Lu2SrAl4SiO12∶Ce3+ Phosphor in Glass Film-on-sapphire and Its Application to Laser Lighting

Peng-fei WANG; Ping SUI; Shi-sheng LIN; Hang LIN; Yuan-sheng WANG

doi:10.37188/CJL.20210152

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Lu₂SrAl₄SiO₁₂∶Ce³⁺ Phosphor in Glass Film-on-sapphire and Its Application to Laser Lighting

Invited Paper | 更新时间：2021-10-17

- Lu₂SrAl₄SiO₁₂∶Ce³⁺ Phosphor in Glass Film-on-sapphire and Its Application to Laser Lighting
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 10, Pages: 1493-1501(2021)
- 作者机构：
  
  1.中国科学院福建物质结构研究所　中国科学院光电材料化学与物理院重点实验室，福建　福州　 350002
  2.福建师范大学　化学与材料学院，福建　福州　 350007
  3.中国福建光电信息科学与技术创新实验室(闽都创新实验室)，福建　福州　 350108
- 作者简介：
- 基金信息：
- DOI：10.37188/CJL.20210152
  CLC： O482.31
- Published：01 October 2021，
  
  Received：27 April 2021，
  
  Revised：12 May 2021，
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Peng-fei WANG, Ping SUI, Shi-sheng LIN, et al. Lu₂SrAl₄SiO₁₂∶Ce³⁺ Phosphor in Glass Film-on-sapphire and Its Application to Laser Lighting. [J]. Chinese Journal of Luminescence 42(10):1493-1501(2021)
DOI：

Peng-fei WANG, Ping SUI, Shi-sheng LIN, et al. Lu₂SrAl₄SiO₁₂∶Ce³⁺ Phosphor in Glass Film-on-sapphire and Its Application to Laser Lighting. [J]. Chinese Journal of Luminescence 42(10):1493-1501(2021) DOI： 10.37188/CJL.20210152.

摘要

“激光+荧光转换材料”产生强白光的方案已成为当下照明领域的研究热点之一。本文基于低温共烧技术制备了一种镶嵌Lu

SrAl

SiO

∶Ce

(LSAS∶Ce

)荧光粉的玻璃陶瓷膜-蓝宝石复合材料。研究表明，共烧时LSAS∶C

荧光粉受到的热侵蚀较少，共烧前后量子效率(~90%)未发生显著变化；并且该材料具有十分优异的抗热猝灭性能，~300 ℃时荧光积分强度仍保持了室温下的~70%，远优于YAG∶Ce

商用荧光粉。当蓝光激光功率密度达到3.0 W/mm

时，材料产生发光饱和，此时光通量为100.49 lm，满足室内照明需求。我们推测，热致饱和与光致饱和是发光亮度无法进一步提升的原因所在。相信通过材料组分、制备工艺的优化和光场调控手段的引入，可进一步提高发光亮度，使之适用于户外照明。

Abstract

"Laser+conversion material" strategy has become one of the hotspots in lighting field. Herein

a phosphor in glass film sintered on sapphire plate(PiG film-on-SP) embedded with Lu

SrAl

SiO

∶Ce

(LSAS∶Ce

) phosphor was prepared

via

low temperature co-sintering method.It was demonstrated that LSAS∶Ce

phosphor was less corroded by glass components during co-sintering

and so

the high quantum efficiency(~90%) was retained. Meanwhile

this material has better thermal quenching performance than commercial YAG∶Ce

phosphor. The fluorescence integral intensity at ~300 ℃ remains~70% of that at room temperature. "Luminescence saturation" takes place under 3.0 W/mm

blue laser irradiation

and the corresponding luminous flux is 100.49 lm

applicable to in-door scenarios. It was speculated that thermal saturation and optical saturation simultaneously occur

restricting the achievable brightness.After optimization of material composition

preparation process

as well as employing the light field regulation method

LSAS∶Ce

PiG film-on-SP with higher brightness will be hopefully applicable to out-door scenarios.

关键词

激光照明荧光粉荧光玻璃陶瓷石榴石结构

Keywords

laser lightingphosphorluminescent glass ceramicsgarnet structure

references

JRWIERER J J, TSAO J Y, SIZOV D S. Comparison between blue lasers and light-emitting diodes for future solid-state lighting[J].Laser Photonics Rev., 2013, 7(6): 963-993.

