Synthesis and Luminescent Properties of Gd2[1-<italic style="font-style: italic">x</italic>(<italic style="font-style: italic">y</italic>)]Eu2<italic style="font-style: italic">x</italic>(<italic style="font-style: italic">y</italic>)W<italic style="font-style: italic">z</italic>Mo(1-<italic style="font-style: italic">z</italic>)O6 Red Phosphors

Min ZHANG; Chun-yan CAO; Chen-lin ZHANG; Zi-jun CHEN; Bi-hai BAI; Ni-hui HUANG; An XIE

doi:10.37188/CJL.20220092

您当前的位置：

首页 >

文章列表页 >

Synthesis and Luminescent Properties of Gd_2[1-_x₍_y_)]Eu₂_x₍_y₎W_zMo_(1-_z₎O₆ Red Phosphors

Synthesis and Properties of Materials | 更新时间：2022-08-01

- Synthesis and Luminescent Properties of Gd_2[1-_x₍_y_)]Eu₂_x₍_y₎W_zMo_(1-_z₎O₆ Red Phosphors
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 7, Pages: 1086-1094(2022)
- 作者机构：
  
  厦门理工学院材料科学与工程学院福建省功能材料及应用重点实验室，福建厦门 361024
- 作者简介：
- 基金信息：
  
  Natural Science Foundation of Fujian Province(2021J011207);Open Fund of Fujian Provincial Key Laboratory of Functional Materials and Applications(厦门理工学院fma2022006);Key Project of Natural Science Foundation of Fujian Province(2020J02049)
- DOI：10.37188/CJL.20220092
  CLC： O482.31
- Published：05 July 2022，
  
  Received：18 March 2022，
  
  Revised：05 April 2022，
扫描看全文
张敏,曹春燕,张陈林等.Gd_2[1-_x₍_y_)]Eu₂_x₍_y₎W_zMo_(1-_z₎O₆红色荧光粉合成及发光性能[J].发光学报,2022,43(07):1086-1094.

ZHANG Min,CAO Chun-yan,ZHANG Chen-lin,et al.Synthesis and Luminescent Properties of Gd_2[1-_x₍_y_)]Eu₂_x₍_y₎W_zMo_(1-_z₎O₆ Red Phosphors[J].Chinese Journal of Luminescence,2022,43(07):1086-1094.
张敏,曹春燕,张陈林等.Gd_2[1-_x₍_y_)]Eu₂_x₍_y₎W_zMo_(1-_z₎O₆红色荧光粉合成及发光性能[J].发光学报,2022,43(07):1086-1094. DOI： 10.37188/CJL.20220092.

ZHANG Min,CAO Chun-yan,ZHANG Chen-lin,et al.Synthesis and Luminescent Properties of Gd_2[1-_x₍_y_)]Eu₂_x₍_y₎W_zMo_(1-_z₎O₆ Red Phosphors[J].Chinese Journal of Luminescence,2022,43(07):1086-1094. DOI： 10.37188/CJL.20220092.

摘要

采用高温固相法制备了Gd

2（1-

）

（0≤

≤0.35）、Gd

2（1-

）

MoO

（0≤

≤0.25）和Gd

1.9

0.1

（1-

）

（0≤

≤1）系列红色荧光粉。探索了Gd

2（1-

）

荧光粉和Gd

2（1-

）

MoO

荧光粉的最佳合成温度及最佳Eu

掺杂浓度，并进一步探索了W

、Mo

比例对Gd

1.9

0.1

（1-

）

结构、形貌及发光性能的影响。随着Eu

浓度增加，在Gd

2（1-

）

和Gd

2（1-

）

MoO

荧光粉X射线衍射图中观察到衍射峰向小角度方向偏移。研究了Gd

2（1-

）

中Eu

发光浓度猝灭机理。随着Mo

含量增加，在Gd

1.9

0.1

（1-

）

中观察到电荷迁移带红移现象，并通过漫反射谱推算了荧光粉材料带隙值。通过扫描电镜图像及电子能谱表征了W

、Mo

比例改变对荧光粉颗粒形貌及组成的影响。

Abstract

2（1-

）

（0≤

≤0.35）， Gd

2（1-

）

MoO

（0≤

≤0.25） and Gd

1.9

0.1

（1-

）

（0≤

≤1） series of red phosphor were prepared by high temperature solid-state reaction method. The optimum synthesis temperature and the optimum doping concentration of Eu

