Yttrium Aluminum Garnet Phosphor-in-glass with Improved Color-rendering for Laser Lighting
返回论文页
Invited Paper|更新时间:2021-10-17
|
Yttrium Aluminum Garnet Phosphor-in-glass with Improved Color-rendering for Laser Lighting
增强出版
Chinese Journal of LuminescenceVol. 42, Issue 10, Pages: 1619-1626(2021)
作者机构:
中国计量大学 光学与电子科技学院,浙江 杭州 310018
作者简介:
基金信息:
Preeminence Youth Science Funds of Zhejiang Province(LR19F050001);National Natural Science Foundation of China(51832005;62075203;51702339);National Key R&D Program of China(2017YFB0403100;2017YFB0403105)
Yao MENG, Qiang-qiang ZHU, Min-hang HUANG, et al. Yttrium Aluminum Garnet Phosphor-in-glass with Improved Color-rendering for Laser Lighting. [J]. Chinese Journal of Luminescence 42(10):1619-1626(2021)
DOI:
Yao MENG, Qiang-qiang ZHU, Min-hang HUANG, et al. Yttrium Aluminum Garnet Phosphor-in-glass with Improved Color-rendering for Laser Lighting. [J]. Chinese Journal of Luminescence 42(10):1619-1626(2021) DOI: 10.37188/CJL.20210166.
Yttrium Aluminum Garnet Phosphor-in-glass with Improved Color-rendering for Laser Lighting增强出版
Due to the spectrum defect of the red and green light component
the Y
3
Al
5
O
12
∶Ce
3+
(YAG∶Ce
3+
) phosphor-in-glass(PiG) cannot be applied in high-quality laser lighting. Based on the yttrium aluminum garnet luminescent material with wide spectrum
high luminous efficiency and high stability
the green-emitting Y
3
(Ga
Al)
5
O
12
∶Ce
3+
(YAGG∶Ce
3+
) and orange-emitting (Y
Gd)
3
Al
5
O
12
∶Ce
3+
(GdYAG∶Ce
3+
) phosphors were used as raw materials to fabricate PiG
and the PiG sample with improved color-rendering was achieved. The effects of fabrication temperature
phosphor-to-glass ratio
YAGG∶Ce
3+
/GdYAG∶Ce
3+
ratio
and the thickness on properties of PiG samples were studied in detail. By optimizing synthetic conditions and PiG components
the color rendering index (
R
a
) of achieved PiG can reach 79.7
showing 13.7% improvement compared with that of YAG∶Ce
3+
PiG. The luminescence saturation threshold of PiG sample with optimal
R
a
is 1.63 W/mm
2
and the luminous efficacy can reach 163.14 lm/W
suggesting a promising application in laser lighting for achieving better lighting effects.
SCHUBERT E F, KIM J K. Solid-state light sources getting smart[J].Science, 2005, 308(5726): 1274-1278.
XIE R J, HIROSAKI N. Review: silicon-based oxynitride and nitride phosphors for white LEDs[J].Sci. Technol. Adv. Mater., 2007, 8(7-8): 588-600.
ZHENG H, LUO X B, HU R, et al. Conformal phosphor coating using capillary microchannel for controlling color deviation of phosphor-converted white light-emitting diodes[J].Opt. Express, 2012, 20(5): 5092-5098.
WANG L, XIE R J, SUEHIRO T, et al. Down-conversion nitride materials for solid state lighting: recent advances and perspectives[J].Chem. Rev., 2018, 118(4): 1951-2009.
PIPREK J. Comparative efficiency analysis of GaN-based light-emitting diodes and laser diodes[J].Appl. Phys. Lett., 2016, 109(2): 021104-1-4.
SHEN Y C, MUELLER G O, WATANABE S, et al. Auger recombination in InGaN measured by photoluminescence[J].Appl. Phys. Lett., 2007, 91(14): 141101-1-3.
JRWIERER J J, TSAO J Y, SIZOV D S. Comparison between blue lasers and light-emitting diodes for future solid-state lighting[J].Laser Photon. Rev., 2013, 7(6): 963-993.
