A Novel Red Fluoride Phosphor BaTaF<sub>7</sub>∶Mn<sup>4+</sup>

KONG Junren; ZHOU Yang; ZHANG Shirui; LI Ruixin; WANG Xiaoming; JIAO Huan

doi:10.37188/CJL.20220411

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A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺

Synthesis and Properties of Materials | 更新时间：2023-10-27

- A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 6, Pages: 975-984(2023)
- 作者机构：
  
  陕西师范大学化学化工学院，陕西西安　710119
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51972203;22271180)
- DOI：10.37188/CJL.20220411
  CLC： O482.31
- Published：05 June 2023，
  
  Received：12 December 2022，
  
  Revised：22 December 2022，
- 稿件说明：
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孔俊人,周洋,张世瑞等.一种新型氟化物红色荧光粉BaTaF₇∶Mn⁴⁺[J].发光学报,2023,44(06):975-984.

KONG Junren,ZHOU Yang,ZHANG Shirui,et al.A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺[J].Chinese Journal of Luminescence,2023,44(06):975-984.
孔俊人,周洋,张世瑞等.一种新型氟化物红色荧光粉BaTaF₇∶Mn⁴⁺[J].发光学报,2023,44(06):975-984. DOI： 10.37188/CJL.20220411.

KONG Junren,ZHOU Yang,ZHANG Shirui,et al.A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺[J].Chinese Journal of Luminescence,2023,44(06):975-984. DOI： 10.37188/CJL.20220411.

摘要

采用共沉淀方法合成了一种新型氟化物红色荧光粉BaTaF

∶Mn

，确定了BaTaF

的组成与晶体结构，研究并讨论了晶体结构与发光性能之间的关系。在紫外（UV）和蓝光激发下，BaTaF

∶Mn

荧光粉在630 nm表现出强烈的零声子线（ZPL）发射，其源于晶体结构中［MnF

］畸变八面体的

群对称环境。由YAG∶Ce

和BaTaF

∶Mn

荧光粉混合制备的暖白光LED表现出较优异的性能，表明BaTaF

∶Mn

具有成为暖白色发光二极管红色荧光粉的应用潜力。

Abstract

A novel red fluoride phosphor BaTaF

∶Mn

was synthesized

via

the conventional co-precipitation method. The structure and luminescence properties of BaTaF

∶Mn

were investigated and discussed under various conditions. The BaTaF

∶Mn

phosphor shows strong ZPL emission intensity at about 630 nm under ultraviolet （UV） and blue light excitation. It originated from the highly distorted Mn

octahedral coordination environment in the

group symmetry. A warm LED fabricated with a blend of YAG∶Ce

and the BaTaF

∶Mn

phosphor showed excellent performance， indicating BaTaF

∶Mn

potential for application as a red phosphor for warm WLEDs.

关键词

氟化物Mn4+掺杂红色荧光粉零声子线暖白色发光二极管

Keywords

fluorideMn4+ dopedred phosphorzero-phonon linewarm WLEDs

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⁰

A Novel Red Fluoride Phosphor BaTaF7∶Mn4+

DOI：10.37188/CJL.20220411

摘要

Abstract

关键词

Keywords

references

A Novel Red Fluoride Phosphor BaTaF₇∶Mn⁴⁺