Broadband Near Infrared Emission and Energy Transfer of Ca2TbHf2Al3O12∶Ce3+,Cr3+ Garnet Phosphor

YAN Yu; SHANG Mengmeng

doi:10.37188/CJL.20230046

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Broadband Near Infrared Emission and Energy Transfer of Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺ Garnet Phosphor

Synthesis and Properties of Materials | 更新时间：2023-09-06

- Broadband Near Infrared Emission and Energy Transfer of Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺ Garnet Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 8, Pages: 1369-1379(2023)
- 作者机构：
  
  山东大学材料科学与工程学院，材料液固结构演变与加工教育部重点实验室，山东济南　250061
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51672265);National Natural Science Foundation of China(ZR2018JL016;ZR2021ZD10);Natural Science Foundation of Shandong Province
- DOI：10.37188/CJL.20230046
  CLC： O482.31
- Published：05 August 2023，
  
  Received：27 February 2023，
  
  Revised：16 March 2023，
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颜雨,尚蒙蒙.Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺石榴石荧光材料的宽带近红外发射与能量传递[J].发光学报,2023,44(08):1369-1379.

YAN Yu,SHANG Mengmeng.Broadband Near Infrared Emission and Energy Transfer of Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺ Garnet Phosphor[J].Chinese Journal of Luminescence,2023,44(08):1369-1379.
颜雨,尚蒙蒙.Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺石榴石荧光材料的宽带近红外发射与能量传递[J].发光学报,2023,44(08):1369-1379. DOI： 10.37188/CJL.20230046.

YAN Yu,SHANG Mengmeng.Broadband Near Infrared Emission and Energy Transfer of Ca₂TbHf₂Al₃O₁₂∶Ce³⁺,Cr³⁺ Garnet Phosphor[J].Chinese Journal of Luminescence,2023,44(08):1369-1379. DOI： 10.37188/CJL.20230046.

摘要

近红外荧光转换型发光二极管（pc⁃LED）在光谱分析、生物成像、夜视照明等领域有重要应用价值，得到了人们的广泛关注。本文采用高温固相法制备了一系列Ca

TbHf

∶Ce

，

（CTHAO∶Ce

，

）近红外荧光材料，通过粉末XRD表征结合结构精修技术确定制备的CTHAO∶Ce

，

为纯相石榴石结构。在该样品中，Tb

作为基质组成，与掺杂离子Ce

共同作为Cr

离子的敏化剂，三者之间存在多种能量传递效应，通过光谱及荧光寿命表征证实存在Ce

→Tb

、Ce

→Cr

、Tb

→Cr

的能量传递过程；重点分析了Tb

向Cr

的能量传递机制，以偶极⁃四极交互作用为主导，能量传递效率可达79.5%。CTHAO∶Ce

，0.02Cr

在100 ℃时的近红外发射强度能保持初始强度的36%，计算得到活化能为0.30 eV。将该样品与410 nm芯片相结合制成器件，在驱动电流为200 mA时，近红外最大输出功率可达7.5 mW，光电转换效率为1.2%。本工作研究了通过多重能量传递提高Cr

的发光，对于设计和开发Cr

激发的高效近红外发光材料有一定的指导意义。

Abstract

Broadband near infrared （NIR） phosphor-converted light-emitting diodes （pc-LEDs） have been widely concerned due to their valuable application in spectral analysis， biological imaging， night vision lighting and other fields. In this work， the novel NIR-emitting Ca

TbHf

∶Ce

，

（CTHAO∶Ce

，

） phosphors were prepared by high temperature solid state method. CTHAO∶Ce

，

were confirmed to be pure phase with garnet structure by powder XRD and Rietveld refinement technology. Tb

， as matrix component， can sensitize Cr

ions. Co-doping Ce

leads to multiple energy transfer processes， and the energy transfer fact of Ce

→Tb

， Ce

→Cr

， Tb

→Cr

was confirmed by the spectra and fluorescence lifetime characterization. The energy transfer mechanism from Tb

to Cr

is dominated by dipole-quadrupole interaction， and the energy transfer efficiency can reach 79.5%. The NIR intensity of CTHAO∶Ce

，0.02Cr

can maintain 36% compared with its initial intensity and the calculated activation energy is 0.30 eV. Combining CTHAO∶Ce

，0.02Cr

with a 410 nm chip， the NIR output power can reach 7.5 mW and the NIR photoelectric conversion efficiency is 1.2% when the driving current is 200 mA. In this work， the enhancement of Cr

luminescence through multiple energy transfer processes has certain guiding significance for the design and development of Cr

excited efficient near infrared luminescence materials.

关键词

能量传递Cr3+荧光转换型发光二极管（pc-LED）宽带近红外发射

Keywords

energy transferCr3+phosphor-converted light-emitting diode（pc-LED）broadband near infrared emission

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