Preparation and Energy Transfer Mechanism of Single-host White-light-emitting NaLaMgWO6:Dy3+/Bi3+ Phosphor

Ming-hua WANG; Jin-sheng LIAO; Li-yun KONG; Jian-hua CHEN; Xin-yi WANG; Hao-kun YAN

doi:10.3788/fgxb20204105.0519

您当前的位置：

首页 >

文章列表页 >

Preparation and Energy Transfer Mechanism of Single-host White-light-emitting NaLaMgWO₆:Dy³⁺/Bi³⁺ Phosphor

Synthesis and Properties of Materials | 更新时间：2020-09-21

- Preparation and Energy Transfer Mechanism of Single-host White-light-emitting NaLaMgWO₆:Dy³⁺/Bi³⁺ Phosphor
- Chinese Journal of Luminescence Vol. 41, Issue 5, Pages: 519-528(2020)
- 作者机构：
  
  1.江西理工大学化学化工学院, 江西赣州 341000
  2.江西稀土功能材料科技有限公司, 江西赣州 341000
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;Major Project of Natural Science Founda
- DOI：10.3788/fgxb20204105.0519
  CLC：
扫描看全文
Ming-hua WANG, Jin-sheng LIAO, Li-yun KONG, et al. Preparation and Energy Transfer Mechanism of Single-host White-light-emitting NaLaMgWO₆:Dy³⁺/Bi³⁺ Phosphor. [J]. Chinese Journal of Luminescence 41(5):519-528(2020)
DOI：

Ming-hua WANG, Jin-sheng LIAO, Li-yun KONG, et al. Preparation and Energy Transfer Mechanism of Single-host White-light-emitting NaLaMgWO₆:Dy³⁺/Bi³⁺ Phosphor. [J]. Chinese Journal of Luminescence 41(5):519-528(2020) DOI： 10.3788/fgxb20204105.0519.

摘要

采用高温固相法制备了一系列单基质荧光粉NaLa,1-,x-y,MgWO,6,：,x,Dy,3+,/,y,Bi,3+,（,x,=0.01，0.02，0.04，0.06；,y,=0.01，0.02，0.04，0.06）。通过对Dy,3+,/Bi,3+,双掺杂浓度进行优化，Bi,3+,离子的掺杂不仅可以有效增强荧光粉的发光强度，还实现了发光颜色的可调。通过对系列NaLaMgWO,6,：,x,Dy,3+,/0.02Bi,3+,样品的荧光衰减曲线的分析可知，Dy,3+,离子浓度从1%增加到6%，Bi,3+,离子的荧光寿命逐渐减少，从而有力地证明了NaLaMgWO,6,：Bi,3+,/Dy,3+,荧光粉中存在Bi,3+,→Dy,3+,的能量传递过程。另外，通过电多极相互作用公式计算可知，Bi,3+,→Dy,3+,能量传递过程为偶极-偶极的相互作用，最优Bi,3+,/Dy,3+,掺杂样品的能量传递效率达到42.67%。在紫外光的有效激发下，通过改变Dy,3+,离子掺杂浓度，NaLaMgWO,6,：Bi,3+,/Dy,3+,荧光粉可以实现白光发射。研究证明NaLaMgWO,6,：Bi,3+,/Dy,3+,荧光粉是一种具有潜在应用前景的白光发光材料。

Abstract

In this paper, a series of single-host phosphors NaLa,1-,x-y,MgWO,6,:,x,Dy,3+,/,y,Bi,3+, (,x,=0.01, 0.02, 0.04, 0.06;,y,=0.01, 0.02, 0.04, 0.06) were prepared by high temperature solid state method. By the optimization of Dy,3+,/Bi,3+, double codoping concentration, the doping of Bi,3+, ions can not only effectively enhance the luminescence intensity of phosphors, but also achieve the tune of luminescence color. The fluorescence lifetime of Bi,3+, for NaLaMgWO,6,:,x,Dy,3+,/0.02 Bi,3+, samples gradually decreased with the increased concentration of Dy,3+, ions (1%-6%), which proves strongly the presence of energy transfer process from Bi,3+, ions to Dy,3+, ions in NaLaMgWO,6,:Bi,3+,/Dy,3+, phosphors. According to the calculation of the electric multipole interaction formula, we can know that the energy transfer process of Bi,3+,→Dy,3+, is a dipole-dipole interaction and the energy transfer efficiency of the optimal Bi,3+,/Dy,3+, doped samples was calculated to be 42.67%. Under the effective excitation of the UV-light (ultraviolet light), NaLaMgWO,6,:Bi,3+,/Dy,3+, phosphor can realize the emission of white light by changing the amount of Dy,3+, ions. The research proves that NaLaMgWO,6,:Bi,3+,/Dy,3+, phosphor is a kind of white light emitting material with potential application prospects.

