Broadband Near Infrared Emission and Energy Transfer of Ca2TbHf2Al3O12∶Ce3+,Cr3+ Garnet Phosphor

YAN Yu; SHANG Mengmeng

doi:10.37188/CJL.20230046

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Broadband Near Infrared Emission and Energy Transfer of Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺ Garnet Phosphor

Synthesis and Properties of Materials | 更新时间：2023-09-06

- Broadband Near Infrared Emission and Energy Transfer of Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺ Garnet Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 8, Pages: 1369-1379(2023)
- 作者机构：
  
  1.山东大学材料科学与工程学院，材料液固结构演变与加工教育部重点实验室，山东济南　250061
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51672265);National Natural Science Foundation of China(ZR2018JL016;ZR2021ZD10);Natural Science Foundation of Shandong Province
- DOI：10.37188/CJL.20230046
  CLC：
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YAN Yu, SHANG Mengmeng. Broadband Near Infrared Emission and Energy Transfer of Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺ Garnet Phosphor. [J]. Chinese Journal of Luminescence 44(8):1369-1379(2023)
DOI：

YAN Yu, SHANG Mengmeng. Broadband Near Infrared Emission and Energy Transfer of Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺ Garnet Phosphor. [J]. Chinese Journal of Luminescence 44(8):1369-1379(2023) DOI： 10.37188/CJL.20230046.

摘要

近红外荧光转换型发光二极管（pc⁃LED）在光谱分析、生物成像、夜视照明等领域有重要应用价值，得到了人们的广泛关注。本文采用高温固相法制备了一系列Ca,2,TbHf,2,Al,3,O,12,∶Ce,3+,，,x,Cr,3+,（CTHAO∶Ce,3+,，,x,Cr,3+,）近红外荧光材料，通过粉末XRD表征结合结构精修技术确定制备的CTHAO∶Ce,3+,，,x,Cr,3+,为纯相石榴石结构。在该样品中，Tb,3+,作为基质组成，与掺杂离子Ce,3+,共同作为Cr,3+,离子的敏化剂，三者之间存在多种能量传递效应，通过光谱及荧光寿命表征证实存在Ce,3+,→Tb,3+,、Ce,3+,→Cr,3+,、Tb,3+,→Cr,3+,的能量传递过程；重点分析了Tb,3+,向Cr,3+,的能量传递机制，以偶极⁃四极交互作用为主导，能量传递效率可达79.5%。CTHAO∶Ce,3+,，0.02Cr,3+,在100 ℃时的近红外发射强度能保持初始强度的36%，计算得到活化能为0.30 eV。将该样品与410 nm芯片相结合制成器件，在驱动电流为200 mA时，近红外最大输出功率可达7.5 mW，光电转换效率为1.2%。本工作研究了通过多重能量传递提高Cr,3+,的发光，对于设计和开发Cr,3+,激发的高效近红外发光材料有一定的指导意义。

Abstract

Broadband near infrared （NIR） phosphor-converted light-emitting diodes （pc-LEDs） have been widely concerned due to their valuable application in spectral analysis， biological imaging， night vision lighting and other fields. In this work， the novel NIR-emitting Ca,2,TbHf,2,Al,3,O,12,∶Ce,3+,，,x,Cr,3+ ,（CTHAO∶Ce,3+,，,x,Cr,3+,） phosphors were prepared by high temperature solid state method. CTHAO∶Ce,3+,，,x,Cr,3+, were confirmed to be pure phase with garnet structure by powder XRD and Rietveld refinement technology. Tb,3+,， as matrix component， can sensitize Cr,3+, ions. Co-doping Ce,3+, leads to multiple energy transfer processes， and the energy transfer fact of Ce,3+,→Tb,3+,， Ce,3+,→Cr,3+,， Tb,3+,→Cr,3+, was confirmed by the spectra and fluorescence lifetime characterization. The energy transfer mechanism from Tb,3+, to Cr,3+, is dominated by dipole-quadrupole interaction， and the energy transfer efficiency can reach 79.5%. The NIR intensity of CTHAO∶Ce,3+,，0.02Cr,3+, can maintain 36% compared with its initial intensity and the calculated activation energy is 0.30 eV. Combining CTHAO∶Ce,3+,，0.02Cr,3+ ,with a 410 nm chip， the NIR output power can reach 7.5 mW and the NIR photoelectric conversion efficiency is 1.2% when the driving current is 200 mA. In this work， the enhancement of Cr,3+, luminescence through multiple energy transfer processes has certain guiding significance for the design and development of Cr,3+, excited efficient near infrared luminescence materials.

关键词

能量传递Cr3+荧光转换型发光二极管（pc-LED）宽带近红外发射

Keywords

energy transferCr3+phosphor-converted light-emitting diode（pc-LED）broadband near infrared emission

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Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials （Ministry of Education）， School of Material Science and Engineering， Shandong University

Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

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