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中国计量大学 光电材料与器件研究所, 浙江 杭州 310018
Received:27 September 2022,
Revised:16 October 2022,
Published:05 April 2023
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温一诺,陈彦伶,付杰等.Bi3+、Eu3+共掺双钙钛矿Gd2ZnTiO6荧光粉制备及其温度传感性能[J].发光学报,2023,44(04):615-626.
WEN Yinuo,CHEN Yanling,FU Jie,et al.Preparation and Temperature Sensing Properties of Bi3+, Eu3+ Co-doped Double Perovskite Gd2ZnTiO6 Phosphor[J].Chinese Journal of Luminescence,2023,44(04):615-626.
温一诺,陈彦伶,付杰等.Bi3+、Eu3+共掺双钙钛矿Gd2ZnTiO6荧光粉制备及其温度传感性能[J].发光学报,2023,44(04):615-626. DOI: 10.37188/CJL.20220341.
WEN Yinuo,CHEN Yanling,FU Jie,et al.Preparation and Temperature Sensing Properties of Bi3+, Eu3+ Co-doped Double Perovskite Gd2ZnTiO6 Phosphor[J].Chinese Journal of Luminescence,2023,44(04):615-626. DOI: 10.37188/CJL.20220341.
采用高温固相法制备了一系列具有双发射中心的Gd
2 (1-
x-y
)
ZnTiO
6
∶
x
Bi
3+
,
y
Eu
3+
荧光粉。采用X射线衍射、扫描电子显微镜、荧光光谱、寿命衰减曲线和变温发射光谱等方法,系统地研究了该材料的结构、发光性能和温度传感特性。在Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
荧光粉中,Bi
3+
和Eu
3+
离子占据了Gd
3+
离子的位置。在紫外激发下,Eu
3+
的激发光谱和Bi
3+
的发射光谱存在光谱重叠,表明从Bi
3+
到Eu
3+
可能存在能量传递。通过荧光强度比技术探究了Bi
3+
蓝光发射与Eu
3+
红光发射的不同温度响应特性。在293~473 K温度范围内,测得Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
荧光粉的最大相对温度灵敏度为1.133%·K
-1
,最大绝对灵敏度为0.73 %·K
-1
。因此,Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
荧光粉是一种有潜力的非接触式光学测温材料。
A series of Gd
2 (1
-x-y
)
ZnTiO
6
∶
x
Bi
3+
,
y
Eu
3+
phosphors with dual emission centers were prepared by high-temperature solid phase method. The structure, luminescence properties and temperature sensing characteristics of the material were systematically studied by X-ray diffraction, scanning electron microscopy, fluorescence spectroscopy, lifetime decay curve and variable temperature emission spectroscopy, respectively. In Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
phosphor, Bi
3+
and Eu
3+
ions occupy Gd
3+
ion position. Under UV excitation, the excitation spectra of Eu
3+
and emission spectra of Bi
3+
overlap, indicating that there may be energy transfer from Bi
3+
to Eu
3+
. The fluorescence intensity ratio technique was used to explore the different temperature response characteristics of Bi
3+
blue light emission and Eu
3+
red light emission. In the temperature range of 293-473 K, the maximum relative temperature sensitivity of Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
phosphors was 1.133%·K
-1
, and the maximum absolute sensitivity value was 0.73%·K
-1
, respectively. Therefore, Gd
2
ZnTiO
6
∶Bi
3+
,Eu
3+
phosphor is a potential non-contact optical temperature measurement material.
