Research Progress of Metal-organic Frameworks in Organic Perovskite Solar Cells

Rui-fu HE; Fei-fan ZHOU; Jun-le QU; Jun SONG; Xuan ZHOU

doi:10.37188/CJL.20210208

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Research Progress of Metal-organic Frameworks in Organic Perovskite Solar Cells

Synthesis and Properties of Materials | 更新时间：2021-11-23

- Research Progress of Metal-organic Frameworks in Organic Perovskite Solar Cells
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 11, Pages: 1722-1738(2021)
- 作者机构：
  
  1.深圳大学　生物医学光子学研究中心/物理与光电工程学院，光电子器件与系统重点实验室，广东　深圳　518060
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(61620106016;61835009;61775145);China Postdoctoral Science Foundation(2019M653007);R & D plan of key fields in Guangdong Province(2019B110233004)
- DOI：10.37188/CJL.20210208
  CLC：
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Rui-fu HE, Fei-fan ZHOU, Jun-le QU, et al. Research Progress of Metal-organic Frameworks in Organic Perovskite Solar Cells. [J]. Chinese Journal of Luminescence 42(11):1722-1738(2021)
DOI：

Rui-fu HE, Fei-fan ZHOU, Jun-le QU, et al. Research Progress of Metal-organic Frameworks in Organic Perovskite Solar Cells. [J]. Chinese Journal of Luminescence 42(11):1722-1738(2021) DOI： 10.37188/CJL.20210208.

摘要

有机钙钛矿太阳能电池(OPSCs)的能量转换效率卓越，可以媲美单晶硅太阳能电池。但是，由于有机钙钛矿材料对水和空气十分敏感，因而当前面临着器件稳定性方面的挑战。金属有机框架(MOFs)与其衍生材料具有开放式孔道结构和非常大的比表面积，可以添加剂的形式用于电子、空穴传输层和混合钙钛矿-MOF光吸收层，或作为界面修饰层有效钝化钙钛矿吸收层的缺陷，并显著提升其能量转换效率及器件稳定性。本文介绍了MOFs的相关知识与MOFs结合OPSCs的研究现状，重点综述了近五年来MOFs在OPSCs中的应用与进展。

Abstract

Organic perovskite solar cells(OPSCs) have exhibited excellent power conversion efficiency, which is comparable to the monocrystalline silicon-based solar cells. But they still face the challenge of device stability due to the moisture and air sensitivities of organic perovskite materials. Metal-organic frameworks(MOFs) and their derivatives have open pore structure and large specific surface area. They can be used as additives in electron/hole transport layer, mixed perovskite MOF optical absorption layer, or as interface modification layer to effectively passivate the defects of perovskite absorption layer. In this way, the energy conversion efficiency and device stability of perovskite solar cells can be significantly improved. This paper introduces the related knowledge of MOFs and the research status of MOFs combined with OPSCs, focusing on the application and progress of MOFs in OPSCs in recent five years.

关键词

光伏技术金属有机框架材料钙钛矿太阳能电池

Keywords

photovoltaic technologymetal organic framework materialsperovskite solar cells

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