Luminescence Properties of Pr3+ Doped in Ba3La(PO4)3 with Vacuum Ultraviolet and X-ray Excitation

Qiu-feng SHI; Lei WANG; Hai-jie GUO; Ping HUANG; Cai-e CUI; Yan HUANG

doi:10.37188/CJL.20210281

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Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation

Synthesis and Properties of Materials | 更新时间：2021-11-23

- Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 11, Pages: 1756-1762(2021)
- 作者机构：
  
  1.太原理工大学　物理与光电工程学院，山西　太原　030024
  2.中国科学院高能物理研究所　北京同步辐射装置，北京　100049
- 作者简介：
- 基金信息：
  
  Key Research and Development （R&D） Projects of Shanxi Province(201903D121097)
- DOI：10.37188/CJL.20210281
  CLC： O482.31
- Published：01 November 2021，
  
  Received：26 August 2021，
  
  Revised：13 September 2021，
扫描看全文
Qiu-feng SHI, Lei WANG, Hai-jie GUO, et al. Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation. [J]. Chinese Journal of Luminescence 42(11):1756-1762(2021)
DOI：

Qiu-feng SHI, Lei WANG, Hai-jie GUO, et al. Luminescence Properties of Pr³⁺ Doped in Ba₃La(PO₄)₃ with Vacuum Ultraviolet and X-ray Excitation. [J]. Chinese Journal of Luminescence 42(11):1756-1762(2021) DOI： 10.37188/CJL.20210281.

摘要

4f5d具有大的辐射跃迁速率，是高效快响应闪烁体材料较有前景的发光中心离子。本文采用高温固相法制备了Pr

掺杂Ba

La(PO

)

(BLP)光转换材料，对其物相、真空紫外发光性质、X射线激发发光性质、发光衰减特性和发光热稳定性进行了表征。结果表明，BLP∶Pr

具有高效的Pr

4f5d宽带发光，发光寿命为~15 ns，且具有较好的发光热稳定性。在基质172 nm激发下，存在基质到Pr

4f5d的能量传递，而在X射线激发下可能受表面缺陷影响未发现明显的Pr

4f5d发光。本文研究结果表明，BLP∶Pr

在作为真空紫外到UV-C光转换材料方面具有潜在的应用价值。本研究对于设计新型快响应闪烁体具有一定的指导意义。

Abstract

The radiative transition rate of Pr

4f5d is large

which makes it as a promising luminescence center of fast scintillators. Samples of Ba

La(PO

)

(BLP) activated with Pr

were prepared through high temperature solid state method and characterized by XRD

temperature-dependent luminescence spectra upon VUV-UV and X-ray excitations and decay curves. Efficient and thermal stable Pr

4f5d broad band emission with decay time of ~15 ns was observed. There is energy transfer from host to Pr

4f5d upon excitation at 172 nm

however

the energy transfer is absent upon X-ray excitation which is attributed to influence of defects on surface. The results indicate that BLP∶Pr

could be applied as an efficient VUV to UV-C converting material. In addition

the research is also important for designing novel fast scintillators.

关键词

真空紫外光Pr3+4f5d能量传递衰减曲线基质发光

Keywords

vacuum ultravioletPr3+4f5denergy transferdecay curveshost luminescence

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Related Author

Qiufeng SHI

Lei WANG

Haijie GUO

Ping HUANG

Cai’e CUI

Yan HUANG

TANG Wei

LIANG Chen

Related Institution

College of Physics and Optoelectronics， Taiyuan University of Technology

Beijing Synchrotron Radiation Facility， Institute of High Energy Physics， Chinese Academy of Sciences

School of Information and Communication， Shenzhen Institute of Information Technology

College of Materials， Xiamen University

State Key Laboratory of Physical Chemistry of Solid Surfaces， Xiamen University

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