FUJIMOTO D , AKIBA K Y , NAKAMURA N . Isolation and characterization of a fluorescent material in bovine achilles tendon collagen [J]. Biochem. Biophys. Res. Commun. , 1977 , 76 ( 4 ): 1124 - 1129 . doi: 10.1016/0006-291X(77)90972-X http://dx.doi.org/10.1016/0006-291X(77)90972-X
PETORAL R M , SÖDERLIND F , KLASSON A , et al . Synthesis and characterization of Tb 3+ -doped Gd 2 O 3 nanocrystals: a bifunctional material with combined fluorescent labeling and MRI contrast agent properties [J]. J. Phys. Chem. C , 2009 , 113 ( 17 ): 6913 - 6920 . doi: 10.1021/jp808708m http://dx.doi.org/10.1021/jp808708m
DE SOUZA SIERRA M M , DONARD O F X , LAMOTTE M . Spectral identification and behaviour of dissolved organic fluorescent material during estuarine mixing processes [J]. Mar. Chem. , 2097 , 58 ( 1-2 ): 51 - 58 .
DAI W B , HU J , LIU G , et al . Thermometer of stable SrAl 2 Si 2 O 8 ∶Ce 3+ ,Tb 3+ based on synergistic luminescence [J]. J. Lumin. , 2020 , 217 : 116807-1 - 7 . doi: 10.1016/j.jlumin.2019.116807 http://dx.doi.org/10.1016/j.jlumin.2019.116807
张娜 , 李阳 , 尹延如 , 等 . Dy 3+ 掺杂Lu 2 O 3 和Y 2 O 3 单晶光纤下转换荧光测温性能 [J]. 发光学报 , 2022 , 43 ( 2 ): 182 - 191 . doi: 10.37188/cjl.20210345 http://dx.doi.org/10.37188/cjl.20210345
ZHANG N , LI Y , YIN Y R , et al . Down-conversion luminescence performance of Dy 3+ doped Lu 2 O 3 and Y 2 O 3 single crystal fibers for temperature sensing [J]. Chin. J. Lumin. , 2022 , 43 ( 2 ): 182 - 191 . (in Chinese) . doi: 10.37188/cjl.20210345 http://dx.doi.org/10.37188/cjl.20210345
LAVIGNE M B . Differences in stem respiration responses to temperature between balsam fir trees in thinned and unthinned stands [J]. Tree Physiol. , 1987 , 3 ( 3 ): 225 - 233 . doi: 10.1093/treephys/3.3.225 http://dx.doi.org/10.1093/treephys/3.3.225
COUPEAUD A , DEMYK K , MENY C , et al . Low-temperature FIR and submillimetre mass absorption coefficient of interstellar silicate dust analogues [J]. Astron. Astrophys. , 2011 , 535 : A124 - 1 - 15 . doi: 10.1051/0004-6361/201116945 http://dx.doi.org/10.1051/0004-6361/201116945
ZHENG Z G , ZHANG J F , LIU X Y , et al . Luminescence and self-referenced optical temperature sensing performance in Ca 2 YZr 2 Al 3 O 12 ∶Bi 3+ , Eu 3+ phosphors [J]. Ceram. Int. , 2020 , 46 ( 5 ): 6154 - 6159 . doi: 10.1016/j.ceramint.2019.11.081 http://dx.doi.org/10.1016/j.ceramint.2019.11.081
XU F , ZHENG B , XIA H P , et al . Ratiometric temperature sensing behavior of dual-emitting Ce 3+ /Tb 3+ co-doped Na 5 Y 9 F 32 single crystal with high relative sensitivity [J]. J. Alloys Compd. , 2021 , 873 ( 25 ): 159790-1 - 11 . doi: 10.1016/j.jallcom.2021.159790 http://dx.doi.org/10.1016/j.jallcom.2021.159790
ZHAO J T , SUN X Y , WANG Z Q . Ce 3+ /Eu 2+ doped SrSc 2 O 4 phosphors: synthesis, luminescence and energy transfer from Ce 3+ to Eu 2+ [J]. Chem. Phys. Lett. , 2018 , 691 : 68 - 72 . doi: 10.1016/j.cplett.2017.10.062 http://dx.doi.org/10.1016/j.cplett.2017.10.062
ZHANG X Z , ZHU Z P , GUO Z Y , et al . A ratiometric optical thermometer with high sensitivity and superior signal discriminability based on Na 3 Sc 2 P 3 O 12 ∶Eu 2+ , Mn 2+ thermochromic phosphor [J]. Chem. Eng. J. , 2019 , 365 : 413 - 422 . doi: 10.1016/j.cej.2018.09.075 http://dx.doi.org/10.1016/j.cej.2018.09.075
