Preparation and Temperature Sensing Properties of Bi3+, Eu3+ Co-doped Double Perovskite Gd2ZnTiO6 Phosphor

WEN Yinuo; CHEN Yanling; FU Jie; LIN Jianhua; ZHOU Liuyan; LI Jie; HAN Mingxiao; CHEN Shuyang; DENG Degang; CHEN Liang

doi:10.37188/CJL.20220341

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Preparation and Temperature Sensing Properties of Bi³⁺, Eu³⁺ Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor

Synthesis and Properties of Materials | 更新时间：2023-05-10

- Preparation and Temperature Sensing Properties of Bi³⁺, Eu³⁺ Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 4, Pages: 615-626(2023)
- 作者机构：
  
  中国计量大学光电材料与器件研究所，浙江杭州　310018
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(52172164);the Fundamental Research Funds for the Provincial Universities of Zhejiang(2020YW21;2020YW23;2019YW03;2020YW31)
- DOI：10.37188/CJL.20220341
  CLC： O482.31
- Published：05 April 2023，
  
  Received：27 September 2022，
  
  Revised：16 October 2022，
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温一诺,陈彦伶,付杰等.Bi³⁺、Eu³⁺共掺双钙钛矿Gd₂ZnTiO₆荧光粉制备及其温度传感性能[J].发光学报,2023,44(04):615-626.

WEN Yinuo,CHEN Yanling,FU Jie,et al.Preparation and Temperature Sensing Properties of Bi³⁺, Eu³⁺ Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor[J].Chinese Journal of Luminescence,2023,44(04):615-626.
温一诺,陈彦伶,付杰等.Bi³⁺、Eu³⁺共掺双钙钛矿Gd₂ZnTiO₆荧光粉制备及其温度传感性能[J].发光学报,2023,44(04):615-626. DOI： 10.37188/CJL.20220341.

WEN Yinuo,CHEN Yanling,FU Jie,et al.Preparation and Temperature Sensing Properties of Bi³⁺, Eu³⁺ Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor[J].Chinese Journal of Luminescence,2023,44(04):615-626. DOI： 10.37188/CJL.20220341.

摘要

采用高温固相法制备了一系列具有双发射中心的Gd

2 （1-

x-y

）

ZnTiO

∶

，

荧光粉。采用X射线衍射、扫描电子显微镜、荧光光谱、寿命衰减曲线和变温发射光谱等方法，系统地研究了该材料的结构、发光性能和温度传感特性。在Gd

ZnTiO

∶Bi

，Eu

荧光粉中，Bi

和Eu

离子占据了Gd

离子的位置。在紫外激发下，Eu

的激发光谱和Bi

的发射光谱存在光谱重叠，表明从Bi

到Eu

可能存在能量传递。通过荧光强度比技术探究了Bi

蓝光发射与Eu

红光发射的不同温度响应特性。在293~473 K温度范围内，测得Gd

ZnTiO

∶Bi

，Eu

荧光粉的最大相对温度灵敏度为1.133%·K

-1

，最大绝对灵敏度为0.73 %·K

-1

。因此，Gd

ZnTiO

∶Bi

，Eu

荧光粉是一种有潜力的非接触式光学测温材料。

Abstract

A series of Gd

2 （1

-x-y

）

ZnTiO

∶

，

phosphors with dual emission centers were prepared by high-temperature solid phase method. The structure， luminescence properties and temperature sensing characteristics of the material were systematically studied by X-ray diffraction， scanning electron microscopy， fluorescence spectroscopy， lifetime decay curve and variable temperature emission spectroscopy， respectively. In Gd

ZnTiO

∶Bi

，Eu

phosphor， Bi

and Eu

ions occupy Gd

ion position. Under UV excitation， the excitation spectra of Eu

and emission spectra of Bi

overlap， indicating that there may be energy transfer from Bi

to Eu

. The fluorescence intensity ratio technique was used to explore the different temperature response characteristics of Bi

blue light emission and Eu

red light emission. In the temperature range of 293-473 K， the maximum relative temperature sensitivity of Gd

ZnTiO

∶Bi

，Eu

phosphors was 1.133%·K

-1

， and the maximum absolute sensitivity value was 0.73%·K

-1

， respectively. Therefore， Gd

ZnTiO

∶Bi

，Eu

phosphor is a potential non-contact optical temperature measurement material.

