 2011， 406（2）： 192-199. doi: 10.1016/j.physb.2010.09.051http://dx.doi.org/10.1016/j.physb.2010.09.051

WENGER O S， BÉNARD S， GÜDEL H U. Crystal field effects on the optical absorption and luminescence properties of Ni2+-doped chlorides and bromides： crossover in the emitting higher excited state ［J］. Inorg. Chem.， 2002， 41（23）： 5968-5977. doi: 10.1021/ic020347yhttp://dx.doi.org/10.1021/ic020347y

OETLIKER U， RILEY M J， GÜDEL H U. Excited state spectroscopy of Ni2+ doped chloride and fluoride lattices ［J］. J. Lumin.， 1995， 63（1-2）： 63-73. doi: 10.1016/0022-2313(94)00046-fhttp://dx.doi.org/10.1016/0022-2313(94)00046-f

FENG W L， CHEN J J， HAN Z. Investigations of the optical and EPR spectra for （NiX6）4- （X=Cl， Br， I） clusters ［J］. J. Magn. Magn. Mater.， 2009， 321（19）： 3290-3292. doi: 10.1016/j.jmmm.2009.05.065http://dx.doi.org/10.1016/j.jmmm.2009.05.065

FERGUSON J， GUGGENHEIM H J， WOOD D L. Electronic absorption spectrum of Ni Ⅱ in cubic perovskite fluorides. Ⅰ ［J］. J. Chem. Phys.， 1964， 40（3）： 822-830. doi: 10.1063/1.1725212http://dx.doi.org/10.1063/1.1725212

BARREDA-ARGÜESO J A， RODRÍGUEZ F. Pressure dependence of the crystal-field spectrum of KNiF3： Single and double excitations ［J］. Phys. Rev. B， 2021， 103（8）： 085115-1-9. doi: 10.1103/physrevb.103.085115http://dx.doi.org/10.1103/physrevb.103.085115

BRIK M G， KUMAR G A， SARDAR D K. Ab initio， crystal field and experimental spectroscopic studies of pure and Ni2+-doped KZnF3 crystals ［J］. Mater. Chem. Phys.， 2012， 136（1）： 90-102. doi: 10.1016/j.matchemphys.2012.06.035http://dx.doi.org/10.1016/j.matchemphys.2012.06.035

WANG S J， KUANG X Y， LU C. Theoretical study of local structure for Ni2+ ions at tetragonal sites in K2ZnF4∶Ni2+ system ［J］. Spectrochim. Acta A Mol. Biomol. Spectrosc.， 2008， 71（4）： 1317-1320. doi: 10.1016/j.saa.2008.04.002http://dx.doi.org/10.1016/j.saa.2008.04.002

FANG W， TANG H Y， CHENG W D， et al. Theoretical investigations of optical spectra and electron paramagnetic resonance spectra of LiCl：Ni2+ crystals ［J］. Spectrochim. Acta A Mol. Biomol. Spectrosc.， 2012， 99： 342-346. doi: 10.1016/j.saa.2012.08.041http://dx.doi.org/10.1016/j.saa.2012.08.041

FENG W L， ZHENG W C. Studies of the defect structure from the calculations of optical and electron paramagnetic resonance spectra for Ni2+ centre in α⁃LiIO3 crystal ［J］. Pramana， 2008， 71（3）： 573-578. doi: 10.1007/s12043-008-0132-yhttp://dx.doi.org/10.1007/s12043-008-0132-y

YANG Z Y， RUDOWICZ C， YEUNG Y Y. Microscopic spin-Hamiltonian parameters and crystal field energy levels for the low C3 symmetry Ni2+ centre in LiNbO3 crystals ［J］. Phys. B Condens. Matter， 2004， 348（1-4）： 151-159. doi: 10.1016/j.physb.2003.11.085http://dx.doi.org/10.1016/j.physb.2003.11.085

BRIK M G， AVRAM N M， AVRAM C N， et al. Ground and excited state absorption of Ni2+ ions in MgAl2O4： crystal field analysis ［J］. J. Alloys Compd.， 2007， 432（1-2）： 61-68. doi: 10.1016/j.jallcom.2006.06.025http://dx.doi.org/10.1016/j.jallcom.2006.06.025

GONZÁLEZ E， RODRIGUE-WITCHEL A， REBER C. Absorption spectroscopy of octahedral nickel （Ⅱ） complexes： a case study of interactions between multiple electronic excited states ［J］. Coord. Chem. Rev.， 2007， 251（3-4）： 351-363. doi: 10.1016/j.ccr.2006.08.011http://dx.doi.org/10.1016/j.ccr.2006.08.011

ANDREICI E L， STANCIU M， AVRAM N M. Crystal field studies on MgGa2O4∶Ni2+ ［J］. AIP Conf. Proc.， 2010， 1262（1）： 130-135. doi: 10.1063/1.3482219http://dx.doi.org/10.1063/1.3482219

MIRONOVA-ULMANE N， BRIK M G， SILDOS I. Crystal field calculations of energy levels of the Ni2+ ions in MgO ［J］. J. Lumin.， 2013， 135： 74-78. doi: 10.1016/j.jlumin.2012.10.026http://dx.doi.org/10.1016/j.jlumin.2012.10.026

ZAMYATIN O A， CHURBANOV M F， PLOTNICHENKO V G， et al. Optical properties of the MoO3-TeO2 glasses doped with Ni2+ ions ［J］. J. Non⁃Cryst. Solids， 2018， 480： 74-80. doi: 10.1016/j.jnoncrysol.2017.08.016http://dx.doi.org/10.1016/j.jnoncrysol.2017.08.016