CHEN D Q , WANG Z Y , ZHOU Y , et al . Tb 3+ /Eu 3+ ∶YF 3 nanophase embedded glass ceramics: structural characterization, tunable luminescence and temperature sensing behavior [J]. J. Alloys Compd. , 2015 , 646 : 339 - 344 . doi: 10.1016/j.jallcom.2015.06.030 http://dx.doi.org/10.1016/j.jallcom.2015.06.030
FU J P , PANG R , JIANG L H , et al . A novel dichromic self-referencing optical probe SrO∶Bi 3+ ,Eu 3+ for temperature spatially and temporally imaging [J]. Dalton Trans. , 2016 , 45 ( 34 ): 13317 - 13323 . doi: 10.1039/c6dt01552b http://dx.doi.org/10.1039/c6dt01552b
WANG Z L , LIANG H B , GONG M L , et al . Novel red phosphor of Bi 3+ , Sm 3+ co-activated NaEu (MoO 4 ) 2 [J]. Opt. Mater. , 2007 , 29 ( 7 ): 896 - 900 . doi: 10.1016/j.optmat.2005.12.010 http://dx.doi.org/10.1016/j.optmat.2005.12.010
LUWANG M N , NINGTHOUJAM R S , SRIVASTAVA S K , et al . Disappearance and recovery of luminescence in Bi 3+ , Eu 3+ codoped YPO 4 nanoparticles due to the presence of water molecules up to 800 ℃ [J]. J. Am. Chem. Soc. , 2011 , 133 ( 9 ): 2998 - 3004 . doi: 10.1021/ja1092437 http://dx.doi.org/10.1021/ja1092437
DAS N , NATH M A , THAKUR G S , et al . Monoclinically distorted perovskites, A 2 ZnTiO 6 ( A = Pr, Gd): rietveld refinement, and dielectric studies [J]. J. Solid State Chem. , 2015 , 229 : 97 - 102 . doi: 10.1016/j.jssc.2015.05.003 http://dx.doi.org/10.1016/j.jssc.2015.05.003
FU A J , GUAN A X , GAO F F , et al . A novel double perovskite La 2 ZnTiO 6 ∶Eu 3+ red phosphor for solid-state lighting: synthesis and optimum luminescence [J]. Opt. Laser Technol. , 2017 , 96 : 43 - 49 . doi: 10.1016/j.optlastec.2017.04.025 http://dx.doi.org/10.1016/j.optlastec.2017.04.025
潘金泉 , 吴启运 , 杨汝军 , 等 . 低温制备Mn 4+ 掺杂Gd 2 ZnTiO 6 红色荧光粉及其发光性能研究 [J]. 中国稀土学报 , 2021 , 39 ( 6 ): 881 - 889 .
PAN J Q , WU Q Y , YANG R J , et al . Low-temperature preparation and luminescence properties of Mn 4+ doped Gd 2 ZnTiO 6 red phosphor [J]. J. Chin. Soc. Rare Earths , 2021 , 39 ( 6 ): 881 - 889 . (in Chinese)
KIM D R , PARK S W , MOON B K , et al . The role of Yb 3+ concentrations on Er 3+ doped SrLaMgTaO 6 double perovskite phosphors [J]. RSC Adv. , 2017 , 7 ( 3 ): 1464 - 1470 . doi: 10.1039/c6ra24808j http://dx.doi.org/10.1039/c6ra24808j
VERMA B , BAGHEL R N , BISEN D P , et al . A. Structural characterization and effects of Dy concentration on luminescent properties of BaMgSiO 4 phosphors [J]. J. Alloys Compd. , 2019 , 805 : 663 - 672 . doi: 10.1016/j.jallcom.2019.07.077 http://dx.doi.org/10.1016/j.jallcom.2019.07.077
ZHANG J , JIN C . Electronic structure, upconversion luminescence and optical temperature sensing behavior of Yb 3+ -Er 3+ /Ho 3+ doped NaLaMgWO 6 [J]. J. Alloys Compd. , 2019 , 783 : 84 - 94 . doi: 10.1016/j.jallcom.2018.12.281 http://dx.doi.org/10.1016/j.jallcom.2018.12.281
WOOD D L , TAUC J . Weak absorption tails in amorphous semiconductors [J]. Phys. Rev. B , 1972 , 5 ( 8 ): 3144 - 3151 . doi: 10.1103/physrevb.5.3144 http://dx.doi.org/10.1103/physrevb.5.3144
MORALES A E , MORA E S , PAL U . Use of diffuse reflectance spectroscopy for optical characterization of un-supported nanostructures [J]. Rev. Mexic. Fís. S , 2007 , 53 ( 5 ): 18 - 22 .
