Ratiometric Photon-upconversion Cryometer Based on Er<sup>3+</sup>/Tm<sup>3+</sup> Partition Doped Nanostructure

WU Han; CHEN Haoran; XIE Xiaoyu; TU Langping; LI Qiqing; KONG Xianggui; CHANG Yulei

doi:10.37188/CJL.20230073

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Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure

Cover Story | 更新时间：2023-09-06

- Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 8, Pages: 1335-1343(2023)
- 作者机构：
  
  1.中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室，吉林长春　130033
  2.中国科学院大学，北京　100049
- 作者简介：
- 基金信息：
  
  the National Key Research and Development Program of China(2021YFA0715603);The National Natural Science Foundation of China(62075217);Project of Science and Technology Agency, Jilin Province(20210101148JC;202512JC010475440;20230508104RC);The State Key Laboratory of Luminescence and Applications(SKLA⁃2019⁃02;SKLA⁃2020⁃09)
- DOI：10.37188/CJL.20230073
  CLC：
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WU Han, CHEN Haoran, XIE Xiaoyu, et al. Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure. [J]. Chinese Journal of Luminescence 44(8):1335-1343(2023)
DOI：

WU Han, CHEN Haoran, XIE Xiaoyu, et al. Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure. [J]. Chinese Journal of Luminescence 44(8):1335-1343(2023) DOI： 10.37188/CJL.20230073.

摘要

利用溶剂热法制备了六角相NaYF,4,∶20%Yb，2%Er@NaYF,4,@NaYbF,4,∶0.5%Tm@NaYF,4,多层核壳结构稀土掺杂上转换纳米粒子，研究其在低温场（10~295 K）及980 nm激发下分别来自于Er,3+,的绿色与红色以及Tm,3+,的蓝色发光的上转换发光性质。结果显示，绿光强度随温度升高呈现出先增后降的变化趋势，而蓝光强度随温度升高呈现热衰减的趋势。本工作利用发光强度比的测温方法实现了精准的温度测量，相对灵敏度可达3.2%·K,-1,。并通过改变外层发光壳层的厚度调节发光强度比，进一步应用于低温场光学防伪。

Abstract

Hexagonal phase NaYF,4,∶20%Yb，2%Er@NaYF,4,@NaYbF,4,∶0.5%Tm@NaYF,4, lanthanide-doped nano⁃particles with the core@multishell structure were synthesized by solvothermal method. The upconversion luminescence （UCL） properties of the materials at temperature from 10 K to 295 K were studied under 980 nm excitation. Green and red UCL from Er,3+, and blue UCL from Tm,3+, were observed in the visible light range. The luminescence intensity of green UCL first increased and then decreased， while the luminescence intensity of blue light showed a thermal attenuation trend with the temperature increase. The method of temperature-dependent luminescence intensity ratio （LIR） can be used in accurate temperature measurement， and the relative sensitivity is up to 3.2%·K,-1,. With various thicknesses of the outer luminescent shell， the different tendencies of LIR can be realized， which can be applied to cryogenic field anticounterfeiting.

关键词

稀土纳米粒子发光强度比测温上转换发光低温场防伪

Keywords

rare-earth nanoparticlesluminescence intensity ratio（LIR） thermometryupconversion luminescence cryogenic fieldanticounterfeiting

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University of the Chinese Academy of Sciences

State Key Laboratory of Luminescence and Applications， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences

School of Materials Science & Engineering, Beijing Institute of Technology

School of Optics and Photonics, Beijing Institute of Technology

Department of Physics, Zhejiang University

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Ratiometric Photon-upconversion Cryometer Based on Er3+/Tm3+ Partition Doped Nanostructure

DOI：10.37188/CJL.20230073

摘要

Abstract

关键词

Keywords

references

Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure