A Novel Red Fluoride Phosphor BaTaF<sub>7</sub>∶Mn<sup>4+</sup>

KONG Junren; ZHOU Yang; ZHANG Shirui; LI Ruixin; WANG Xiaoming; JIAO Huan

doi:10.37188/CJL.20220411

您当前的位置：

首页 >

文章列表页 >

A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺

Synthesis and Properties of Materials | 更新时间：2023-10-27

- A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 6, Pages: 975-984(2023)
- 作者机构：
  
  陕西师范大学化学化工学院，陕西西安　710119
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51972203;22271180)
- DOI：10.37188/CJL.20220411
  CLC： O482.31
- Published：05 June 2023，
  
  Received：12 December 2022，
  
  Revised：22 December 2022，
扫描看全文
孔俊人,周洋,张世瑞等.一种新型氟化物红色荧光粉BaTaF₇∶Mn⁴⁺[J].发光学报,2023,44(06):975-984.

KONG Junren,ZHOU Yang,ZHANG Shirui,et al.A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺[J].Chinese Journal of Luminescence,2023,44(06):975-984.
孔俊人,周洋,张世瑞等.一种新型氟化物红色荧光粉BaTaF₇∶Mn⁴⁺[J].发光学报,2023,44(06):975-984. DOI： 10.37188/CJL.20220411.

KONG Junren,ZHOU Yang,ZHANG Shirui,et al.A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺[J].Chinese Journal of Luminescence,2023,44(06):975-984. DOI： 10.37188/CJL.20220411.

摘要

采用共沉淀方法合成了一种新型氟化物红色荧光粉BaTaF

∶Mn

，确定了BaTaF

的组成与晶体结构，研究并讨论了晶体结构与发光性能之间的关系。在紫外（UV）和蓝光激发下，BaTaF

∶Mn

荧光粉在630 nm表现出强烈的零声子线（ZPL）发射，其源于晶体结构中［MnF

］畸变八面体的

群对称环境。由YAG∶Ce

和BaTaF

∶Mn

荧光粉混合制备的暖白光LED表现出较优异的性能，表明BaTaF

∶Mn

具有成为暖白色发光二极管红色荧光粉的应用潜力。

Abstract

A novel red fluoride phosphor BaTaF

∶Mn

was synthesized

via

the conventional co-precipitation method. The structure and luminescence properties of BaTaF

∶Mn

were investigated and discussed under various conditions. The BaTaF

∶Mn

phosphor shows strong ZPL emission intensity at about 630 nm under ultraviolet （UV） and blue light excitation. It originated from the highly distorted Mn

octahedral coordination environment in the

group symmetry. A warm LED fabricated with a blend of YAG∶Ce

and the BaTaF

∶Mn

phosphor showed excellent performance， indicating BaTaF

∶Mn

potential for application as a red phosphor for warm WLEDs.

关键词

氟化物Mn4+掺杂红色荧光粉零声子线暖白色发光二极管

Keywords

fluorideMn4+ dopedred phosphorzero-phonon linewarm WLEDs

references

SCHUBERT E F， KIM J K. Solid-state light sources getting smart ［J］. Science， 2005， 308（5726）： 1274-1278. doi: 10.1126/science.1108712http://dx.doi.org/10.1126/science.1108712

IM W B， GEORGE N， KURZMAN J， et al. Efficient and color-tunable oxyfluoride solid solution phosphors for solid-state white lighting ［J］. Adv. Mater.， 2011， 23（20）： 2300-2305. doi: 10.1002/adma.201003640http://dx.doi.org/10.1002/adma.201003640

DAICHO H， IWASAKI T， ENOMOTO K， et al. A novel phosphor for glareless white light-emitting diodes ［J］. Nat. Commun.， 2012， 3： 1132-1-8. doi: 10.1038/ncomms2138http://dx.doi.org/10.1038/ncomms2138

ZHU H M， LIN C C， LUO W Q， et al. Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes ［J］. Nat. Commun.， 2014， 5： 4312-1-7. doi: 10.1038/ncomms5312http://dx.doi.org/10.1038/ncomms5312

WEI L L， LIN C C， WANG Y Y， et al. Photoluminescent evolution induced by structural transformation through thermal treating in the red narrow-band phosphor K2GeF6∶Mn4+ ［J］. ACS Appl. Mater. Interfaces， 2015， 7（20）： 10656-10659. doi: 10.1021/acsami.5b02212http://dx.doi.org/10.1021/acsami.5b02212

WEI L L， LIN C C， FANG M H， et al. A low-temperature co-precipitation approach to synthesize fluoride phosphors K2MF6∶Mn4+ （M = Ge， Si） for white LED applications ［J］. J. Mater. Chem. C， 2015， 3（8）： 1655-1660. doi: 10.1039/c4tc02551bhttp://dx.doi.org/10.1039/c4tc02551b

SONG E H， WANG J Q， YE S， et al. Room-temperature synthesis and warm-white LED applications of Mn4+ ion doped fluoroaluminate red phosphor Na3AlF6∶Mn4+ ［J］. J. Mater. Chem. C， 2016， 4（13）： 2480-2487. doi: 10.1039/c6tc00502khttp://dx.doi.org/10.1039/c6tc00502k

JIN Y， FANG M H， GRINBERG M， et al. Narrow red emission band fluoride phosphor KNaSiF6∶Mn4+ for warm white light-emitting diodes ［J］. ACS Appl. Mater. Interfaces， 2016， 8（18）： 11194-11203. doi: 10.1021/acsami.6b01905http://dx.doi.org/10.1021/acsami.6b01905

DENG T T， SONG E H， SUN J， et al. The design and preparation of the thermally stable， Mn4+ ion activated， narrow band， red emitting fluoride Na3GaF6∶Mn4+ for warm WLED applications ［J］. J. Mater. Chem. C， 2017， 5（11）： 2910-2918. doi: 10.1039/c7tc00011ahttp://dx.doi.org/10.1039/c7tc00011a

NGUYEN H D， LIU R S. Narrow-band red-emitting Mn4+-doped hexafluoride phosphors： synthesis， optoelectronic properties， and applications in white light-emitting diodes ［J］. J. Mater. Chem. C， 2016， 4（46）： 10759-10775. doi: 10.1039/c6tc03292chttp://dx.doi.org/10.1039/c6tc03292c

PIAO X， MACHIDA K I， HORIKAWA T， et al. Preparation of CaAlSiN3∶Eu2+ phosphors by the self-propagating high-temperature synthesis and their luminescent properties ［J］. Chem. Mater.， 2007， 19（18）： 4592-4599. doi: 10.1021/cm070623chttp://dx.doi.org/10.1021/cm070623c

UHEDA K， HIROSAKI N， YAMAMOTO Y， et al. Luminescence properties of a red phosphor， CaAlSiN3∶Eu2+， for white light-emitting diodes ［J］. Electrochem. Solid⁃State Lett.， 2006， 9（4）： H22-H25. doi: 10.1149/1.2173192http://dx.doi.org/10.1149/1.2173192

WU Z Y， LI C， ZHANG F， et al. High-performance ultra-narrow-band green-emitting phosphor LaMgAl11O19∶Mn2+ for wide color-gamut WLED backlight displays ［J］. J. Mater. Chem. C， 2022， 10（19）： 7443-7448. doi: 10.1039/d2tc00850ehttp://dx.doi.org/10.1039/d2tc00850e

LI C， WANG X M， CHI F F， et al. A narrow-band blue emitting phosphor Ca8Mg7Si9N22∶Eu2+ for pc-LEDs ［J］. J Mater. Chem. C， 2019， 7（13）： 3730-3734. doi: 10.1039/c9tc00855ahttp://dx.doi.org/10.1039/c9tc00855a