in Gd

2（1-

）

and Gd

2（1-

）

MoO

phosphors were explored. The effects of W

and Mo

ratio on Gd

1.9

0.1

phosphors were further explored. In Gd

2（1-

）

and Gd

2（1-

）

MoO

phosphors， the diffraction peaks moved to small angle with the Eu

concentration increasing. The luminescence concentration quenching mechanisms of Eu

in Gd

2（1-

）

were studied. With the content of Mo

increasing， the red-shift of the charge transfer band was observed in Gd

1.9

0.1

（1-

）

phosphors. The values of energy band gaps of some phosphors were calculated based on diffuse reflectance spectra. The morphologies and the compositions of some phosphors were characterized by field emission scanning electron microscope and energy disperse spectroscopy.

关键词

高温固相法荧光粉光致发光浓度猝灭红移

Keywords

high temperature solid state reaction methodphosphorsphotoluminescenceconcentration quenchingred shift

references

LI Y，LI Z Y，GUO L N，et al. Enhanced dual-wavelength upconversion luminescence，thermosensitivity and DMMP detection of multifunctional Gd2MoO6∶Er3+/Yb3+ nanoparticles ［J］. J. Alloys Compd.， 2020，847：156399-1-11. doi: 10.1016/j.jallcom.2020.156399http://dx.doi.org/10.1016/j.jallcom.2020.156399

MENG Q Y，HUA R N，CHEN B J，et al. Study on luminescent properties of Eu3+ doped Gd2WO6，Gd2W2O9 and Gd2（WO4）3 nanophosphors prepared by co-precipitation ［J］. J. Nanosci. Nanotechnol.， 2011，11（1）：182-188. doi: 10.1166/jnn.2011.3078http://dx.doi.org/10.1166/jnn.2011.3078

林金填，邱镇民，蔡金兰，等. Gd2MoO6∶Sm3+荧光粉的制备及其发光性能研究［J］. 中国照明电器， 2018（8）：5-8.

LIN J T，QIU Z M，CAI J L，et al. Preparation and photoluminescence properties of Gd2MoO6∶Sm3+ phosphors ［J］. China Light Light.， 2018（8）：5-8. （in Chinese）

WANG X F，WANG Y M，BU Y Y，et al. Influence of doping and excitation powers on optical thermometry in Yb3+-Er3+ doped CaWO4 ［J］. Sci. Rep.， 2017，7：43383-1-9. doi: 10.1038/srep43383http://dx.doi.org/10.1038/srep43383

耿秀娟，田彦文，陈永杰，等. 白光LED用钨/钼酸盐红色荧光粉的研究进展［J］. 材料导报， 2010，24（13）：54-57.

GENG X J，TIAN Y W，CHEN Y J，et al. Progress in studies on tungstate and molybdate red emitting phosphor used for white-LED ［J］. Mater. Rev.， 2010，24（13）：54-57. （in Chinese）

阮文科，谢木标. 白光LED用钨/钼酸盐红色发光材料研究进展［J］. 人工晶体学报， 2021，50（1）：167-178.

RUAN W K，XIE M B. Recent research progress on tungsten and molybdate red luminescent material for white LED ［J］. J. Synth. Cryst.， 2021，50（1）：167-178. （in Chinese）

NEERAJ S，KIJIMA N，CHEETHAM A K. Novel red phosphors for solid-state lighting：the system NaM（WO4）2-x（MoO4）x∶Eu3+ （M=Gd，Y，Bi）［J］. Chem. Phys. Lett.， 2004，387（1-3）：2-6. doi: 10.1016/j.cplett.2003.12.130http://dx.doi.org/10.1016/j.cplett.2003.12.130

CAO F B，TIAN Y W，CHEN Y J，et al. Novel red phosphors for solid-state lighting：Ca0.54Sr0.34-1.5xEu0.08Lax（MoO4）y（WO4）1-y ［J］. J. Alloys Compd.， 2009，475（1-2）：387-390. doi: 10.1016/j.jallcom.2008.07.026http://dx.doi.org/10.1016/j.jallcom.2008.07.026

李香萍，佟莉莉，程丽红，等. Tm3+浓度对Y2（MoO4）3∶Tm3+，Yb3+荧光粉上转换发光性质的影响［J］. 发光学报， 2014，35（8）：905-910.