MOLCHANOVA A D. Experimental study and analysis of absorption spectra of Ni2+ ions in nickel orthoborate Ni3（BO3）2 ［J］. Phys. Solid State， 2018， 60（10）： 1957-1965. doi: 10.1134/s1063783418100219http://dx.doi.org/10.1134/s1063783418100219

BRIK M G， AVRAM N M， AVRAM C N. Comparative crystal field study of Ni2+ energy levels in NiCl2， NiBr2， and NiI2 crystals ［J］. Phys. B Condens. Matter， 2006， 371（1）： 43-49. doi: 10.1016/j.physb.2005.09.034http://dx.doi.org/10.1016/j.physb.2005.09.034

KAMMOUN S， DAMMAK M， MAALEJ R， et al. Crystal-field analysis for d8 ions at D4h symmetry sites： Electronic states in trans-NiCl2（H2O）4 complex ［J］. J. Lumin.， 2007， 124（2）： 316-320. doi: 10.1016/j.jlumin.2006.04.006http://dx.doi.org/10.1016/j.jlumin.2006.04.006

ZHAO M G， DU M L. Determination of the state equation of NiX2 from the high-pressure spectra shifts ［J］. J. Phys. C： Solid State Phys.， 1987， 20（28）： 4467-4475. doi: 10.1088/0022-3719/20/28/011http://dx.doi.org/10.1088/0022-3719/20/28/011

LI H F， KUANG X Y， WANG H Q. Local structural properties of （NiF6）4- clusters in perovskite fluorides RbMF3（M = Cd2+， Ca2+， Mg2+） series： EPR and optical spectra study in tetragonal and trigonal ligand field ［J］. Chem. Phys. Lett.， 2008， 462（1-3）： 133-137. doi: 10.1016/j.cplett.2008.07.053http://dx.doi.org/10.1016/j.cplett.2008.07.053

ALCALA R， CASAS GONZALEZ J， VILLACAMPA B， et al. Photoluminescence of Ni2+ ions in RbCdF3 and RbCaF3 ［J］. J. Lumin.， 1991， 48-49： 569-573. doi: 10.1016/0022-2313(91)90195-2http://dx.doi.org/10.1016/0022-2313(91)90195-2

PLOTNICHENKO V G， SOKOLOV V O， SNOPATIN G E， et al. Optical absorption and structure of impurity Ni2+ center in tungstate⁃tellurite glass ［J］. J. Non⁃Cryst. Solids， 2011， 357（3）： 1070-1073. doi: 10.1016/j.jnoncrysol.2010.10.026http://dx.doi.org/10.1016/j.jnoncrysol.2010.10.026

SUZUKI T， HORIBUCHI K， OHISHI Y. Structural and optical properties of ZnO-Al2O3-SiO2 system glass⁃eramics containing Ni2+-doped nanocrystals ［J］. J. Non Cryst. Solids， 2005， 351（27-29）： 2304-2309. doi: 10.1016/j.jnoncrysol.2005.06.015http://dx.doi.org/10.1016/j.jnoncrysol.2005.06.015

KUMARI G K， BEGUM M， KRISHNA R， et al. Physical and optical properties of Co2+， Ni2+ doped 20ZnO+xLi2O+（30-x）K2O+50B2O3 （5 ≤ x ≤ 25） glasses： observation of mixed alkali effect ［J］. Mater. Res. Bull.， 2012， 47（9）： 2646-2654.

RAO T R， KRISHNA R， VENKATA REDDY C H Vet al. Mixed alkali effect and optical properties of Ni2+ doped 20ZnO+xLi2O+（30-x）Na2O+50B2O3 glasses ［J］. Spectrochim. Acta A Mol. Biomol. Spectrosc.， 2011， 79（5）： 1116-1122. doi: 10.1016/j.saa.2011.04.030http://dx.doi.org/10.1016/j.saa.2011.04.030

WANG S J， KUANG X Y， DUAN M L， et al. Comparative study of EPR spectra and crystal field effect on local structure for （NiF6）4- coordination complex in Ni2+∶ZnF2， NiF2， and Ni2+∶MgF2 systems ［J］. Phys. Status Sol. B， 2010， 247（2）： 416-421. doi: 10.1002/pssb.200945261http://dx.doi.org/10.1002/pssb.200945261

GURUGUBELLI T R， RAVIKUMAR R V S S N， KOUTAVARAPU R.Structural， optical， and luminescence properties of Ni2+ doped ZnO⁃CdS nanocomposite： synthesis and investigations for green light emission ［J］. Chem. Papers， 2022， 76（1）： 557-566. doi: 10.3390/catal12010084http://dx.doi.org/10.3390/catal12010084

LI C G， KUANG X Y， ZHAO Y R， et al. Investigation of the local structure and ZFS parameter for Ni2+ （V2+） ions in zinc fluosilicate at different pressure ［J］. Chem. Phys. Lett.， 2011， 512（4-6）： 263-268. doi: 10.1016/j.cplett.2011.07.031http://dx.doi.org/10.1016/j.cplett.2011.07.031

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八面体配合物中Ni2+离子的光谱性质

Spectroscopic Properties of Ni2+ Ions in Octahedral Complexes

DOI：10.37188/CJL.20220243

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八面体配合物中Ni²⁺离子的光谱性质

Spectroscopic Properties of Ni²⁺Ions in Octahedral Complexes