LI C， ZHENG H W， WEI H W， et al. Narrow-band blue emitting nitridomagnesosilicate phosphor Sr8Mg7Si9N22∶Eu2+ for phosphor-converted LEDs ［J］. Chem. Commun.， 2018， 54（82）： 11598-11601. doi: 10.1039/c8cc07218chttp://dx.doi.org/10.1039/c8cc07218c

ZHOU Q， ZHOU Y Y， LIU Y， et al. A new and efficient red phosphor for solid-state lighting： Cs2TiF6∶Mn4+ ［J］. J. Mater. Chem. C， 2015， 3（37）： 9615-9619. doi: 10.1039/c5tc02290hhttp://dx.doi.org/10.1039/c5tc02290h

TANG F， SU Z C， YE H G， et al. A set of manganese ion activated fluoride phosphors （A2BF6∶Mn4+， A = K， Na， B = Si， Ge， Ti）： synthesis below 0 ℃ and efficient room-temperature photoluminescence ［J］. J. Mater. Chem. C， 2016， 4（40）： 9561-9568. doi: 10.1039/c6tc02737ghttp://dx.doi.org/10.1039/c6tc02737g

WU W L， FANG M H， ZHOU W L， et al. High color rendering index of Rb2GeF6∶Mn4+ for light-emitting diodes ［J］. Chem. Mater.， 2017， 29（3）： 935-939.

ZHOU Q， ZHOU Y Y， LIU Y， et al. A new red phosphor BaGeF6∶Mn4+： hydrothermal synthesis， photo-luminescence properties， and its application in warm white LED devices ［J］. J. Mater. Chem. C， 2015， 3（13）： 3055-3059. doi: 10.1039/c4tc02956ahttp://dx.doi.org/10.1039/c4tc02956a

ZHONG J S， CHEN D Q， WANG X， et al. Synthesis and optical performance of a new red-emitting ZnTiF6·6H2O∶Mn4+ phosphor for warm white-light-emitting diodes ［J］. J. Alloys Compd.， 2016， 662： 232-239. doi: 10.1016/j.jallcom.2015.12.075http://dx.doi.org/10.1016/j.jallcom.2015.12.075

HOSHINO R， ADACHI S. Optical spectroscopy and degradation behavior of ZnGeF6·6H2O∶Mn4+ red-emitting phosphor ［J］. J. Lumin.， 2015， 162： 63-71. doi: 10.1016/j.jlumin.2015.02.011http://dx.doi.org/10.1016/j.jlumin.2015.02.011

DENG T T， SONG E H， ZHOU Y Y， et al. Stable narrowband red phosphor K3GaF6∶Mn4+ derived from hydrous K2GaF5（H2O） and K2MnF6 ［J］. J. Mater. Chem. C， 2017， 5（37）： 9588-9596. doi: 10.1039/C7TC03116Ehttp://dx.doi.org/10.1039/C7TC03116E

SONG E H， WANG J Q， SHI J H， et al. Highly efficient and thermally stable K3AlF6∶Mn4+ as a red phosphor for ultra-high-performance warm white light-emitting diodes ［J］. ACS Appl. Mater. Interfaces， 2017， 9（10）： 8805-8812. doi: 10.1021/acsami.7b00749http://dx.doi.org/10.1021/acsami.7b00749

LIN H， HU T， HUANG Q M， et al. Non-rare-earth K2XF7∶Mn4+ （X = Ta， Nb）： a highly-efficient narrow-band red phosphor enabling the application in wide-color-gamut LCD ［J］. Laser Photonics Rev.， 2017， 11（6）： 1700148-1-10. doi: 10.1002/lpor.201700148http://dx.doi.org/10.1002/lpor.201700148

WANG L Y， SONG E H， DENG T T， et al. Luminescence properties and warm white LED application of a ternary-alkaline fluoride red phosphor K2NaAlF6∶Mn4+ ［J］. Dalton Tans.， 2017， 46（30）： 9925-9933. doi: 10.1039/c7dt02036hhttp://dx.doi.org/10.1039/c7dt02036h