关键词

铋/镝离子共掺杂高温固相能量传递NaLaMgWO6

Keywords

bismuth/dysprosium ion co-dopinghigh temperature solid stateenergy transferNaLaMgWO6

references

GAO D J, LI Y, LAI X, et al.. Fa/pication and luminescence properties of Dy3+ doped CaMoO4 powders[J].Mater. Chem. Phys., 2011, 126(1-2):391-397.

GAÂBEL F, KHLIFI M, HAMDAOUI N,et al.. Conduction mechanisms study in CaCu2.8Ni0.2Ti4O12 ceramics sintered at different temperatures[J].J. Alloys Compd., 2020, 828:154373.

LIAO J S, WANG Q, WEN H R, et al.. First observation of mutual energy transfer of Mn4+-Er3+ via different excitation in Gd2ZnTiO6:Mn4+/Er3+ phosphors[J].J. Mater. Chem. C, 2017, 5(35):9098-9105.

WANG Q, LIAO J S, KONG L Y, et al.. Luminescence properties of a non-rare-earth doped oxyfluoride LiAl4O6F:Mn4+ red phosphor for solid-state lighting[J].J. Alloys Compd., 2019, 772:499-506.

SHANG M M, LI C X, LIN J. How to produce white light in a single-phase host?[J].Chem. Soc. Rev., 2014, 43(5):1372-1386.

ZHONG J P, LIANG H B, HAN B, et al.. NaGd(PO3)4:Tb3+-a new promising green phosphor for PDPs application[J].Chem. Phys. Lett., 2008, 453(4-6):192-196.

LIAO J S, KONG L Y, WANG Q, et al.. Sol-gel preparation and near-infrared emission properties of Yb3+ sensitized by Mn4+ in double-perovskite La2ZnTiO6[J].Opt. Mater., 2018, 84:82-88.

LAGATSKY A A, ANTIPOV O L, SIBBETT W. Broadly tunable femtosecond Tm:Lu2O3 ceramic laser operating around 2070 nm[J].Opt. Express, 2012, 20(17):19349-19354.

WANG Q, LIAO J S, GUO J F, et al.. Upconversion emission and temperature sensing behavior of LuF3:Yb3+, Er3+ microcrystals prepared by one-step hydrothermal synthesis[J].Chin. J. Inorg. Chem., 2018, 34(3):579-588.

LIAO J S, WANG Q, KONG L Y, et al.. Effect of Yb3+ concentration on tunable upconversion luminescence and optically temperature sensing behavior in Gd2TiO5:Yb3+/Er3+phosphors[J].Opt. Mater., 2018, 75:841-849.

ZHAI Y Q, HAN Y, ZHANG W, et al.. Influence of doping alkali metal ions on the structure and luminescent properties of microwave synthesized CaMoO4:Dy3+ phosphors[J].J. Alloys Compd., 2016, 688:241-247.

蒲勇, 赵聪, 敬小龙, 等. CaGd2(MoO4)4:Eu3+, Bi3+红色荧光粉的制备及发光性能[J].发光学报, 2018, 39(8):1046-1050.

PU Y, ZHAO C, JING X L, et al.. Synthesis and luminescence properties of CaGd2(MoO4)4:Eu3+, Bi3+ red phosphors[J].Chin. J. Lumin., 2018, 39(8):1046-1050. (in Chinese)

MAHALLEY B N, PODE R B, GUPTA P K. Synthesis of GdVO4:Bi, Eu red phosphor by combustion process[J].Phys. Status Solid A, 2000, 177(1):293-302.