关键词

Gd2ZnTiO6∶Bi3+，Eu3+双钙钛矿荧光能量传递光学测温荧光强度比

Keywords

Gd2ZnTiO6∶Bi3+，Eu3+double perovskitefluorescence energy transferoptical thermometryfluorescence intensity ratio

references

FUJIMOTO D， AKIBA K Y， NAKAMURA N. Isolation and characterization of a fluorescent material in bovine achilles tendon collagen ［J］. Biochem. Biophys. Res. Commun.， 1977， 76 （4）： 1124-1129. doi: 10.1016/0006-291X(77)90972-Xhttp://dx.doi.org/10.1016/0006-291X(77)90972-X

PETORAL R M， SÖDERLIND F， KLASSON A， et al. Synthesis and characterization of Tb3+-doped Gd2O3 nanocrystals： a bifunctional material with combined fluorescent labeling and MRI contrast agent properties ［J］. J. Phys. Chem. C， 2009， 113 （17）： 6913-6920. doi: 10.1021/jp808708mhttp://dx.doi.org/10.1021/jp808708m

DE SOUZA SIERRA M M， DONARD O F X， LAMOTTE M. Spectral identification and behaviour of dissolved organic fluorescent material during estuarine mixing processes ［J］. Mar. Chem.， 2097， 58 （1-2）： 51-58.

DAI W B， HU J， LIU G， et al. Thermometer of stable SrAl2Si2O8∶Ce3+，Tb3+ based on synergistic luminescence ［J］. J. Lumin.， 2020， 217： 116807-1-7. doi: 10.1016/j.jlumin.2019.116807http://dx.doi.org/10.1016/j.jlumin.2019.116807

张娜，李阳，尹延如，等. Dy3+掺杂Lu2O3和Y2O3单晶光纤下转换荧光测温性能［J］. 发光学报， 2022， 43 （2）： 182-191. doi: 10.37188/cjl.20210345http://dx.doi.org/10.37188/cjl.20210345

ZHANG N， LI Y， YIN Y R， et al. Down-conversion luminescence performance of Dy3+ doped Lu2O3 and Y2O3 single crystal fibers for temperature sensing ［J］. Chin. J. Lumin.， 2022， 43 （2）： 182-191. （in Chinese）. doi: 10.37188/cjl.20210345http://dx.doi.org/10.37188/cjl.20210345

LAVIGNE M B. Differences in stem respiration responses to temperature between balsam fir trees in thinned and unthinned stands ［J］. Tree Physiol.， 1987， 3 （3）： 225-233. doi: 10.1093/treephys/3.3.225http://dx.doi.org/10.1093/treephys/3.3.225

COUPEAUD A， DEMYK K， MENY C， et al. Low-temperature FIR and submillimetre mass absorption coefficient of interstellar silicate dust analogues ［J］. Astron. Astrophys.， 2011， 535： A124-1-15. doi: 10.1051/0004-6361/201116945http://dx.doi.org/10.1051/0004-6361/201116945

ZHENG Z G， ZHANG J F， LIU X Y， et al. Luminescence and self-referenced optical temperature sensing performance in Ca2YZr2Al3O12∶Bi3+， Eu3+ phosphors ［J］. Ceram. Int.， 2020， 46 （5）： 6154-6159. doi: 10.1016/j.ceramint.2019.11.081http://dx.doi.org/10.1016/j.ceramint.2019.11.081

