Luminescence Characteristics of Polyaluminate Broadband Cyan Phosphor

Wan-lu LI; Peng-peng DAI

doi:10.37188/CJL.20210178

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Luminescence Characteristics of Polyaluminate Broadband Cyan Phosphor

Synthesis and Properties of Materials | 更新时间：2021-09-13

- Luminescence Characteristics of Polyaluminate Broadband Cyan Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 9, Pages: 1376-1385(2021)
- 作者机构：
  
  新疆师范大学物理与电子工程学院　新疆矿物发光及其微结构重点实验室，新疆　乌鲁木齐　 830054
- 作者简介：
- 基金信息：
  
  the National Natural Science Foundation of China(517040);High-level Talents Introduction Program of the Ministry of Science and Technology of the Autonomous Region;Tianshan Talent Phase III;Key Laboratory of Education Department of Xinjiang Normal University(KWFG2002)
- DOI：10.37188/CJL.20210178
  CLC： O482.31
- Published：01 September 2021，
  
  Received：07 May 2021，
  
  Revised：06 June 2021，
扫描看全文
Wan-lu LI, Peng-peng DAI. Luminescence Characteristics of Polyaluminate Broadband Cyan Phosphor. [J]. Chinese Journal of Luminescence 42(9):1376-1385(2021)
DOI：

Wan-lu LI, Peng-peng DAI. Luminescence Characteristics of Polyaluminate Broadband Cyan Phosphor. [J]. Chinese Journal of Luminescence 42(9):1376-1385(2021) DOI： 10.37188/CJL.20210178.

摘要

通过高温固相法成功合成了系列宽带发射且发光颜色可调的Ba

∶

(0.01≤

≤0.09)荧光粉。X射线衍射、扫描电子显微镜和能量色散X射线能谱元素映射图像结果证明合成了纯相且元素分布均匀的铝酸盐荧光粉。在361 nm近紫外光激发下，随着Ce

掺杂浓度逐渐增加，Ba

∶

样品的发光强度逐渐增强且发光颜色由蓝光逐渐调节到青光。在

=0.05 mol时，Ba

0.95

∶0.05Ce

样品发光强度达到最大值，荧光内量子产率为30.8%。稳态光谱和荧光寿命结果证实，当Ce

掺杂浓度大于0.05 mol时，Ba

∶

样品发生浓度猝灭，该浓度猝灭主要归因于邻近的Ce

-Ce

之间的能量传递。Ba

0.95

∶0.05Ce

样品表现出光谱覆盖范围为365~650 nm、主峰位于450 nm的青光发射，其半高宽为120 nm。该不对称的宽发射带主要源于占据基质晶格中Ba1和Ba2格位的两个Ce

发光中心。将Ba

0.95

∶0.05Ce

和商用红色荧光粉混合制备出简单的可被紫外光(

=365 nm)激发的二色pc-WLEDs，并实现了显色指数和相关色温可调的全可见光谱白光。该宽带青色发光的Ba

0.95

∶0.05Ce

荧光粉在全光谱照明领域具有潜在应用。

Abstract

In this paper

a series of broadband-emitting and tunable Ba

∶

(0.01≤

≤0.09) phosphors were successfully synthesized by the high-temperature solid-phase method. The results of X-ray diffraction

scanning tunnel electron microscopy and EDS mapping proved that we synthesized aluminate phosphor with pure phase and uniform element distribution. Under the excitation of near-ultraviolet light wavelength of 361 nm

we found that the luminous intensity of Ba

∶

samples gradually increased and the luminous color of Ba

∶

samples gradually change from blue to cyan as the Ce

concentration increased. When

=0.05 mol

the luminescence intensity of the Ba

0.95

∶0.05Ce

sample reaches the maximum

and the fluorescence internal quantum yield is 30.8%. Steady-state spectroscopy and fluorescence lifetime results confirm that when the doped Ce

concentration is greater than 0.05 mol

the Ba

∶

sample undergoes concentration quenching

and the concentration quenching is mainly due to the energy transfer between adjacent Ce

-Ce

. The Ba

0.95

∶0.05Ce

sample exhibits a cyan emission with a spectral coverage of 365-650 nm

a main peak at 450 nm

and its full width at half maximum is 120 nm. The asymmetric broad emission band mainly originates from the two Ce

emission centers occupying the Ba1 and Ba2 sites in the host lattice. Simple dichromatic pc-WLEDs with UV excitation(

=365 nm)

full-visible-spectrum white light with adjustable color index and associated color temperature were prepared by mixing Ba

0.95

∶0.05Ce

with a commercial red phosphor. The Ba

0.95

∶0.05Ce

phosphor with broadband cyan luminescence developed in this work has potential applications in the field of full-spectrum lighting.

关键词

宽带发射青色光谱间隙Ce3+掺杂铝酸盐全光谱

Keywords

broadband emissioncyan spectral gapCe3+ dopedaluminatefull spectrum

references

DAI P P, CAO J, ZHANG X T, et al. Bright and high-color-rendering white light-emitting diode using color-tunable oxychloride and oxyfluoride phosphors [J].J. Phys. Chem. C, 2016, 120(33):18713-18720.

