Preparation of Pig Bone Nitrogen-doped Carbon Quantum Dots and Application in Detection of Co<sup>2+</sup>

Wen QIAN; Li HE; Wu-shuang PAN; Yan-hua CHEN; Hui WANG; Shu-liang LIU; Shu-juan CHEN; Ai-ping LIU

doi:10.37188/CJL.20210260

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Preparation of Pig Bone Nitrogen-doped Carbon Quantum Dots and Application in Detection of Co²⁺

Luminescence Applications and Interdisciplinary Fields | 更新时间：2021-11-23

- Preparation of Pig Bone Nitrogen-doped Carbon Quantum Dots and Application in Detection of Co²⁺
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 11, Pages: 1818-1827(2021)
- 作者机构：
  
  四川农业大学　食品学院，四川　雅安　625014
- 作者简介：
- 基金信息：
  
  Sub-projects of the National Key Research and development Program(2019YFC1605302-3)
- DOI：10.37188/CJL.20210260
  CLC： O482.31
- Published：01 November 2021，
  
  Received：04 August 2021，
  
  Revised：11 August 2021，
扫描看全文
Wen QIAN, Li HE, Wu-shuang PAN, et al. Preparation of Pig Bone Nitrogen-doped Carbon Quantum Dots and Application in Detection of Co²⁺. [J]. Chinese Journal of Luminescence 42(11):1818-1827(2021)
DOI：

Wen QIAN, Li HE, Wu-shuang PAN, et al. Preparation of Pig Bone Nitrogen-doped Carbon Quantum Dots and Application in Detection of Co²⁺. [J]. Chinese Journal of Luminescence 42(11):1818-1827(2021) DOI： 10.37188/CJL.20210260.

摘要

以猪骨和乙二胺为碳源和氮源，通过一步水热法合成了氮掺杂碳量子点(N-CQDs)，并优化其制备条件。通过透射电子显微镜(TEM)、傅里叶变换红外光谱(FT-IR)、X射线衍射图(XRD)、紫外-可见吸收光谱(UV-Vis)和X射线光电子能谱(XPS)技术，研究了N-CQDs的结构和光学性质及元素组成。所制备的N-CQDs具有较高的量子产率(26.4%)，平均粒径为2.34 nm，在365 nm紫外光照射下呈现出明亮的蓝色荧光。研究发现Co

对N-CQDs有良好的猝灭作用，从而建立了一种快速检测Co

的新方法。N-CQDs荧光猝灭强度与Co

浓度在0~15 μg/mL和30~80 μg/mL呈良好的线性关系，检出限为20 μg/L，加标回收率为97.26%~109.14%

RSD

3.24%，能够应用于实际水样中Co

含量的测定。

Abstract

Nitrogen-doped carbon quantum dots(N-CQDs) were successfully synthesized using pig bone and ethylenediamine as carbon and nitrogen sources by one-step hydrothermal method. Structure

optical properties and element composition of N-CQDs have been studied by transmission electron microscope(TEM)

Fourier transform infrared spectroscopy(FT-IR)

X-ray diffractometer patterns(XRD)

UV-Vis absorption spectroscopy(UV-Vis) and X-ray photoelectron spectroscopy(XPS) technologies. The synthesized N-CQDs have a high quantum yield(26.4%)

an average particle size of 2.34 nm

showing bright blue fluorescence under a 365 nm UV lamp. The study found that Co

had a good quenching effect on N-CQDs

so as to establish a new method for rapid detection of Co

. The fluorescence quenching intensity of N-CQDs has a good linear relationship with the concentration of Co

at 0-15 μg/mL and 30-80 μg/mL

the detection limit is 20 μg/L

and the recovery rate of standard addition is 97.26%-109.14%

RSD

3.24%

which can be applied to the determination of Co

content in actual water samples.

关键词

氮掺杂碳量子点猪骨荧光检测Co2+

Keywords

nitrogen-doped carbon quantum dotspig bonefluorescence detectionCo2+

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Related Author

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Shu-liang LIU

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刘爱平

Related Institution

College of Food Science，Sichuan Agricultural University，Yaan

School of Chemistry and Environmental Engineering， Changchun University of Science and Technology， Changchun 130022， China

Jilin Petrochemical North Chemical Industrial Company， Jilin 132022， China

Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University

Laboratory of Analytical Chemistry for Life Science, Institute of Chemistry, Chinese Academy of Sciences (CAS)

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⁰

Preparation of Pig Bone Nitrogen-doped Carbon Quantum Dots and Application in Detection of Co2+

DOI：10.37188/CJL.20210260

摘要

Abstract

关键词

Keywords

references

Preparation of Pig Bone Nitrogen-doped Carbon Quantum Dots and Application in Detection of Co²⁺