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1.广东省晶体与激光技术工程研究中心, 广东 广州 510632
2.暨南大学理工学院 光电工程系, 广东 广州 510632
Published:05 November 2022,
Received:29 April 2022,
Revised:19 May 2022,
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谭慧瑜,张沛雄,牛晓晨等.可见光激光晶体Sm3+∶CaDyAlO4的光学性能[J].发光学报,2022,43(11):1741-1749.
TAN Hui-yu,ZHANG Pei-xiong,NIU Xiao-chen,et al.Optical Properties of Visible Laser Crystal Sm3+∶CaDyAlO4[J].Chinese Journal of Luminescence,2022,43(11):1741-1749.
谭慧瑜,张沛雄,牛晓晨等.可见光激光晶体Sm3+∶CaDyAlO4的光学性能[J].发光学报,2022,43(11):1741-1749. DOI: 10.37188/CJL.20220164.
TAN Hui-yu,ZHANG Pei-xiong,NIU Xiao-chen,et al.Optical Properties of Visible Laser Crystal Sm3+∶CaDyAlO4[J].Chinese Journal of Luminescence,2022,43(11):1741-1749. DOI: 10.37188/CJL.20220164.
采用提拉法成功地生长了Sm
3+
掺杂CaDyAlO
4
晶体,并对其可见光光学性能进行研究,利用Judd‑Ofelt理论,得到强度参数、自发辐射概率及荧光分支比等重要的光谱性能参数。该晶体在353 nm处吸收峰最强,半高宽(FWHM)为13 nm,吸收截面为1.11×10
-20
cm
2
;在353 nm激发下,获得了500~650 nm的超宽带橙黄光发射,Dy
3+
离子和Sm
3+
离子的主要发射峰分别位于570 nm和620 nm处,发射截面分别为4.15×10
-20
cm
2
和4.03×10
-20
cm
2
。上述结果表明,Sm
3+
∶CaDyAlO
4
晶体可能是500~650 nm橙黄色调谐激光器的一种有前景的增益材料。
The Czochralski method was used to successfully grow the Sm
3+
-doped CaDyAlO
4
crystal, and its optical properties in visible light were investigated. Important spectral performance parameters such as intensity parameters, spontaneous emission probability, and fluorescence branching ratio were obtained using the Judd-Ofelt theory. The crystal has a strong absorption peak at 353 nm, a full width at half maximum(FWHM) of 13 nm, and an absorption cross section of 9.76×10
-20
cm
2
. When excited at 353 nm, an ultra-broadband orange-yellow emission from 500 nm to 650 nm is obtained, with Dy
3+
ions and Sm
3+
ions. The main emission peaks of Dy
3+
ions and Sm
3+
ions are at 570 nm and 620 nm, respectively, and the emission cross sections are 4.15×10
-20
cm
2
and 4.03×10
-20
cm
2
, respectively. The above findings suggest that Sm
3+
∶CaDyAlO
4
crystals could be a promising gain material for orange-yellow tunable lasers from 500 nm to 650 nm.
激光晶体Sm3+掺杂Judd-Ofelt理论橙黄光发射
laser crystalSm3+-dopedJudd-Ofelt theoryorange-yellow emission
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