QIU S J， WEI H W， WANG M M， et al. Synthesis and photoluminescence of Mn4+ activated ternary-alkaline fluoride K2NaGaF6 red phosphor for warm-white LED application ［J］. RSC Adv.， 2017， 7（79）： 50396-50402. doi: 10.1039/c7ra10274ghttp://dx.doi.org/10.1039/c7ra10274g

JANSEN T， BAUR F， JÜSTEL T. Red emitting K2NbF7∶Mn4+ and K2TaF7∶Mn4+ for warm-white LED applications ［J］. J. Lumin.， 2017， 192： 644-652. doi: 10.1016/j.jlumin.2017.07.061http://dx.doi.org/10.1016/j.jlumin.2017.07.061

ZHOU Y， ZHANG S， WANG X M， et al. Structure and luminescence properties of Mn4+-activated K3TaO2F4 red phosphor for white LEDs ［J］. Inorg. Chem.， 2019， 58（7）： 4412-4419. doi: 10.1021/acs.inorgchem.8b03577http://dx.doi.org/10.1021/acs.inorgchem.8b03577

LAZAROWSKA A， MAHLIK S， GRINBERG M， et al. Pressure effect on the zero-phonon line emission of Mn4+ in K2SiF6 ［J］. J. Chem. Phys.， 2015， 143（13）： 134704-1-4. doi: 10.1063/1.4932181http://dx.doi.org/10.1063/1.4932181

司帅晨，黄霖，王静. K2SiF6∶Mn4+荧光玻璃陶瓷及其在激光照明中的应用［J］. 发光学报， 2021， 42（10）： 1549-1558. doi: 10.37188/CJL.20210176http://dx.doi.org/10.37188/CJL.20210176

SI S C， HUANG L， WANG J. K2SiF6∶Mn4+ luminescent glass ceramics applicable to laser lighting ［J］. Chin. J. Lumin.， 2021， 42（10）： 1549-1558. （in Chinese）. doi: 10.37188/CJL.20210176http://dx.doi.org/10.37188/CJL.20210176

SHELDRICK G M.Crystal structure refinement with SHELXL ［J］.Acta Crystallogr C Struct. Chem.， 2015， 71（Pt 1）： 3-8. doi: 10.1107/s2053229614024218http://dx.doi.org/10.1107/s2053229614024218

SHELDRICK G M. A short history of SHELX ［J］. Acta Crystallogr. A， 2008， 64： 112-122. doi: 10.1107/s0108767307043930http://dx.doi.org/10.1107/s0108767307043930

SEGALL M D， LINDAN P J D， PROBERT M J， et al. First-principles simulation： ideas， illustrations and the CASTEP code ［J］. J. Phys.： Condens Matter.， 2002， 14（11）： 2717-2744. doi: 10.1088/0953-8984/14/11/301http://dx.doi.org/10.1088/0953-8984/14/11/301

HENDERSON B， IMBUSCH G F. Optical Spectroscopy of Inorganic Solids ［M］. Oxford： Oxford University Press， 2006. doi: 10.1016/s1369-7021(06)71623-6http://dx.doi.org/10.1016/s1369-7021(06)71623-6

SRIVASTAVA A M， ACKERMAN J F. Synthesis and luminescence properties of barium niobium oxide fluoride（BaNbOF5） with isolated ［NbOF5］2- octahedra ［J］. Chem. Mater.， 1992， 4（5）： 1011-1013. doi: 10.1021/cm00023a016http://dx.doi.org/10.1021/cm00023a016

WANG Y G， WEN T， TANG L Y， et al. Impact of hydrostatic pressure on the crystal structure and photoluminescence properties of Mn4+-doped BaTiF6 red phosphor ［J］. Dalton Trans.， 2015， 44（16）： 7578-7585. doi: 10.1039/c5dt00426hhttp://dx.doi.org/10.1039/c5dt00426h

姬海鹏. Mn4+离子光谱学基础［J］. 发光学报， 2022， 43（8）： 1175-1187. doi: 10.37188/cjl.20220102http://dx.doi.org/10.37188/cjl.20220102