LI K, FAN J, SHANG M M, et al.. Sr2Y8(SiO4)6O2:Bi3+/Eu3+:a single-component white-emitting phosphor via energy transfer for UV w-LEDs[J].J. Mater. Chem. C, 2015, 3(38):9989-9998.

SHAO J Y, YAN J H, LI X G, et al.. Novel fluorescent label based on YVO4:Bi3+, Eu3+ for latent fingerprint detection[J].Dyes Pigm., 2019, 160:555-562.

丁益, 张波, 张奇才, 等.水热法制备PEG-400辅助下的Bi3+敏化NaLa(WO4)2:Eu3+荧光粉及其发光性能研究[J].人工晶体学报, 2018, 47(4):784-789.

DING Y, ZHANG B, ZHANG Q C, et al.. Preparation and luminescence properties of Bi3+ sensitized NaLa(WO4)2:Eu3+ phosphors by hydrothermal method assisted by PEG-400[J].J. Synth. Cryst., 2018, 47(4):784-789. (in Chinese)

蒲勇, 刘碧桃, 朱达川, 等.溶剂热-溶胶凝胶两步法合成(Y, Gd)(P, V)O4:Eu3+, Bi3+荧光粉及其发光研究[J].稀有金属材料与工程, 2015, 44(10):2529-2533.

PU Y, LIU B T, ZHU D C, et al.. Solvent thermal-sol gel synthesis and luminescence properties of (Y, Gd)(P, V)O4:Eu3+, Bi3+ phosphors[J].Rare Metal Mater. Eng., 2018, 44(10):2529-2533. (in Chinese)

ZHU R, ZENG Y S, LIANG S C, et al.. Regulated morphology of ScF3:Eu3+, Bi3+ microcrystals:microwave-assisted hydrothermal synthesis, structure and luminescence properties[J].J. Solid State Chem., 2019, 269:447-453.

ZHANG L H, ZHONG H Y, LI X P, et al.. Solid state reaction synthesis and photoluminescence properties of Dy3+ doped NaGd(MoO4)2 phosphor[J].Ceram. Int., 2012, 38(6):4737-4743.

KIMANI M M, KOLIS J W. Synthesis and luminescence studies of a novel white Dy:K3Y(VO4)2 and yellow emitting phosphor Dy, Bi:K3Y(VO4)2 with potential application in white light emitting diodes[J].J. Lumin., 2014, 145:492-497.

钟诚, 吴云, 李涛, 等.水热法制备的NaEu(MoO4)2-x(WO4)x固溶体微晶及其发光特性[J].发光学报, 2014, 35(9):1076-1081.

ZHONG C, WU Y, LI T, et al.. Hydrothermal synthesis and luminescent properties of NaEu(MoO4)2-x(WO4)x solid solution microcrystallines[J].Chin. J. Lumin., 2014, 35(9):1076-1081. (in Chinese)

钟诚, 吴云, 李涛, 等.水热制备Sr(MoO4)x(WO4)1-x固溶体微晶及其发光性能[J].发光学报, 2014, 35(6):666-671.

ZHONG C, WU Y, LI T, et al.. Hydrothermal synthesis of Sr(MoO4)x(WO4)1-x microcrystallines and luminescent properties[J].Chin. J. Lumin., 2014, 35(6):666-671. (in Chinese)

HAN B, LIU B B, DAI Y Z, et al.. Alkali metal ion substitution induced luminescence enhancement of NaLaMgWO6:Eu3+ red phosphor for white light-emitting diodes[J].Ceram. Int., 2019, 45(3):3419-3424.

侯京山.氧化物基白光LED荧光粉的设计与合成[D].上海: 东华大学, 2014.

HOU J S. Design and Synthesis Oxide-based Phosphors for White Light-emitting Diodes Application[D]. Shanghai: Donghua University, 2014. (in Chinese)

DI J Q, SAI Q L, SUN X H, et al.. Synthesis and luminescent behavior of Dy:Y3Ga5O12 phosphor for UV induced white LEDs[J].Optik, 2017, 144:86-90.