KOZAKI T, NAGAHAMA SI, MUKAI T. Recent progress of high-power GaN-based laser diodes[C].Proceeding of SPIE 2007 Novel In-plane Semiconductor Lasers Ⅵ, San Jose, 2007: 648503.

陈亮, 王健超, 潘涌, 等. 车用激光照明研究进展及关键技术分析[J].应用激光, 2018, 38(6): 1044-1048.

CHEN L, WANG J C, PAN Y, et al. Research progress and key technology analysis of laser illumination for automobile[J].Appl. Laser, 2018, 38(6): 1044-1048. (in Chinese)

LENEF A, RAUKAS M, WANG J, et al. Phosphor performance under high intensity excitation by InGaN laser diodes[J].ECS J. Solid State Sci. Technol., 2020, 9(1): 016019.

LENEF A, KELSOJ , ZHENGY , et al. Radiance limits of ceramic phosphors under high excitation fluxes[C].Proceedings SPIE 8814 Current Developments in Lens Design and Optical Engineering ⅪⅤ, San Diego, 2013: 884107.

CHEN D Q, XIANG W D, LIANG X J, et al.Advances in transparent glass-ceramic phosphors for white light-emitting diodes—a review[J].J. Eur. Ceram. Soc., 2015, 35(3): 859-869.

PARKK W, LIM S G, DERESSA G, et al.High power and temperature luminescence of Y3Al5O12∶Ce3+ bulky and pulverized single crystal phosphors by a floating-zone method[J].J. Lumin., 2015, 168: 334-338.

RAUKAS M, KELSO J, ZHENG Y, et al. Ceramic phosphors for light conversion in LEDs[J].ECS J. Solid State Sci. Technol., 2013, 2(2): R3168-R3176.

TANG Y R, ZHOU S M, CHEN C, et al. Composite phase ceramic phosphor of Al2O3-Ce∶YAG for high efficiency light emitting[J].Opt. Express, 2015, 23(14): 17923-17928.

YAO Q, HU P, SUN P, et al. YAG∶Ce3+ transparent ceramic phosphors brighten the next-generation laser-driven lighting[J].Adv. Mater., 2020, 32(19): 1907888.

YU J B, SI S C, LIU Y, et al. High-power laser-driven phosphor-in-glass for excellently high conversion efficiency white light generation for special illumination or display backlighting[J].J. Mater. Chem. C, 2018, 6(30): 8212-8218.

RAN W A, LE W A, PENG Z B, et al. On the luminance saturation of phosphor-in-glass (PiG) films for blue-laser-driven white lighting: effects of the phosphor content and the film thickness[J].J. Eur. Ceram. Soc., 2019, 39(5): 1909-1917.

YOU S H, LI S X, ZHENG P, et al. A thermally robust La3Si6N11∶Ce-in-glass film for high-brightness blue-laser-driven solid state lighting[J].Laser Photonics Rev., 2019, 13(2): 1800216-1-10.

WANG L, WEI R, ZHENG P, et al. Realizing high-brightness and ultra-wide-color-gamut laser-driven backlighting by using laminated phosphor-in-glass (PiG) films[J].J. Mater. Chem. C, 2020, 8(5): 1746-1754.

ZHANG X J, YU J B, WANG J, et al. Facile preparation and ultrastable performance of single-component white-light-emitting phosphor-in-glass used for high-power warm white LEDs[J].ACS Appl.Mater.Interfaces, 2015, 7(51): 28122-28127.

ZHENG P, LI S X, WANG L, et al. Unique color converter architecture enabling phosphor-in-glass(PiG) films suitable for high-power and high-luminance laser-driven white lighting[J].ACS Appl. Mater. Interfaces, 2018, 10(17): 14930-14940.

XIA L B, YUE Y Y, YANG X L, et al. Facile preparation and optical properties of Te/Pb-free Y3Al5O12∶Ce3+ phosphor-in-glass via a screen-printing route for high-power WLEDs[J].J. Eur. Ceram. Soc., 2019, 39(13): 3848-3855.