LI X P，TONG L L，CHENG L H，et al. Effect of Tm3+ concentration on upconversion fluorescence in Y2（MoO4）3∶Tm3+，Yb3+ phosphors ［J］. Chin. J. Lumin.， 2014，35（8）：905-910. （in Chinese）

SUN W T，GU Y X，ZHANG Q H，et al. CaTiO3∶Eu3+ layers coated SiO2 particles：core-shell structured red phosphors for near-UV white LEDs ［J］. J. Alloys Compd.， 2010，493（1-2）：561-564. doi: 10.1016/j.jallcom.2009.12.155http://dx.doi.org/10.1016/j.jallcom.2009.12.155

冯晓辉，孟庆裕，孙江亭，等. Eu3+掺杂Gd2W2O9和Gd2（WO4）3纳米荧光粉发光性质研究［J］. 物理学报， 2011，60（3）：037806-1-9. doi: 10.7498/aps.60.037806http://dx.doi.org/10.7498/aps.60.037806

FENG X H，MENG Q Y，SUN J T，et al. Luminescent properties of Eu3+ doped Gd2W2O9 and Gd2（WO4）3 nanophosphors ［J］. Acta Phys. Sinica， 2011，60（3）：037806-1-9. （in Chinese）. doi: 10.7498/aps.60.037806http://dx.doi.org/10.7498/aps.60.037806

ZHANG L X，XIE Y，GENG X，et al. Double perovskite Ca2MgTeO6∶Eu3+ red-emitting phosphors with high thermal stability for near UV/blue excited white LEDs ［J］. J. Lumin.， 2020，225：117365-1-8. doi: 10.1016/j.jlumin.2020.117365http://dx.doi.org/10.1016/j.jlumin.2020.117365

CHEN W P. Achieving tunable luminescence in Eu2+ and Eu3+ codoped MAl2B2O7∶Eu （M=Ca2+，Sr2+，and Ba2+） phosphor by structure defect designing and site symmetry controlling ［J］. Opt. Mater.， 2021，122：111673. doi: 10.1016/j.optmat.2021.111673http://dx.doi.org/10.1016/j.optmat.2021.111673

王林香，孙德方，李晴，等. Dy3+和Ce3+共掺Y3Al5O12荧光粉的制备及发光性质［J］. 发光学报， 2020，41（2）：160-167.

WANG L X，SUN D F，LI Q，et al. Luminescent properties of Dy3+，Ce3+ co-doped Y3Al5O12 phosphors ［J］. Chin. J. Lumin.， 2020，41（2）：160-167. （in Chinese）

PINATTI I M，PIRES F A，ALMEIDA P B，et al. Tailoring Bi2MoO6 by Eu3+ incorporation for enhanced photoluminescence emissions ［J］. J. Lumin.， 2022，243：118675-1-7. doi: 10.1016/j.jlumin.2021.118675http://dx.doi.org/10.1016/j.jlumin.2021.118675

KALIMUTHU K R，BABU S M，KALIMUTHU V. Synthesis and photoluminescence properties of Sm3+ doped LiGd（WO4）2 phosphors with high color purity ［J］. Opt. Mater.，2020，102：109804-1-8. doi: 10.1016/j.optmat.2020.109804http://dx.doi.org/10.1016/j.optmat.2020.109804

张玉红，刘丹，王婷婷，等. Yb3+/Er3+/Gd3+掺杂Lu2O3、Y2O3荧光粉的上转换发光及温度特性［J］. 发光学报， 2019，40（12）：1478-1485. doi: 10.3788/fgxb20194012.1478http://dx.doi.org/10.3788/fgxb20194012.1478

ZHANG Y H，LIU D，WANG T T，et al. Upconversion luminescence and optical temperature sensing properties for Lu2O3⁃（Y2O3）∶Yb3+/Er3+/Gd3+ phosphors ［J］. Chin. J. Lumin.， 2019，40（12）：1478-1485. （in Chinese）. doi: 10.3788/fgxb20194012.1478http://dx.doi.org/10.3788/fgxb20194012.1478

BLASSE G. Energy transfer in oxidic phosphors ［J］. Phys. Lett. A， 1968，28（6）：444-445. doi: 10.1016/0375-9601(68)90486-6http://dx.doi.org/10.1016/0375-9601(68)90486-6

