Upconversion Luminescence and Temperature Sensing Characteristics of Tm3+/Yb3+ Co-doped Germanate Glass Ceramics Containing LaF3 Nanocrystals

LI Bo; HUANG Lihui; CHEN Xinyu; BAI Gongxun; ZHAO Shilong; XU Shiqing

doi:10.37188/CJL.20220337

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Upconversion Luminescence and Temperature Sensing Characteristics of Tm³⁺/Yb³⁺ Co-doped Germanate Glass Ceramics Containing LaF₃ Nanocrystals

Synthesis and Properties of Materials | 更新时间：2023-03-13

- Upconversion Luminescence and Temperature Sensing Characteristics of Tm³⁺/Yb³⁺ Co-doped Germanate Glass Ceramics Containing LaF₃ Nanocrystals
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 2, Pages: 271-278(2023)
- 作者机构：
  
  中国计量大学光学与电子科技学院，光电材料与器件研究院，浙江省稀土光电材料与器件重点实验室，浙江杭州　310018
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(12174360)
- DOI：10.37188/CJL.20220337
  CLC： O482.31
- Published：05 February 2023，
  
  Received：16 September 2022，
  
  Revised：09 October 2022，
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李波,黄立辉,陈新禹等.Tm³⁺/Yb³⁺共掺含LaF₃纳米晶锗酸盐微晶玻璃的上转换发光及其温度传感特性[J].发光学报,2023,44(02):271-278.

LI Bo,HUANG Lihui,CHEN Xinyu,et al.Upconversion Luminescence and Temperature Sensing Characteristics of Tm³⁺/Yb³⁺ Co-doped Germanate Glass Ceramics Containing LaF₃ Nanocrystals[J].Chinese Journal of Luminescence,2023,44(02):271-278.
李波,黄立辉,陈新禹等.Tm³⁺/Yb³⁺共掺含LaF₃纳米晶锗酸盐微晶玻璃的上转换发光及其温度传感特性[J].发光学报,2023,44(02):271-278. DOI： 10.37188/CJL.20220337.

LI Bo,HUANG Lihui,CHEN Xinyu,et al.Upconversion Luminescence and Temperature Sensing Characteristics of Tm³⁺/Yb³⁺ Co-doped Germanate Glass Ceramics Containing LaF₃ Nanocrystals[J].Chinese Journal of Luminescence,2023,44(02):271-278. DOI： 10.37188/CJL.20220337.

摘要

通过传统的熔融淬火技术以及后续热处理法制备了Tm

/Yb

共掺含LaF

纳米晶锗酸盐微晶玻璃。通过DTA和XRD研究其热性质和LaF

纳米晶的可控析出。通过透过光谱和上转换发光光谱研究了玻璃的光学性能。利用荧光强度比（FIR）技术研究了微晶玻璃样品在980 nm激光激发下的上转换发光光谱与温度的依赖关系。研究发现，该微晶玻璃样品在313~573 K温度范围内的最大绝对灵敏度

和最大相对灵敏度

分别为2.6×10

-4

-1

（573 K）和2.3×10

-2

-1

（313 K）。结果表明，Tm

/Yb

共掺含LaF

纳米晶锗酸盐微晶玻璃在温度传感领域具有潜在的应用前景。

Abstract

/Yb

co-doped germanate glass ceramics containing LaF

nanocrystals were prepared by traditional melt quenching technique and subsequent heat treatment. The thermal properties and the controllable precipitation of LaF

nanocrystals were studied by DTA and XRD. The optical properties of the glasses were studied by transmission spectra and upconversion luminescence spectra. The temperature dependence of upconversion luminescence spectra of glass ceramics excited by 980 nm laser was studied by fluorescence intensity ratio （FIR） technique. It is found that the maximum absolute sensitivity （

） and the maximum relative sensitivity （

） of the glass ceramics are 2.6×10

-4

-1

（573 K） and 2.3×10

-2

-1

（313 K） at the temperature range of 313-573 K， respectively. The results show that Tm

/Yb

co-doped germanate glass ceramics containing LaF

nanocrystals have potential application prospects in the field of temperature sensing.

关键词

锗酸盐玻璃微晶玻璃Tm3+/Yb3+温度传感

Keywords

germanate glassglass ceramicsTm3+/Yb3+temperature sensing

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