DAI P P, LEE S P, CHAN T S, et al. Sr3Ce(PO4)3∶Eu2+:a broadband yellow-emitting phosphor for near ultraviolet-pumped white light-emitting devices [J].J. Mater. Chem. C, 2016, 4(6):1170-1177.

ZHOU J, LIU Q L, XIA Z G. Structural construction and photoluminescence tuning via energy transfer in apatite-type solid-state phosphors [J].J. Mater. Chem. C, 2018, 6(16):4371-4383.

HUANG X Y. Cyan phosphors for full-visible-spectrum lighting:shining new light on high-CRI white pc-LEDs [J].Sci. Bull., 2019, 64(22):1649-1651.

HE J, GUO X X, CHEN Y B, et al. VUV/Vis Photoluminescence, site occupancy, and thermal-resistance properties of K4SrSi3O9∶Ce3+ [J].Chem. -Eur. J., 2018, 24(6):1287-1294.

ZHOU N L, WANG J L, HUANG J, et al. Enhanced color rendering index of organic/inorganic hybrid white light-emitting diodes with trans-1-(9-anthryl)-2-phenylethene derivatives as organic blue-green emitting materials [J].Opt. Mater., 2021, 113:110832.

ZHONG J Y, ZHUO Y, HARIYANI S, et al. Thermally robust and color-tunable blue-green-emitting BaMgSi4O10∶Eu2+, Mn2+ phosphor for warm-white LEDs [J].Inorg. Chem., 2020, 59(18):13427-13434.

LIU Y F, SILVER J, XIE R J, et al. An excellent cyan-emitting orthosilicate phosphor for NUV-pumped white LED application [J].J. Mater. Chem. C, 2017, 5(47):12365-12377.

ZHANG J C, ZHANG J L, ZHOU W L, et al. Composition screening in blue-emitting Li4Sr1+xCa0.97-x(SiO4)2∶Ce3+ phosphors for high quantum efficiency and thermally stable photoluminescence [J].ACS Appl. Mater. Interfaces, 2017, 9(36):30746-30754.

SUN L L, DEVAKUMAR B, LIANG J, et al. A broadband cyan-emitting Ca2LuZr2(AlO4)3∶Ce3+ garnet phosphor for near-ultraviolet-pumped warm-white light-emitting diodes with an improved color rendering index [J].J. Mater. Chem. C, 2020, 8(3):1095-1103.

SUN D S, ZHANG L L, HAO Z D, et al. Two Ce3+ centers induced broadband emission in Y3Si6N11∶Ce3+ yellow phosphor [J].Dalton Trans., 2018, 47(46):16723-16728.

ZHANG S, HAO Z D, ZHANG L L, et al. Observation of a red Ce3+ center in SrLu2O4∶Ce3+ phosphor and its potential application in temperature sensing [J].Dalton Trans., 2019, 48(16):5263-5270.

YOU S H, ZHUO Y, CHEN Q L, et al. Dual-site occupancy induced broadband cyan emission in Ba2CaB2Si4O14∶Ce3+ [J].J. Mater. Chem. C, 2020, 8(44):15626-15633.

ZHU Q Q, WANG L, HIROSAKI N, et al. Extra-broad band orange-emitting Ce3+-doped Y3Si5N9O phosphor for solid-state lighting:electronic, crystal structures and luminescence properties [J].Chem. Mater., 2016, 28(13):4829-4839.

WEI Q, DING J Y, WANG Y H. A novel tunable extra-broad yellow-emitting nitride phosphor with zero-thermal-quenching property [J].Chem. Eng. J., 2020, 386:124004.

ZHONG R X, ZHANG J H. Red photoluminescence due to energy transfer from Eu2+ to Cr3+ in BaAl12O19 [J].J. Lumin., 2010, 130(2):206-210.

XIAO L J, XIE Y, HE M R, et al. Luminescent properties of BaAl12O19∶Tb, Dy phosphors prepared by sol-gel method [J].J. Nanosci. Nanotechnol., 2014, 14(6):4570-4573.

WEI Y, CAO L, LV L M, et al. Highly efficient blue emission and superior thermal stability of BaAl12O19∶Eu2+ phosphors based on highly symmetric crystal structure [J].Chem. Mater., 2018, 30(7):2389-2399.

XIE Y, XIAO L J, HE M R, et al. Study on luminescence behavior of BaAl12O19∶Tb, Eu [J].J. Nanosci. Nanotechnol., 2011, 11(11):9908-9911.

YADAV R S, PANDEY S K, PANDEY A C. BaAl12O19∶Mn2+ green emitting nanophosphor for PDP application synthesized by solution combustion method and its vacuum ultra-violet photoluminescence characteristics [J].J. Lumin., 2011, 131(9):1998-2003.