DEXTER D L. A theory of sensitized luminescence in solids ［J］. J. Chem. Phys.， 1953，21（5）：836-850. doi: 10.1063/1.1699044http://dx.doi.org/10.1063/1.1699044

LIU F，LIANG Y J，CHEN Y F，et al. Divalent nickel-activated gallate-based persistent phosphors in the short-wave infrared ［J］. Adv. Opt. Mater.， 2016，4（4）：562-566. doi: 10.1002/adom.201500656http://dx.doi.org/10.1002/adom.201500656

QIAO J W，XIA Z G，ZHANG Z C，et al. Near UV-pumped yellow-emitting Sr9MgLi（PO4）7∶Eu2+ phosphor for white-light LEDs ［J］. Sci. China Mater.， 2018，61（7）：985-992. doi: 10.1007/s40843-017-9207-2http://dx.doi.org/10.1007/s40843-017-9207-2

赵旺，平兆艳，郑庆华，等. 白光发光二极管用SrGdLiTeO6∶Eu3+红色荧光粉的浓度猝灭和温度猝灭行为［J］. 物理学报， 2018，67（24）：247801-1-10. doi: 10.7498/aps.67.20181523http://dx.doi.org/10.7498/aps.67.20181523

ZHAO W，PING Z Y，ZHENG Q H，et al. Concentration and thermal quenching of SrGdLiTeO6∶Eu3+ red-emitting phosphor for white light-emitting diode ［J］. Acta Phys. Sinica， 2018，67（24）：247801-1-10. （in Chinese）. doi: 10.7498/aps.67.20181523http://dx.doi.org/10.7498/aps.67.20181523

SINGH J，BAITHA P K，MANAM J. Influence of heat treatment on the structural and optical properties of SrGd2O4∶Eu3+ phosphor ［J］. J. Rare Earths， 2015，33（10）：1040-1050. doi: 10.1016/s1002-0721(14)60524-xhttp://dx.doi.org/10.1016/s1002-0721(14)60524-x

XUE J P，LI H P，NOH H M，et al. Molybdenum substitution induced luminescence enhancement in Gd2W1-xMoxO6∶Eu3+ phosphors for near ultraviolet based solid-state lighting ［J］. J. Lumin.， 2018，202：97-106. doi: 10.1016/j.jlumin.2018.05.033http://dx.doi.org/10.1016/j.jlumin.2018.05.033

ZHANG R，SUN J F. An efficient perovskite-type Rb2CaPO4F∶Eu2+ phosphor with high brightness towards closing the cyan gap ［J］. J. Alloys Compd.， 2021，872：159698-1-16. doi: 10.1016/j.jallcom.2021.159698http://dx.doi.org/10.1016/j.jallcom.2021.159698

张敏（1997-），女，山东菏泽人，硕士研究生，2020年于厦门理工学院获得学士学位，主要从事稀土离子掺杂红色荧光粉的研究。. doi: 10.1016/j.jallcom.2021.159698http://dx.doi.org/10.1016/j.jallcom.2021.159698

Views

168

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Photoluminescence Properties of Sr₆Lu₂Al₄O₁₅∶Tb³⁺ Phosphor

Tunable Photoluminescence Properties and Energy Transfer of Ba₃YB₉O₁₈:Tb³⁺, Eu³⁺ Phosphors

Preparation and Luminescent Properties of Near UV Excited KBaGd(MoO₄)₃: Dy³⁺ Phosphors

Synthesis and Photoluminescence Properties of A Novel Green-emitting Phosphor(Ce_0.67Tb_0.33)MgAl₁₁O₁₉∶Mn²⁺

Related Author

Min ZHANG

Chun-yan CAO

Chen-lin ZHANG

Zi-jun CHEN

Bi-hai BAI

Ni-hui HUANG

An XIE

LI Min

Related Institution

Key Laboratory of Functional Materials and Applications School of Materials Science and Engineering， Xiamen University of Technology

Department of Physics， Changchun Normal University

State Key Laboratory of Luminescence and Applications， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences

School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology

College of Chemistry, Jilin University

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Synthesis and Luminescent Properties of Gd2[1-x(y)]Eu2x(y)WzMo(1-z)O6 Red Phosphors

DOI：10.37188/CJL.20220092

摘要

Abstract

关键词

Keywords

references

Synthesis and Luminescent Properties of Gd_2[1-_x₍_y_)]Eu₂_x₍_y₎W_zMo_(1-_z₎O₆ Red Phosphors