Preparation and Temperature Sensing Properties of Bi3+, Eu3+ Co-doped Double Perovskite Gd2ZnTiO6 Phosphor

WEN Yinuo; CHEN Yanling; FU Jie; LIN Jianhua; ZHOU Liuyan; LI Jie; HAN Mingxiao; CHEN Shuyang; DENG Degang; CHEN Liang

doi:10.37188/CJL.20220341

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Preparation and Temperature Sensing Properties of Bi³⁺, Eu³⁺ Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor

Synthesis and Properties of Materials | 更新时间：2023-05-10

- Preparation and Temperature Sensing Properties of Bi³⁺, Eu³⁺ Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 4, Pages: 615-626(2023)
- 作者机构：
  
  中国计量大学光电材料与器件研究所，浙江杭州　310018
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(52172164);the Fundamental Research Funds for the Provincial Universities of Zhejiang(2020YW21;2020YW23;2019YW03;2020YW31)
- DOI：10.37188/CJL.20220341
  CLC： O482.31
- Published：05 April 2023，
  
  Received：27 September 2022，
  
  Revised：16 October 2022，
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温一诺,陈彦伶,付杰等.Bi³⁺、Eu³⁺共掺双钙钛矿Gd₂ZnTiO₆荧光粉制备及其温度传感性能[J].发光学报,2023,44(04):615-626.

WEN Yinuo,CHEN Yanling,FU Jie,et al.Preparation and Temperature Sensing Properties of Bi³⁺, Eu³⁺ Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor[J].Chinese Journal of Luminescence,2023,44(04):615-626.
温一诺,陈彦伶,付杰等.Bi³⁺、Eu³⁺共掺双钙钛矿Gd₂ZnTiO₆荧光粉制备及其温度传感性能[J].发光学报,2023,44(04):615-626. DOI： 10.37188/CJL.20220341.

WEN Yinuo,CHEN Yanling,FU Jie,et al.Preparation and Temperature Sensing Properties of Bi³⁺, Eu³⁺ Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor[J].Chinese Journal of Luminescence,2023,44(04):615-626. DOI： 10.37188/CJL.20220341.

摘要

采用高温固相法制备了一系列具有双发射中心的Gd

2 （1-

x-y

）

ZnTiO

∶

，

荧光粉。采用X射线衍射、扫描电子显微镜、荧光光谱、寿命衰减曲线和变温发射光谱等方法，系统地研究了该材料的结构、发光性能和温度传感特性。在Gd

ZnTiO

∶Bi

，Eu

荧光粉中，Bi

和Eu

离子占据了Gd

离子的位置。在紫外激发下，Eu

的激发光谱和Bi

的发射光谱存在光谱重叠，表明从Bi

到Eu

可能存在能量传递。通过荧光强度比技术探究了Bi

蓝光发射与Eu

红光发射的不同温度响应特性。在293~473 K温度范围内，测得Gd

ZnTiO

∶Bi

，Eu

荧光粉的最大相对温度灵敏度为1.133%·K

-1

，最大绝对灵敏度为0.73 %·K

-1

。因此，Gd

ZnTiO

∶Bi

，Eu

荧光粉是一种有潜力的非接触式光学测温材料。

Abstract

A series of Gd

2 （1

-x-y

）

ZnTiO

∶

，

phosphors with dual emission centers were prepared by high-temperature solid phase method. The structure， luminescence properties and temperature sensing characteristics of the material were systematically studied by X-ray diffraction， scanning electron microscopy， fluorescence spectroscopy， lifetime decay curve and variable temperature emission spectroscopy， respectively. In Gd

ZnTiO

∶Bi

，Eu

phosphor， Bi

and Eu

ions occupy Gd

ion position. Under UV excitation， the excitation spectra of Eu

and emission spectra of Bi

overlap， indicating that there may be energy transfer from Bi

to Eu

. The fluorescence intensity ratio technique was used to explore the different temperature response characteristics of Bi

blue light emission and Eu

red light emission. In the temperature range of 293-473 K， the maximum relative temperature sensitivity of Gd

ZnTiO

∶Bi

，Eu

phosphors was 1.133%·K

-1

， and the maximum absolute sensitivity value was 0.73%·K

-1

， respectively. Therefore， Gd

ZnTiO

∶Bi

，Eu

phosphor is a potential non-contact optical temperature measurement material.

关键词

Gd2ZnTiO6∶Bi3+，Eu3+双钙钛矿荧光能量传递光学测温荧光强度比

Keywords

Gd2ZnTiO6∶Bi3+，Eu3+double perovskitefluorescence energy transferoptical thermometryfluorescence intensity ratio

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