ZHANG W, SHEN H, HU X L, et al.. Solid-state synthesis, structure and spectroscopic analysis of Dy:CaYAl3O7 phosphors[J].J. Alloys Compd., 2019, 781:255-260.

SHANNON R D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J].Acta Crystallogr. Sect. A, 1976, 32(5):751-767.

HAQUE M, KIM D K. Luminescent properties of Eu3+ activated MLa2(MoO4)4 based (M=Ba, Sr and Ca) novel red-emitting phosphors[J].Mater. Lett., 2009, 63(9-10):793-796.

HAN B, DAI Y Z, ZHANG J, et al.. Luminescence properties of a novel yellow-emitting phosphor NaLaMgWO6:Dy3+[J].Mater. Lett., 2017, 204:145-148.

YU M, LIN J, WANG Z, et al.. Fa/pication, patterning, and optical properties of nanocrystalline YVO4:A(A=Eu3+, Dy3+, Sm3+, Er3+) phosphor films via sol-gel soft lithography[J].Chem. Mater., 2002, 14(5):2224-2231.

YANG B B, XU J Y, ZHANG Y, et al.. A yellow emitting phosphor Dy:Bi 4Si3O12crystal for LED application[J].Mater. Lett., 2014, 135:176-179.

PERUMAL R N, LOPEZ A X, SUBALAKSHMI G. Synthesis and luminescence property of Bi3+ and Dy3+ ions doped MLa2O4(M=Ba, Sr and Ca) phosphors for LEDs application[J].Optik, 2019, 179:1001-1008.

PAULOSE P I, JOSE G, THOMAS V, et al.. Sensitized fluorescence of Ce3+/Mn2+ system in phosphate glass[J].J. Phys. Chem. Solids, 2003, 64(5):841-846.

HUANG C H, CHEN T M. A novel single-composition trichromatic white-light Ca3Y(GaO)3(BO3)4:Ce3+, Mn2+, Tb3+ phosphor for UV-light emitting diodes[J].J. Phys. Chem. C, 2011, 115(5):2349-2355.

BLASSE G. Energy transfer in oxidic phosphors[J].Phys. Lett. A, 1968, 28(6):444-445.

DEXTER D L, SCHULMAN J H. Theory of concentration quenching in inorganic phosphors[J].J. Chem. Phys., 1954, 22(6):1063-1070.

REISFELD R, GREENBERG E, VELAPOLDI R, et al.. Luminescence quantum efficiency of Gd and Tb in borate glasses and the mechanism of energy transfer between them[J].J. Chem. Phys., 1972, 56(4):1698-1705.

NIE Z G, ZHANG J H, ZHANG X, et al.. Photon cascade luminescence in CaAl12O19:Pr, Cr[J].J. Solid State Chem., 2007, 180(10):2933-2941.

DEXTER D L. A theory of sensitized luminescence in solids[J].J. Chem. Phys., 1953, 21(5):836-850.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Broadband Near Infrared Emission and Energy Transfer of Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺ Garnet Phosphor

Mechanoluminescent Properties of Mixed-anion Compounds: Ba₂Gd（BO₃）₂Cl∶Ln

Color-tunable Luminescence and Temperature Sensing Behavior of Sr_0.3Ca_0.7MoO₄∶Tb³⁺, Eu³⁺ Phosphor

Electroluminescent Performances of Solution-processed Phosphorescent Organic Light-emitting Diodes Based on Cascade Energy Transfer of Ternary Blends

Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr₃Gd（BO₃）₃∶Dy³⁺/RE³⁺（RE=Tb, Eu） Crystals

Related Author

No data

Related Institution

Key Laboratory for Liquid-solid Structural Evolution and Processing of Materials （Ministry of Education）， School of Material Science and Engineering， Shandong University

College of Materials and Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials， Xiamen University

State Key Laboratory of Physical Chemistry of Solid Surfaces，Xiamen University

College of Physics and Optoelectronic Engineering， Harbin Engineering University

Institute of Aeronautical Engineering， Binzhou University

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