SETLUR A A , SRIVASTAVA A M . The nature of Bi 3+ luminescence in garnet hosts [J]. Opt. Mater. , 2006 , 29 ( 4 ): 410 - 415 . doi: 10.1016/j.optmat.2005.09.076 http://dx.doi.org/10.1016/j.optmat.2005.09.076
RIBEIRO S J L , DAHMOUCHE K , RIBEIRO C A , et al . Study of hybrid silica-polyethyleneglycol xerogels by Eu 3+ luminescence spectroscopy [J]. J. Sol⁃Gel Sci. Technol. , 1998 , 13 ( 1-3 ): 427 - 432 . doi: 10.1023/a:1008673211834 http://dx.doi.org/10.1023/a:1008673211834
CHEN X Y , ZHENG Z G , TENG L M , et al . Self-calibrated optical thermometer based on luminescence from SrLu 2 O 4 ∶ Bi 3+ , Eu 3+ phosphors [J]. RSC Adv. , 2018 , 8 ( 62 ): 35422 - 35428 . doi: 10.1039/c8ra06358c http://dx.doi.org/10.1039/c8ra06358c
FU J , LIU F W , ZHOU L Y , et al . Dual-mode optical thermometry based on Bi 3+ /Eu 3+ co-activated BaGd 2 O 4 phosphor with high sensitivity and signal discriminability [J]. Ceram. Int. , 2021 , 47 ( 21 ): 30221 - 30233 . doi: 10.1016/j.ceramint.2021.07.202 http://dx.doi.org/10.1016/j.ceramint.2021.07.202
邓超 , 林利添 , 汤利 , 等 . Al 3+ 掺杂ScVO 4 ∶Eu 3+ , Bi 3+ 荧光粉的制备及发光性质 [J]. 发光学报 , 2015 , 36 ( 11 ): 1246 - 1251 . doi: 10.3788/fgxb20153611.1246 http://dx.doi.org/10.3788/fgxb20153611.1246
DENG C , LIN L T , TANG L , et al . Synthesis and luminescence of ScVO 4 ∶Eu 3+ , Bi 3+ ,Al 3+ phosphors [J]. Chin. J. Lumin. , 2015 , 36 ( 11 ): 1246 - 1251 . (in Chinese) . doi: 10.3788/fgxb20153611.1246 http://dx.doi.org/10.3788/fgxb20153611.1246
MCCAMY C S . Correlated color temperature as an explicit function of chromaticity coordinates [J]. Color Res. Appl. , 1992 , 17 ( 2 ): 142 - 144 . doi: 10.1002/col.5080170211 http://dx.doi.org/10.1002/col.5080170211
CHEN Y H , CHEN J , TONG Y , et al . Y 4 GeO 8 ∶Er 3+ ,Yb 3+ up-conversion phosphors for optical temperature sensor based on FIR technique [J]. J. Rare Earths , 2021 , 39 ( 12 ): 1512 - 1519 . doi: 10.1016/j.jre.2021.06.007 http://dx.doi.org/10.1016/j.jre.2021.06.007
TIAN Y , CHEN B J , HUA R N , et al . Optical transition, electron-phonon coupling and fluorescent quenching of La 2 (MoO 4 ) 3 ∶Eu 3+ phosphor [J]. J. Appl. Phys. , 2011 , 109 ( 5 ): 053511-1 - 6 . doi: 10.1063/1.3551584 http://dx.doi.org/10.1063/1.3551584
CHEN W P , CAO J K , HU F F , et al . Highly efficient Na 5 Gd 9 F 32 ∶Tb 3+ glass ceramic as nanocomposite scintillator for X-ray imaging [J]. Opt. Mater. Express , 2018 , 8 ( 1 ): 41 - 49 . doi: 10.1364/ome.8.000041 http://dx.doi.org/10.1364/ome.8.000041