ZHU Y T, LI C X, DENG D G, et al. High-sensitivity based on Eu2+/Cr3+ co-doped BaAl12O19 phosphors for dual-mode optical thermometry [J].J. Lumin., 2021, 237:118142.

SINGH V, SIVARAMAIAH G, RAO J L, et al. An electron paramagnetic resonance and optical study of Cr doped BaAl12O19 powders [J].Ceram. Int., 2014, 40(7):9629-9636.

WEI Y, GAO Z Y, YUN X H, et al. Abnormal Bi3+-activated NIR emission in highly symmetric XAl12O19 (X=Ba, Sr, Ca) by selective sites occupation [J].Chem. Mater., 2020, 32(19):8747-8753.

LIU D J, YUN X H, LI G G, et al. Enhanced cyan emission and optical tuning of Ca3Ga4O9∶Bi3+ for high-quality full-spectrum white light-emitting diodes [J].Adv. Opt. Mater., 2020, 8(22):2001037.

DAI P P, LI C, ZHANG X T, et al. A single Eu2+-activated high-color-rendering oxychloride white-light phosphor for white-light-emitting diodes [J].Light:Sci. Appl., 2016, 5(2):e16024-1-9.

LIU S Q, LIANG Y J, ZHU Y L, et al. Synthesis and luminescence properties of novel Ce3+ doped BaZrSi3O9 phosphors [J].Opt. Laser Technol., 2016, 84:1-8.

ZHANG S, HAO Z D, ZHANG L L, et al. Efficient blue-emitting phosphor SrLu2O4∶Ce3+ with high thermal stability for near ultraviolet (~400 nm) LED-Chip based white LEDs [J].Sci. Rep., 2018, 8(1):10463-1-8.

GAO T Y, ZHUANG W D, LIU R H, et al. Site occupancy and enhanced luminescence of broadband NIR gallogermanate phosphors by energy transfer [J].J. Am. Ceram. Soc., 2020, 103(1):202-213.

ZHAO D, ZHANG S R, FAN Y P, et al. Thermally stable phosphor KBa2(PO3)5∶Eu2+ with broad-band cyan emission caused by multisite occupancy of Eu2+ [J].Inorg. Chem., 2020, 59(13):8789-8799.

HONG S U, SINGH S P, PYO M, et al. Density functional theory calculations for the band gap and formation energy of Pr4-xCaxSi12O3+xN18-x; a highly disordered compound with low symmetry and a large cell size [J].Phys. Chem. Chem. Phys., 2017, 19(25):16702-16712.

BAI Q Y, ZHAO S L, XU Z, et al. Partial cation substitution of tunable blue-cyan-emitting Ba2B2O5∶Ce3+ for near-UV white LEDs [J].J. Am. Ceram. Soc., 2019, 102(10):6213-6226.

LI G, WANG Y H, ZENG W, et al. Photo-/cathodoluminescence and energy transfer properties of novel Ce3+ singly doped and Ce3+/Tb3+ codoped NaBaScSi2O7 phosphors [J].J. Mater. Chem. C, 2016, 4(15):3304-3312.

ZHANG Z J, LIANG J, SUN L L, et al. Synthesis and photoluminescence properties of near-UV-excitable cyan-emitting Ca2YHf2Ga3O12∶Ce3+ garnet phosphors[J].J. Lumin., 2020, 227:117544.

LI X S, GUO C J, WANG H W, et al. Green emitting Ba1.5Lu1.5Al3.5Si1.5O12∶Ce3+ phosphor with high thermal emission stability for warm WLEDs and FEDs [J].Ceram. Int., 2020, 46(5):5863-5870.

XIAO Y J, ZHANG D Y, CHANG C K, et al. Photoluminescence and afterglow behavior of Ce3+ activated Li2Sr0.9Mg0.1SiO4 phosphor [J].RSC Adv., 2019, 9(47):27386-2730.

SHENG X X, DAI P P, SUN Z Y, et al. Site-selective occupation of Eu2+ activators toward full-visible-spectrum emission in well-designed borophosphate phosphors [J].Chem. Eng. J., 2020, 395:125141.

TAKAHASHI H, YONEZAWA S, KAWAI M, et al. Preparation and optical properties of CeF3-containing oxide fluoride glasses [J].J. Fluorine Chem., 2008, 129(11):1114-1118.

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Related Institution

School of Physics and Electronic Engineering， Xinjiang Key Laboratory of Mineral Luminescence and Microstructure， Xinjiang Normal University， No.102， Xinyi Road

Xinjiang Key Laboratory for Luminescence Minerals and Optical Functional Materials， School of Physics and Electronic Engineering， Xinjiang Normal University

College of Electronic and Optical Engineering & College of Flexible Electronics（Future Technology）， Nanjing University of Posts and Telecommunications

School of Chemistry， Fuzhou University

CAS Key Laboratory of Design and Assembly of Functional Nanostructures， Fujian Key Laboratory of Nanomaterials， Fujian Institute of Research on The Structure of Matter， Chinese Academy of Sciences

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