XU F， ZHENG B， XIA H P， et al. Ratiometric temperature sensing behavior of dual-emitting Ce3+/Tb3+ co-doped Na5Y9F32 single crystal with high relative sensitivity ［J］. J. Alloys Compd.， 2021， 873 （25）： 159790-1-11. doi: 10.1016/j.jallcom.2021.159790http://dx.doi.org/10.1016/j.jallcom.2021.159790

ZHAO J T， SUN X Y， WANG Z Q. Ce3+/Eu2+ doped SrSc2O4 phosphors： synthesis， luminescence and energy transfer from Ce3+ to Eu2+ ［J］. Chem. Phys. Lett.， 2018， 691： 68-72. doi: 10.1016/j.cplett.2017.10.062http://dx.doi.org/10.1016/j.cplett.2017.10.062

ZHANG X Z， ZHU Z P， GUO Z Y， et al. A ratiometric optical thermometer with high sensitivity and superior signal discriminability based on Na3Sc2P3O12∶Eu2+， Mn2+ thermochromic phosphor ［J］. Chem. Eng. J.， 2019， 365： 413-422. doi: 10.1016/j.cej.2018.09.075http://dx.doi.org/10.1016/j.cej.2018.09.075

CHEN D Q， WANG Z Y， ZHOU Y， et al. Tb3+/Eu3+∶YF3 nanophase embedded glass ceramics： structural characterization， tunable luminescence and temperature sensing behavior ［J］. J. Alloys Compd.， 2015， 646： 339-344. doi: 10.1016/j.jallcom.2015.06.030http://dx.doi.org/10.1016/j.jallcom.2015.06.030

FU J P， PANG R， JIANG L H， et al. A novel dichromic self-referencing optical probe SrO∶Bi3+，Eu3+ for temperature spatially and temporally imaging ［J］. Dalton Trans.， 2016， 45 （34）： 13317-13323. doi: 10.1039/c6dt01552bhttp://dx.doi.org/10.1039/c6dt01552b

WANG Z L， LIANG H B， GONG M L， et al. Novel red phosphor of Bi3+， Sm3+ co-activated NaEu （MoO4）2 ［J］. Opt. Mater.， 2007， 29 （7）： 896-900. doi: 10.1016/j.optmat.2005.12.010http://dx.doi.org/10.1016/j.optmat.2005.12.010

LUWANG M N， NINGTHOUJAM R S， SRIVASTAVA S K， et al. Disappearance and recovery of luminescence in Bi3+， Eu3+ codoped YPO4 nanoparticles due to the presence of water molecules up to 800 ℃ ［J］. J. Am. Chem. Soc.， 2011， 133 （9）： 2998-3004. doi: 10.1021/ja1092437http://dx.doi.org/10.1021/ja1092437

DAS N， NATH M A， THAKUR G S， et al. Monoclinically distorted perovskites， A2ZnTiO6 （A= Pr， Gd）： rietveld refinement， and dielectric studies ［J］. J. Solid State Chem.， 2015， 229： 97-102. doi: 10.1016/j.jssc.2015.05.003http://dx.doi.org/10.1016/j.jssc.2015.05.003

FU A J， GUAN A X， GAO F F， et al. A novel double perovskite La2ZnTiO6∶Eu3+ red phosphor for solid-state lighting： synthesis and optimum luminescence ［J］. Opt. Laser Technol.， 2017， 96： 43-49. doi: 10.1016/j.optlastec.2017.04.025http://dx.doi.org/10.1016/j.optlastec.2017.04.025

潘金泉，吴启运，杨汝军，等. 低温制备Mn4+掺杂Gd2ZnTiO6红色荧光粉及其发光性能研究［J］. 中国稀土学报， 2021， 39 （6）： 881-889.

