Si-hua QUE, Li-ming WEI, Xiong-tu ZHOU, et al. Color-tunable QLED Based on Mixed Quantum Dots and Its White-light Application. [J]. Chinese Journal of Luminescence 43(4):591-597(2022)
DOI:
Si-hua QUE, Li-ming WEI, Xiong-tu ZHOU, et al. Color-tunable QLED Based on Mixed Quantum Dots and Its White-light Application. [J]. Chinese Journal of Luminescence 43(4):591-597(2022) DOI: 10.37188/CJL.20210392.
Color-tunable QLED Based on Mixed Quantum Dots and Its White-light Application增强出版
A color tunable quantum-dot light emitting diode(QLED) with the structure of ITO/PEDOT∶PSS/TFB/Mixed-QDs/ZnO/Ag was fabricated by using red and green mixed quantum dots as the light-emitting layer
and the electroluminescence spectrum of QLED device was studied. The experimental results show that the QLED device has significant color tunability. With the increase of applied voltage
the QLED device presents a color change from dark red to orange and then to dazzling yellow-green. The QLED device exhibits a turn-on voltage of 2.0 V and the maximum brightness can reach 6×10
4
cd/m
2
. What's more
the device achieves a maximum current efficiency of 21 cd/A and a maximum external quantum efficiency of 7.5% at 31 934 cd/m
2
. As an application demonstration
we further combine the color tunable QLED device with GaN-based blue LED to prepare a white light emission. The results show that the color temperature of white light emission can be tuned from 3 568 K(warm white) to 10 269 K(cold white) and color rendering index is not less than 70
exhibiting great prospects in the application of lighting.
关键词
量子点发光二极管颜色可调白光应用相关色温
Keywords
quantum-dot light emitting diodecolor tunablewhite-light applicationcorrelated color temperature
references
DAI X L, ZHANG Z X, JIN Y Z, et al. Solution-processed,high-performance light-emitting diodes based on quantum dots [J]. Nature, 2014, 515(7525):96-99.
SHEN H B, GAO Q, ZHANG Y B, et al. Visible quantum dot light-emitting diodes with simultaneous high brightness and efficiency [J]. Nat. Photonics, 2019, 13(3):192-197.
DAI X L, DENG Y Z, PENG X G, et al. Quantum-dot light-emitting diodes for large-area displays:towards the dawn ofcommercialization [J]. Adv. Mater., 2017, 29(14):1607022-1-22.
KIM S, LIM Y T, SOLTESZ E G, et al. Near-infrared fluorescent type II quantum dots for sentinel lymph node mapping [J]. Nat. Biotechnol., 2004, 22(1):93-97.
TANG J, KEMP K W, HOOGLAND S, et al. Colloidal-quantum-dot photovoltaics using atomic-ligand passivation [J]. Nat. Mater., 2011, 10(10):765-771.
HE L R, FEI M, CHEN J, et al. Graphitic C3N4 quantum dots for next-generation QLED displays [J]. Mater. Today, 2019, 22:76-84.
PARK S J, SONG S H, KIM S S, et al. Charge modulation layer and wide-color tunability in a QD-LED with multiemission layers [J]. Small, 2021, 17(17):2007397.
ZHAO Y, GAO X P, LU P, et al. Quantum dot-based white LEDs and their applications of smart lighting [J]. Chin. J. Liq. Cryst. Disp., 2021, 36(1):187-202. (in Chinese)
CAO F, WANG H R, SHEN P Y, et al. High-efficiency and stable quantum dot light-emitting diodes enabled by a solution-processed metal-doped nickel oxide hole injection interfacial layer [J]. Adv. Funct. Mater., 2017, 27(42):1704278-1-7.
CAO F, ZHAO D W, SHEN P Y, et al. High-efficiency,solution-processed white quantum dot light-emitting diodes with serially stacked red/green/blue units [J]. Adv. Opt. Mater., 2018, 6(20):1800652-1-7.
LIU Y, JIANG C B, SONG C, et al. Highly efficient all-solution processed inverted quantum dots based light emitting diodes [J]. ACS Nano, 2018, 12(2):1564-1570.
SUPRAN G J, SHIRASAKI Y, SONG K W, et al. QLEDs for displays and solid-state lighting [J]. MRS Bull., 2013, 38(9):703-711.
SUN Y Z, SU Q, ZHANG H, et al. Investigation on thermally induced efficiency roll-off:toward efficient and ultrabright quantum-dot light-emitting diodes [J]. ACS Nano, 2019, 13(10):11433-11442.
SHEN P Y, LI X M, CAO F, et al. Correction:highly efficient,all-solution-processed,flexible white quantum dot light-emitting diodes [J]. J. Mater. Chem. C, 2020, 8(45):16241.
SUN Q J, WANG Y A, LI L S, et al. Bright,multicoloured light-emitting diodes based on quantum dots [J]. Nat. Photonics, 2007, 1(12):717-722.
LEE K H, HAN C Y, JANG E P, et al. Full-color capable light-emitting diodes based on solution-processed quantum dot layer stacking [J]. Nanoscale, 2018, 10(14):6300-6305.
ZHUANG Z, GUO X, LIU B, et al. High color rendering index hybrid Ⅲ-nitride/nanocrystals white light-emitting diodes [J]. Adv. Funct. Mater., 2016, 26(1):36-43.
SONG S H, PARK S J, BAE T J, et al. All-solution-processed colour-tuneable tandem quantum-dot light-emitting diode driven by AC signal [J]. Nanoscale, 2020, 12(32):17020-17028.
BAE W K, LIM J, LEE D, et al. R/G/B/natural white light thin colloidal quantum dot-based light-emitting devices [J]. Adv. Mater., 2014, 26(37):6387-6393.
LEE J S, KANG B H, KIM S H, et al. All-solution-processed high-brightness hybrid white quantum-dot light-emitting devices utilizing polymer modified quantum dots [J]. Org. Electron., 2017, 42:393-398.
HSU S C, KE L A, LIN H C, et al. Fabrication of a highly stable white light-emitting diode with multiple-layer colloidal quantum dots [J]. IEEE J. Sel. Top. Quant., 2017, 23(5):2000409-1-9.
ZHU Y B, XU R, ZHOU Y G, et al. Ultrahighly efficient white quantum dot light-emitting diodes operating at low voltage [J]. Adv. Opt. Mater., 2020, 8(24):2001479.
YUAN Q L, WANG T, YU P L, et al. A review on the electroluminescence properties of quantum-dot light-emitting diodes [J]. Org. Electron., 2021, 90:106086-1-23.
YAN Q, SUN J, NIE J Y, et al. Display device formed by parallel connection of opposite polarities of LED and OLED:CN,111785714A [P]. 2020-10-16. (in Chinese)
CHEN P W, HSIAO P W, SHEN P C, et al. Improved performance of passive-matrix micro-LED displays using a multi-function passivation structure [J]. IEEE Photonics J., 2020, 12(4):7000711-1-11.
CHEN Z, YAN S K, DANESH C. MicroLED technologies and applications:characteristics,fabrication,progress,and challenges [J]. J. Phys. D: Appl. Phys., 2021, 54(12):123001-1-34.