DENG H J , GAO Z W , XUE N , et al . A novel Eu 3+ -doped garnet-type tellurate red-emitting phosphor with high thermal stability and color purity [J]. J. Lumin. , 2017 , 192 : 684 - 689 . doi: 10.1016/j.jlumin.2017.07.063 http://dx.doi.org/10.1016/j.jlumin.2017.07.063
ZOU A L , SUN S X , YU J J , et al . Luminescence and energy transfer mechanism of KZnPO 4 ∶Dy 3+ , Eu 3+ [J]. J. Mater. Sci. Mater. Electron. , 2019 , 30 ( 10 ): 9155 - 9162 . doi: 10.1007/s10854-019-01244-w http://dx.doi.org/10.1007/s10854-019-01244-w
GUO H , HUANG X Y , ZENG Y J . Synthesis and photoluminescence properties of novel highly thermal-stable red-emitting Na 3 Sc 2 (PO 4 ) 3 ∶Eu 3+ phosphors for UV-excited white-light-emitting diodes [J]. J. Alloys Compd. , 2018 , 741 : 300 - 306 . doi: 10.1016/j.jallcom.2017.12.316 http://dx.doi.org/10.1016/j.jallcom.2017.12.316
LIU Y , WANG J Y , LIU X X , et al . Energy transfer and luminescence properties of BaSr 2 Gd 1- x M x (PO 4 ) 3 ( M = Dy, Tm, Eu) phosphors for warm white UV LEDs [J]. Opt. Mater. , 2019 , 95 : 109194-1 - 8 . doi: 10.1016/j.optmat.2019.109194 http://dx.doi.org/10.1016/j.optmat.2019.109194
LENG Z H , YU G H , LI L L , et al . Enhanced of Tb 3+ emission in KSr 4 (BO 3 ) 3 ∶Dy 3+ ,Tb 3+ phosphors via energy transfer from Dy 3+ [J]. J. Alloys Compd. , 2015 , 651 : 679 - 684 . doi: 10.1016/j.jallcom.2015.08.184 http://dx.doi.org/10.1016/j.jallcom.2015.08.184
DEXTER D L . A theory of sensitized luminescence in solids [J]. J. Chem. Phys. , 1953 , 21 ( 5 ): 836 - 850 . doi: 10.1063/1.1699044 http://dx.doi.org/10.1063/1.1699044
ZHANG J S , CHEN B J , LIANG Z Q , et al . Optical transition and thermal quenching mechanism in CaSnO 3 ∶Eu 3+ phosphors [J]. J. Alloys Compd. , 2014 , 612 ( 5 ): 204 - 209 。. doi: 10.1016/j.jallcom.2014.05.188 http://dx.doi.org/10.1016/j.jallcom.2014.05.188
BAJGIRAN K R , DARAPANENI P , MELVIN A T , et al . Effects of weak electric field on the photoluminescence behavior of Bi 3+ -doped YVO 4 -Eu 3+ core-shell nanoparticles [J]. J. Phys. Chem. C , 2019 , 123 ( 20 ): 13027 - 13035 . doi: 10.1021/acs.jpcc.9b01872 http://dx.doi.org/10.1021/acs.jpcc.9b01872
PENG X S , CHEN J , CHEN Y H , et al . Optical thermometry based fluorescence intensity ratio in Y 2 Mg 2 Al 2 Si 2 O 12 ∶Bi 3+ ,Eu 3+ phosphors [J]. J. Alloys Compd. , 2021 , 885 : 161010-1 - 8 . doi: 10.1016/j.jallcom.2021.161010 http://dx.doi.org/10.1016/j.jallcom.2021.161010