PAN J Q， WU Q Y， YANG R J， et al. Low-temperature preparation and luminescence properties of Mn4+ doped Gd2ZnTiO6 red phosphor ［J］. J. Chin. Soc. Rare Earths， 2021， 39 （6）： 881-889. （in Chinese）

KIM D R， PARK S W， MOON B K， et al. The role of Yb3+ concentrations on Er3+ doped SrLaMgTaO6 double perovskite phosphors ［J］. RSC Adv.， 2017， 7 （3）： 1464-1470. doi: 10.1039/c6ra24808jhttp://dx.doi.org/10.1039/c6ra24808j

VERMA B， BAGHEL R N， BISEN D P， et al. A. Structural characterization and effects of Dy concentration on luminescent properties of BaMgSiO4 phosphors ［J］. J. Alloys Compd.， 2019， 805： 663-672. doi: 10.1016/j.jallcom.2019.07.077http://dx.doi.org/10.1016/j.jallcom.2019.07.077

ZHANG J， JIN C. Electronic structure， upconversion luminescence and optical temperature sensing behavior of Yb3+-Er3+/Ho3+ doped NaLaMgWO6 ［J］. J. Alloys Compd.， 2019， 783： 84-94. doi: 10.1016/j.jallcom.2018.12.281http://dx.doi.org/10.1016/j.jallcom.2018.12.281

WOOD D L， TAUC J. Weak absorption tails in amorphous semiconductors ［J］. Phys. Rev. B， 1972， 5 （8）： 3144-3151. doi: 10.1103/physrevb.5.3144http://dx.doi.org/10.1103/physrevb.5.3144

MORALES A E， MORA E S， PAL U. Use of diffuse reflectance spectroscopy for optical characterization of un-supported nanostructures ［J］. Rev. Mexic. Fís. S， 2007， 53 （5）： 18-22.

SETLUR A A， SRIVASTAVA A M. The nature of Bi3+ luminescence in garnet hosts ［J］. Opt. Mater.， 2006， 29 （4）： 410-415. doi: 10.1016/j.optmat.2005.09.076http://dx.doi.org/10.1016/j.optmat.2005.09.076

RIBEIRO S J L， DAHMOUCHE K， RIBEIRO C A， et al. Study of hybrid silica-polyethyleneglycol xerogels by Eu3+ luminescence spectroscopy ［J］. J. Sol⁃Gel Sci. Technol.， 1998， 13 （1-3）： 427-432. doi: 10.1023/a:1008673211834http://dx.doi.org/10.1023/a:1008673211834

CHEN X Y， ZHENG Z G， TENG L M， et al. Self-calibrated optical thermometer based on luminescence from SrLu2O4∶ Bi3+， Eu3+ phosphors ［J］. RSC Adv.， 2018， 8 （62）： 35422-35428. doi: 10.1039/c8ra06358chttp://dx.doi.org/10.1039/c8ra06358c

FU J， LIU F W， ZHOU L Y， et al. Dual-mode optical thermometry based on Bi3+/Eu3+ co-activated BaGd2O4 phosphor with high sensitivity and signal discriminability ［J］. Ceram. Int.， 2021， 47 （21）： 30221-30233. doi: 10.1016/j.ceramint.2021.07.202http://dx.doi.org/10.1016/j.ceramint.2021.07.202

邓超，林利添，汤利，等. Al3+掺杂ScVO4∶Eu3+， Bi3+荧光粉的制备及发光性质［J］. 发光学报， 2015， 36 （11）： 1246-1251. doi: 10.3788/fgxb20153611.1246http://dx.doi.org/10.3788/fgxb20153611.1246

DENG C， LIN L T， TANG L， et al. Synthesis and luminescence of ScVO4∶Eu3+， Bi3+，Al3+ phosphors ［J］. Chin. J. Lumin.， 2015， 36 （11）： 1246-1251. （in Chinese）. doi: 10.3788/fgxb20153611.1246http://dx.doi.org/10.3788/fgxb20153611.1246

MCCAMY C S. Correlated color temperature as an explicit function of chromaticity coordinates ［J］. Color Res. Appl.， 1992， 17 （2）： 142-144. doi: 10.1002/col.5080170211http://dx.doi.org/10.1002/col.5080170211

