Luminescence Properties of Pr3+ Doped in Ba3La(PO4)3 with Vacuum Ultraviolet and X-ray Excitation

Qiu-feng SHI; Lei WANG; Hai-jie GUO; Ping HUANG; Cai-e CUI; Yan HUANG

doi:10.37188/CJL.20210281

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Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation

Synthesis and Properties of Materials | 更新时间：2021-11-23

- Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 11, Pages: 1756-1762(2021)
- 作者机构：
  
  1.太原理工大学　物理与光电工程学院，山西　太原　030024
  2.中国科学院高能物理研究所　北京同步辐射装置，北京　100049
- 作者简介：
- 基金信息：
  
  Key Research and Development （R&D） Projects of Shanxi Province(201903D121097)
- DOI：10.37188/CJL.20210281
  CLC：
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Qiu-feng SHI, Lei WANG, Hai-jie GUO, et al. Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation. [J]. Chinese Journal of Luminescence 42(11):1756-1762(2021)
DOI：

Qiu-feng SHI, Lei WANG, Hai-jie GUO, et al. Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation. [J]. Chinese Journal of Luminescence 42(11):1756-1762(2021) DOI： 10.37188/CJL.20210281.

摘要

Pr,3+,4f5d具有大的辐射跃迁速率，是高效快响应闪烁体材料较有前景的发光中心离子。本文采用高温固相法制备了Pr,3+,掺杂Ba,3,La(PO,4,),3,(BLP)光转换材料，对其物相、真空紫外发光性质、X射线激发发光性质、发光衰减特性和发光热稳定性进行了表征。结果表明，BLP∶Pr,3+,具有高效的Pr,3+,4f5d宽带发光，发光寿命为~15 ns，且具有较好的发光热稳定性。在基质172 nm激发下，存在基质到Pr,3+,4f5d的能量传递，而在X射线激发下可能受表面缺陷影响未发现明显的Pr,3+,4f5d发光。本文研究结果表明，BLP∶Pr,3+,在作为真空紫外到UV-C光转换材料方面具有潜在的应用价值。本研究对于设计新型快响应闪烁体具有一定的指导意义。

Abstract

The radiative transition rate of Pr,3+,4f5d is large, which makes it as a promising luminescence center of fast scintillators. Samples of Ba,3,La(PO,4,),3,(BLP) activated with Pr,3+, were prepared through high temperature solid state method and characterized by XRD, temperature-dependent luminescence spectra upon VUV-UV and X-ray excitations and decay curves. Efficient and thermal stable Pr,3+,4f5d broad band emission with decay time of ~15 ns was observed. There is energy transfer from host to Pr,3+,4f5d upon excitation at 172 nm, however, the energy transfer is absent upon X-ray excitation which is attributed to influence of defects on surface. The results indicate that BLP∶Pr,3+, could be applied as an efficient VUV to UV-C converting material. In addition, the research is also important for designing novel fast scintillators.

关键词

真空紫外光Pr3+4f5d能量传递衰减曲线基质发光

Keywords

vacuum ultravioletPr3+4f5denergy transferdecay curveshost luminescence

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