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南京大学 现代工程与应用科学学院, 江苏 南京 210000
Published:05 March 2023,
Received:28 September 2022,
Revised:18 October 2022,
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李曼亚,李禄东,刘洲等.柔性钙钛矿光伏:研究进展、商业化进程和展望[J].发光学报,2023,44(03):466-485.
LI Manya,LI Ludong,LIU Zhou,et al.Flexible Perovskite Photovoltaics: Progress, Commercialization and Prospects[J].Chinese Journal of Luminescence,2023,44(03):466-485.
李曼亚,李禄东,刘洲等.柔性钙钛矿光伏:研究进展、商业化进程和展望[J].发光学报,2023,44(03):466-485. DOI: 10.37188/CJL.20220355.
LI Manya,LI Ludong,LIU Zhou,et al.Flexible Perovskite Photovoltaics: Progress, Commercialization and Prospects[J].Chinese Journal of Luminescence,2023,44(03):466-485. DOI: 10.37188/CJL.20220355.
目前,推动能源产业向高效、清洁、灵活的体系转型已成为解决世界环境问题的关键。与此同时,随着技术革命和物联网的发展,将太阳能电池和设备集成到一个部件中从而在更多元化的应用场景中采集能量成为了人们的新需求。以聚苯二甲酸乙二醇酯(PET)、聚萘二甲酸乙二醇酯(PEN)等柔性聚合物为基底的柔性钙钛矿太阳能电池(FPSCs)具有高能量转换效率、高柔韧性和灵活性、低制备成本和一定的便携性,在近十年的发展时间里成为了第三代太阳能电池中的后起之秀。此外,它对环境友好和经济效益良好的卷对卷制造技术具有的天然亲和力,使其在柔性自供电电子产品、大型建筑集成光伏(BIPV)和空间航空航天的发展中发挥着关键作用。本文着重讨论了柔性透明导电衬底、低温加工电荷传输层和机械弹性钙钛矿膜在单结和叠层FPSCs中的重要作用,并简要总结了其最新进展。最后,结合FPSCs的大规模制造技术,对封装的可靠性和操作稳定性提出了一些见解,并展望了在大面积组件等方面的潜在实际应用。
At present, promoting the transition of the energy industry to a system that is effective, clean, and flexible has currently emerged as the key to tackling the world's environmental issues. The progress of the Internet of Things and the technology revolution have created a new demand to combine solar equipment and cells into a single component in order to collect energy in a wider range of application situations. Flexible perovskite solar cells(FPSCs) based on flexible polymers such as polyethylene terephthalate (PET) and polyethylene naphthalate(PEN) have emerged as a rising star in the third generation of solar cells in the past decade due to their high energy conversion efficiency, high flexibility, low preparation cost and certain portability. In addition, it has a natural affinity for environmentally friendly and economically beneficial roll-to-roll manufacturing technology which will enable it to play a key role in the development of flexible self-powered electronic products, large-scale building integrated photovoltaic(BIPV) and space aerospace. In this review, we emphatically discuss the critical role and briefly summarize the most recent developments of the flexible transparent conductive substrate, low-temperature processed charge transporting layer, and mechanically resilient perovskite film in single and tandem FPSCs. Finally, combined with the large-scale manufacturing technology of FPSCs, we offer some insight into the reliability and operational stability of the package and discuss potential practical applications in large-area modules and so forth.
柔性钙钛矿太阳能电池柔性钙钛矿叠层太阳能电池光伏组件
flexibleperovskite solar cellflexible perovskite tandem solar cellphotovoltaic module
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