JI H B. Basic knowledge for understanding spectroscopic property of Mn4+ ion ［J］. Chin. J. Lumin.， 2022， 43（8）： 1175-1187. （in Chinese）. doi: 10.37188/cjl.20220102http://dx.doi.org/10.37188/cjl.20220102

ZHONG Y， GAI S J， XIA M， et al. Enhancing quantum efficiency and tuning photoluminescence properties in far-red-emitting phosphor Ca14Ga10Zn6O35∶Mn4+ based on chemical unit engineering ［J］. Chem. Eng. J.， 2019， 374： 381-391. doi: 10.1016/j.cej.2019.05.201http://dx.doi.org/10.1016/j.cej.2019.05.201

DONG X L， PAN Y X， LI D， et al. A novel red phosphor of Mn4+ ion-doped oxyfluoroniobate BaNbOF5 for warm WLED applications ［J］. CrystEngComm， 2018， 20（37）： 5641-5646. doi: 10.1039/c8ce01304ghttp://dx.doi.org/10.1039/c8ce01304g

ZHAO D， ZHANG S R， FAN Y P， et al. Two-site occupancy induced a broad-band emission in phosphor K2YZr（PO4）3∶Eu2+ for white-light-emitting diode applications ［J］. ACS Sustainable Chem. Eng.， 2020， 8（51）： 18992-19002. doi: 10.1021/acssuschemeng.0c07082http://dx.doi.org/10.1021/acssuschemeng.0c07082

NOCEDAL J. Updating quasi-newton matrices with limited storage ［J］. Math. Comput.， 1980， 35（151）： 773-782. doi: 10.1090/s0025-5718-1980-0572855-7http://dx.doi.org/10.1090/s0025-5718-1980-0572855-7

PENG L L， CHEN W B， CAO S X， et al. Enhanced photoluminescence and thermal properties due to size mismatch in Mg2TixGe1-xO4∶Mn4+ deep-red phosphors ［J］. J. Mater. Chem. C， 2019， 7（8）： 2345-2352. doi: 10.1039/c8tc05743ehttp://dx.doi.org/10.1039/c8tc05743e

HU T， LIN H， GAO Y， et al. Host sensitization of Mn4+ in self-activated Na2WO2F4∶Mn4+ ［J］. J. Am. Ceram. Soc.， 2018， 101（8）： 3437-3442. doi: 10.1111/jace.15521http://dx.doi.org/10.1111/jace.15521

Views

136

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Luminescence Performance and Damp⁃heat Stability of K₂SiF₆∶Mn⁴⁺ Phosphor Enhanced by Al₂O₃ Surface Coating

Surface Passivation of Mn⁴⁺-doped Fluoride Red Light-emitting Particles for White Light-emitting Diodes

Mn⁴⁺-doped Red-emitting Fluoride Phosphors with Intense Zero Phonon Line

Synthesis and Luminescence Properties of Red Phosphor Na_8.33La_1.67(SiO₄)₆O₂: Eu³⁺

Related Author

KONG Jun-Ren

YANG ZHOU

ZHANG Shi-Rui

LI Rui-xin

WANG Xiao-Ming

JIAO Huan

DUAN Lingyue

LU Wanbing

Related Institution

Hebei Key Laboratory of Semiconductor Lighting and Display Critical Materials， Hebei Ledphor Optoelectronics Technology Co.， LTD

National ＆ Local Joint Engineering Laboratory of New Energy Optoelectronic Devices，College of Physics Science & Technology， Hebei University

College of Chemistry and Chemical Engineering， Hunan Normal University

Key Laboratory of Light Energy Conversion Materials of Hunan Province College

Intelligent Manufacturing， Luoyang Institute of Science and Technology

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

A Novel Red Fluoride Phosphor BaTaF7∶Mn4+

DOI：10.37188/CJL.20220411

摘要

Abstract

关键词

Keywords

references

A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