XU L Z, ZHAO G Y, MENG S H, et al. Enhanced luminescent performance for remote LEDs of Ce∶YAG phosphor-in-glass film on regular textured glass substrate by using chemical wet-etching[J].Ceram.Int., 2018, 44(18): 22283-22288.

ZHUANG Y J, LI C Y, LIU C L, et al. High-efficiency YAG∶Ce3+ glass-ceramic phosphor by an organic-free screen-printing technique for high-power WLEDs[J].Opt. Mater., 2020, 107: 110118.

XU X J, LI H, ZHUO Y, et al. High refractive index coating of phosphor-in-glass for enhanced light extraction efficiency of white LEDs[J].J. Mater. Sci., 2018, 53(2): 1335-1345.

NAM Y H, HAN K, CHUNG W J, et al. Color conversion properties of various thick-film phosphor-in-glasses depending on structural design for white LEDs[J].J. Am. Ceram. Soc., 2020, 103(8): 4266-4274.

PENG Y, WANG H, LIU J X, et al. Broad-band and stable phosphor-in-glass enabling ultrahigh color rendering for all-inorganic high-power WLEDs[J].ACS Appl. Electron. Mater., 2020, 2(9): 2929-2936.

LIN H, WANG B, HUANG Q M, et al. Lu2CaMg2(Si1-xGex)3O12∶Ce3+ solid-solution phosphors: bandgap engineering for blue-light activated afterglow applicable to AC-LED[J].J. Mater. Chem. C, 2016, 4(43): 10329-10338.

LIN H, HU T, CHENG Y, et al. Glass ceramic phosphors: towards long-lifetime high-power white light-emitting-diode applications—a review[J].Laser Photon. Rev., 2018, 12(6): 1700344-1-31.

LI S X, ZHU Q Q, WANG L, et al. CaAlSiN3∶Eu2+ translucent ceramic: a promising robust and efficient red color converter for solid state laser displays and lighting[J].J. Mater. Chem. C, 2016, 4(35): 8197-8205.

ZHENG P, LI S X, WEI R, et al. Unique design strategy for laser-driven color converters enabling superhigh-luminance and high-directionality white light[J].Laser Photon. Rev., 2019, 13(10): 1900147-1-10.

XIAO Y, XIAO W G, Zhang L L, et al. A highly efficient and thermally stable green phosphor (Lu2SrAl4SiO12∶Ce3+) for full-spectrum white LEDs[J].J. Mater. Chem. C, 2018, 6(45): 12159-12163.

HU T, MOLOKEEV M S, XIA Z G, et al. Aliovalent substitution toward reinforced structural rigidity in Ce3+-doped garnet phosphors featuring improved performance[J].J. Mater. Chem. C, 2019, 7(46): 14594-14600.

LI S X, WANG L, HIROSAKI N, et al. Color conversion materials for high-brightness laser-driven solid-state lighting[J].Laser Photon. Rev., 2018, 12(12): 1800173-1-29.

BELLANCOURT A R, MACKENS U, MOENCH H, et al. Blue diode pumped solid-state lasers for digital projection[J].Laser Phys., 2010, 20(3): 643-648.

WANG W C, CHENG C H, WANG H Y, et al. White-light color conversion with red/green/violet laser diodes and yellow light-emitting diode mixing for 34.8 Gbit/s visible lighting communication[J].Photonics Res., 2020, 8(8): 1398-1408.

SIJBOM H F, JOOS J J, MARTIN L I D J, et al. Luminescent behavior of the K2SiF6∶Mn4+ red phosphor at high fluxes and at the microscopic level[J].ECS J. Solid State Sci. Technol., 2016, 5(1): R3040-R3048.

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Related Author

Peng-fei WANG

Ping SUI

Shi-sheng LIN

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Related Institution

CAS Key Laboratory of Optoelectronic Materials Chemistry and Physics， Fujian Institute of Research on the Structure of Matter， Chinese Academy of Sciences

College of Chemistry and Materials Science， Fujian Normal University

Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China

School of Science， Shenyang Ligong University， Shenyang 110159， China

State Key Laboratory of Luminescence and Applications， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences， Changchun 130033， China

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