HU P, DING H, LIU Y F, et al. Recent progress of YAG∶Ce3+ for white laser diode lighting application[J].Chin. J. Lumin., 2020, 41(12): 1504-1528. (in Chinese)
PENG Y, MOU Y, WANG H, et al. Stable and efficient all-inorganic color converter based on phosphor in tellurite glass for next-generation laser-excited white lighting[J].J. Eur. Ceram. Soc., 2018, 38(16): 5525-5532.
XU J, YANG Y, GUO Z Q, et al. Comparative study of Al2O3-YAG∶Ce composite ceramic and single crystal YAG∶Ce phosphors for high-power laser lighting[J].Ceram. Int., 2020, 46(11): 17923-17928.
XU J, WANG J, GONG Y X, et al. Investigation of an LuAG∶Ce translucent ceramic synthesized via spark plasma sintering: towards a facile synthetic route, robust thermal performance, and highpower solid state laser lighting[J].J. Eur. Ceram. Soc., 2018, 38(1): 343-347.
KANG T W, PARK K W, RYU J H, et al. Strong thermal stability of Lu3Al5O12∶Ce3+ single crystal phosphor for laser lighting[J].J. Lumin., 2017, 191: 35-39.
CHEN D Q, XIANG W D, LIANG X J, et al. Advances in transparent glass-ceramic phosphors for white light-emitting diodes—a review[J].J. Eur. Ceram. Soc., 2015, 35(3): 859-869.
ZHU Q Q, YANG P F, WANG Z Y, et al. Additive-free Y2O3∶Eu3+ red-emitting transparent ceramic with superior thermal conductivity for high-power UV LEDs and UV LDs[J].J. Eur. Ceram. Soc., 2020, 40(6): 2426-2431.
ZHU Q Q, LI S X, YUAN Q, et al. Transparent YAG∶Ce ceramic with designed low light scattering for high-power blue LED and LD applications[J].J. Eur. Ceram. Soc., 2021, 41(1): 735-740.
ZHU Q Q, MENG Y, ZHANG H, et al. YAGG∶Ce phosphor-in-YAG ceramic: an efficient green color converter suitable for high-power blue laser lighting[J].ACS Appl. Electr. Mater., 2020, 2(8): 2644-2650.
XIANG R, LIANG X J, LI P Z, et al. A thermally stable warm WLED obtained by screen-printing a red phosphor layer on the LuAG∶Ce3+ PiG substrate[J].Chem. Eng. J., 2016, 306(15): 858-865.
LEE Y K, KIM Y H, HEO J, et al. Control of chromaticity by phosphor in glasses with low temperature sintered silicate glasses for LED applications[J].Opt. Lett.., 2014, 39(14): 4084-4087.
ZHENG P, LI S X, WANG L, et al. Unique color converter architecture enabling phosphor-in-glass(PiG) films suitable for high-power and high-luminance laser-driven white lighting[J].ACS Appl. Mater. Interfaces, 2018, 10(17): 14930-14940.
KIM E, UNITHRATTIL S, SOHN I S, et al. Facile one-step fabrication of 2-layered and 4-quadrant type phosphor-in-glass plates for white LEDs: an insight into angle dependent luminescence[J].Opt. Mater. Express, 2016, 6(3): 804-814.
HUANG J, HU X L, SHEN J J, et al. Facile synthesis of a thermally stable Ce3+∶Y3Al5O12 phosphor-in-glass for white LEDs[J].CrystEngComm, 2015, 17(37): 7079-7085.
ZHANG X J, YU J B, WANG J, et al. All-inorganic light convertor based on phosphor-in-glass engineering for next-generation modular high-brightness white LEDs/LDs[J].ACS Photonics, 2017, 4(4): 986-995.
WEI R, WANG L, ZHENG P, et al. On the luminance saturation of phosphor-in-glass (PiG) films for blue-laser-driven white lighting: Effects of the phosphor content and the film thickness[J].J. Eur. Ceram. Soc., 2019, 39(5): 1909-1917.
QIAN X L, SHI M M, YANG B B, et al. Thermostability and reliability properties studies of transparent Ce∶GdYAG ceramic by Gd substitution for white LEDs[J].Opt. Mater., 2019, 94: 172-181.