WEI R F , GUO J L , LI K J , et al . Dual-emitting SrY 2 O 4 ∶Bi 3+ ,Eu 3+ phosphor for ratiometric temperature sensing [J]. J. Lumin. , 2019 , 216 : 116737 . doi: 10.1016/j.jlumin.2019.116737 http://dx.doi.org/10.1016/j.jlumin.2019.116737
CHEN J , GUO J J , CHEN Y H , et al . Up-conversion properties of Ba 3 Lu 2 Zn 5 O 11 ∶Yb 3+ ,Er 3+ phosphors for optical thermometer based on FIR technique [J]. J. Lumin. , 2021 , 238 : 118294-1 - 8 . doi: 10.1016/j.jlumin.2021.118294 http://dx.doi.org/10.1016/j.jlumin.2021.118294
SOLER-CARRACEDO K , MARTÍN I R , LAHOZ F , et al . Er 3+ /Ho 3+ codoped nanogarnet as an optical FIR based thermometer for a wide range of high and low temperatures [J]. J. Alloys Compd. , 2020 , 847 : 156541-1 - 7 . doi: 10.1016/j.jallcom.2020.156541 http://dx.doi.org/10.1016/j.jallcom.2020.156541
SHEN Y Y , CHEN Y , CHEN L , et al . Dual emitting from Bi 3+ /Eu 3+ co-activated Sr 3 La 2 Ge 3 O 12 phosphor for optical thermometry [J]. Opt. Mater. , 2021 , 115 : 111036-1 - 8 . doi: 10.1016/j.optmat.2021.111036 http://dx.doi.org/10.1016/j.optmat.2021.111036
JIA M C , SUN Z , XU H Y , et al . An ultrasensitive luminescent nanothermometer in the first biological window based on phonon-assisted thermal enhancing and thermal quenching [J]. J. Mater. Chem. C , 2020 , 8 ( 44 ): 15603 - 15608 . doi: 10.1039/d0tc04082g http://dx.doi.org/10.1039/d0tc04082g
JIA M C , SUN Z , ZHANG M X , et al . What determines the performance of lanthanide-based ratiometric nanothermometers? [J]. Nanoscale , 2020 , 12 ( 40 ): 20776 - 20785 . doi: 10.1039/d0nr05035k http://dx.doi.org/10.1039/d0nr05035k
WEI X T , ZHAO J B , CHEN Y H , et al . Quantum cutting downconversion by cooperative energy transfer from Bi 3+ to Yb 3+ in Y 2 O 3 phosphor [J]. Chin. Phys. B , 2010 , 19 ( 7 ): 077804-1 - 5 . doi: 10.1088/1674-1056/19/7/077804 http://dx.doi.org/10.1088/1674-1056/19/7/077804
JIN Y H , HU Y H , WU H Y , et al . A deep red phosphor Li 2 MgTiO 4 ∶Mn 4+ exhibiting abnormal emission: potential application as color converter for warm w-LEDs [J]. Chem. Eng. J. , 2016 , 288 : 596 - 607 . doi: 10.1016/j.cej.2015.12.027 http://dx.doi.org/10.1016/j.cej.2015.12.027
MARCINIAK L , TREJGIS K . Luminescence lifetime thermometry with Mn 3+ -Mn 4+ co-doped nanocrystals [J]. J. Mater. Chem. C , 2018 , 6 ( 26 ): 7092 - 7100 . doi: 10.1039/c8tc01981a http://dx.doi.org/10.1039/c8tc01981a
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