Preparation, Optical Control and Application of Red/Near Infrared Emitting Carbon Dots

Ji-jian XU; Dan QU; Li AN; Xia-yan WANG; Zai-cheng SUN

doi:10.37188/CJL.20210302

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Preparation, Optical Control and Application of Red/Near Infrared Emitting Carbon Dots

Invited Review | 更新时间：2021-12-17

- Preparation, Optical Control and Application of Red/Near Infrared Emitting Carbon Dots
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 12, Pages: 1837-1851(2021)
- 作者机构：
  
  1.北京工业大学化学与生物系　绿色催化与分离北京市重点实验室　环境安全与生物效应中心，北京　100124
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(21805004;21671011;21872001;51801006;21625501);Natural Science Foundation of Beijing Municipality(2192005);Beijing Municipal Science and Natural Science Fund Project(KM201910005016);Beijing Outstanding Young Scientist Program(BJJWZYJH01201910005017)
- DOI：10.37188/CJL.20210302
  CLC：
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Ji-jian XU, Dan QU, Li AN, et al. Preparation, Optical Control and Application of Red/Near Infrared Emitting Carbon Dots. [J]. Chinese Journal of Luminescence 42(12):1837-1851(2021)
DOI：

Ji-jian XU, Dan QU, Li AN, et al. Preparation, Optical Control and Application of Red/Near Infrared Emitting Carbon Dots. [J]. Chinese Journal of Luminescence 42(12):1837-1851(2021) DOI： 10.37188/CJL.20210302.

摘要

红光/近红外发射碳点(简称R/NIR-CDs)具有生物相容性好、空间分辨率高等优势，受到了研究者们的广泛关注。但目前报道的红光碳点往往存在荧光量子效率低、半峰宽较宽且具有激发波长依赖的缺陷，限制了其在生物医学领域的应用。因此，合成制备高荧光量子产率(PLQY)、半峰宽窄且激发非依赖的红光/近红外发射碳点具有十分重要的意义。本文首先阐述了近年来几种具有代表性的典型前驱体及其合成碳点，总结了尺寸效应、杂原子掺杂、表面态等高效的碳点光学调控理论，并简要介绍了红光/近红外发射碳点在生物成像、疾病治疗及白光发光二极管中的应用现状。最后，针对红光/近红外发射碳点的发光机理、制备方法中面临的问题与挑战进行了展望。

Abstract

Red/near-infrared emitting carbon dots(marked as R/NIR-CDs) have the advantages of good biocompatibility and high spatial resolution, which had attracted the attention of researchers. However, the currently reported red carbon dots often have the defects of low fluorescence quantum efficiency, wide full width at half-maximum and excitation wavelength dependence, which limit their application in the biomedical field. Therefore, it is of great significance to synthesize carbon dots with high photoluminescence quantum yield(PLQY), narrow half-width and excitation-independent red/near-infrared emission. This article first describes several representative typical precursors and their synthesized carbon dots in recent years, and then summarizes several efficient regulation methods for the optical properties of CDs such as size effect, heteroatom doping, surface state,etc, and briefly introduces the application of red/near infrared emitting carbon dots in bioimaging, disease treatment and white light emitting diodes. Finally, the problems and challenges faced in the luminescence mechanism and the preparation method of red/near-infrared emitting carbon dots are prospected.

关键词

碳点红光/近红外发射光学调控生物成像LED

Keywords

carbon dotsred/NIR emissionoptical controlbioimagingLED

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Center of Excellence for Environmental Safety and Biological Effects， Beijing Key Laboratory for Green Catalysis and Separation， Department of Chemistry and Biology， Beijing University of Technology

School of Chemistry and Life Science, Advanced Institute of Materials Science, Changchun University of Technology

Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology

School of Chemistry and Life Science， Advanced Institute of Materials Science， Changchun University of Technology， Yanan Street

State Key Laboratory of Molecular Vaccinology and Molecular Diagnostics & Center for Molecular Imaging and Translational Medicine， Xiamen University

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