CHEN Y H， CHEN J， TONG Y， et al. Y4GeO8∶Er3+，Yb3+ up-conversion phosphors for optical temperature sensor based on FIR technique ［J］. J. Rare Earths， 2021， 39 （12）： 1512-1519. doi: 10.1016/j.jre.2021.06.007http://dx.doi.org/10.1016/j.jre.2021.06.007

TIAN Y， CHEN B J， HUA R N， et al. Optical transition， electron-phonon coupling and fluorescent quenching of La2（MoO4）3∶Eu3+ phosphor ［J］. J. Appl. Phys.， 2011， 109 （5）： 053511-1-6. doi: 10.1063/1.3551584http://dx.doi.org/10.1063/1.3551584

CHEN W P， CAO J K， HU F F， et al. Highly efficient Na5Gd9F32∶Tb3+ glass ceramic as nanocomposite scintillator for X-ray imaging ［J］. Opt. Mater. Express， 2018， 8 （1）： 41-49. doi: 10.1364/ome.8.000041http://dx.doi.org/10.1364/ome.8.000041

DENG H J， GAO Z W， XUE N， et al. A novel Eu3+-doped garnet-type tellurate red-emitting phosphor with high thermal stability and color purity ［J］. J. Lumin.， 2017， 192： 684-689. doi: 10.1016/j.jlumin.2017.07.063http://dx.doi.org/10.1016/j.jlumin.2017.07.063

ZOU A L， SUN S X， YU J J， et al. Luminescence and energy transfer mechanism of KZnPO4∶Dy3+， Eu3+ ［J］. J. Mater. Sci. Mater. Electron.， 2019， 30 （10）： 9155-9162. doi: 10.1007/s10854-019-01244-whttp://dx.doi.org/10.1007/s10854-019-01244-w

GUO H， HUANG X Y， ZENG Y J. Synthesis and photoluminescence properties of novel highly thermal-stable red-emitting Na3Sc2 （PO4）3∶Eu3+ phosphors for UV-excited white-light-emitting diodes ［J］. J. Alloys Compd.， 2018， 741： 300-306. doi: 10.1016/j.jallcom.2017.12.316http://dx.doi.org/10.1016/j.jallcom.2017.12.316

LIU Y， WANG J Y， LIU X X， et al. Energy transfer and luminescence properties of BaSr2Gd1-xMx （PO4）3（M= Dy， Tm， Eu） phosphors for warm white UV LEDs ［J］. Opt. Mater.， 2019， 95： 109194-1-8. doi: 10.1016/j.optmat.2019.109194http://dx.doi.org/10.1016/j.optmat.2019.109194

LENG Z H， YU G H， LI L L， et al. Enhanced of Tb3+ emission in KSr4（BO3）3∶Dy3+，Tb3+ phosphors via energy transfer from Dy3+ ［J］. J. Alloys Compd.， 2015， 651： 679-684. doi: 10.1016/j.jallcom.2015.08.184http://dx.doi.org/10.1016/j.jallcom.2015.08.184

DEXTER D L. A theory of sensitized luminescence in solids ［J］. J. Chem. Phys.， 1953， 21 （5）： 836-850. doi: 10.1063/1.1699044http://dx.doi.org/10.1063/1.1699044

ZHANG J S， CHEN B J， LIANG Z Q， et al. Optical transition and thermal quenching mechanism in CaSnO3∶Eu3+ phosphors ［J］. J. Alloys Compd.， 2014， 612 （5）： 204-209。. doi: 10.1016/j.jallcom.2014.05.188http://dx.doi.org/10.1016/j.jallcom.2014.05.188

BAJGIRAN K R， DARAPANENI P， MELVIN A T， et al. Effects of weak electric field on the photoluminescence behavior of Bi3+-doped YVO4-Eu3+ core-shell nanoparticles ［J］. J. Phys. Chem. C， 2019， 123 （20）： 13027-13035. doi: 10.1021/acs.jpcc.9b01872http://dx.doi.org/10.1021/acs.jpcc.9b01872

PENG X S， CHEN J， CHEN Y H， et al. Optical thermometry based fluorescence intensity ratio in Y2Mg2Al2Si2O12∶Bi3+，Eu3+ phosphors ［J］. J. Alloys Compd.， 2021， 885： 161010-1-8. doi: 10.1016/j.jallcom.2021.161010http://dx.doi.org/10.1016/j.jallcom.2021.161010

WEI R F， GUO J L， LI K J， et al. Dual-emitting SrY2O4∶Bi3+，Eu3+ phosphor for ratiometric temperature sensing ［J］. J. Lumin.， 2019， 216： 116737. doi: 10.1016/j.jlumin.2019.116737http://dx.doi.org/10.1016/j.jlumin.2019.116737

CHEN J， GUO J J， CHEN Y H， et al. Up-conversion properties of Ba3Lu2Zn5O11∶Yb3+，Er3+ phosphors for optical thermometer based on FIR technique ［J］. J. Lumin.， 2021， 238： 118294-1-8. doi: 10.1016/j.jlumin.2021.118294http://dx.doi.org/10.1016/j.jlumin.2021.118294

SOLER-CARRACEDO K， MARTÍN I R， LAHOZ F， et al. Er3+/Ho3+ codoped nanogarnet as an optical FIR based thermometer for a wide range of high and low temperatures ［J］. J. Alloys Compd.， 2020， 847： 156541-1-7. doi: 10.1016/j.jallcom.2020.156541http://dx.doi.org/10.1016/j.jallcom.2020.156541

SHEN Y Y， CHEN Y， CHEN L， et al. Dual emitting from Bi3+/Eu3+ co-activated Sr3La2Ge3O12 phosphor for optical thermometry ［J］. Opt. Mater.， 2021， 115： 111036-1-8. doi: 10.1016/j.optmat.2021.111036http://dx.doi.org/10.1016/j.optmat.2021.111036

JIA M C， SUN Z， XU H Y， et al. An ultrasensitive luminescent nanothermometer in the first biological window based on phonon-assisted thermal enhancing and thermal quenching ［J］. J. Mater. Chem. C， 2020， 8 （44）： 15603-15608. doi: 10.1039/d0tc04082ghttp://dx.doi.org/10.1039/d0tc04082g

JIA M C， SUN Z， ZHANG M X， et al. What determines the performance of lanthanide-based ratiometric nanothermometers？［J］. Nanoscale， 2020， 12 （40）： 20776-20785. doi: 10.1039/d0nr05035khttp://dx.doi.org/10.1039/d0nr05035k

WEI X T， ZHAO J B， CHEN Y H， et al. Quantum cutting downconversion by cooperative energy transfer from Bi3+ to Yb3+ in Y2O3 phosphor ［J］. Chin. Phys. B， 2010， 19 （7）： 077804-1-5. doi: 10.1088/1674-1056/19/7/077804http://dx.doi.org/10.1088/1674-1056/19/7/077804

JIN Y H， HU Y H， WU H Y， et al. A deep red phosphor Li2MgTiO4∶Mn4+ exhibiting abnormal emission： potential application as color converter for warm w-LEDs ［J］. Chem. Eng. J.， 2016， 288： 596-607. doi: 10.1016/j.cej.2015.12.027http://dx.doi.org/10.1016/j.cej.2015.12.027

MARCINIAK L， TREJGIS K. Luminescence lifetime thermometry with Mn3+-Mn4+ co-doped nanocrystals ［J］. J. Mater. Chem. C， 2018， 6 （26）： 7092-7100. doi: 10.1039/c8tc01981ahttp://dx.doi.org/10.1039/c8tc01981a

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