Research Progress of Mn<sup>4+</sup> Activated Typical LED Red Phosphors

Wei ZHANG; Meng-ting HE; Xu-sheng QIAO; Xian-ping FAN

doi:10.37188/CJL.20210148

您当前的位置：

首页 >

文章列表页 >

Research Progress of Mn⁴⁺ Activated Typical LED Red Phosphors

Invited Review | 更新时间：2021-09-13

- Research Progress of Mn⁴⁺ Activated Typical LED Red Phosphors
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 9, Pages: 1345-1364(2021)
- 作者机构：
  
  1.浙江大学材料科学与工程学院　硅材料国家重点实验室，浙江　杭州　 310027
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51872255)
- DOI：10.37188/CJL.20210148
  CLC：
扫描看全文
Wei ZHANG, Meng-ting HE, Xu-sheng QIAO, et al. Research Progress of Mn⁴⁺ Activated Typical LED Red Phosphors. [J]. Chinese Journal of Luminescence 42(9):1345-1364(2021)
DOI：

Wei ZHANG, Meng-ting HE, Xu-sheng QIAO, et al. Research Progress of Mn⁴⁺ Activated Typical LED Red Phosphors. [J]. Chinese Journal of Luminescence 42(9):1345-1364(2021) DOI： 10.37188/CJL.20210148.

摘要

Mn,4+,激活的红色荧光粉具有宽带吸收、窄带发射、色纯度高以及成本低的特点，在白光发光二极管(Light emitting diode,LED)室内照明、农业上辅助植物生长、背光显示等领域的研究备受关注。本文综述了Mn,4+,激活的典型LED用红色荧光粉研究进展。首先讨论了Mn,4+,发光的晶体场理论，归纳了近来报道的Mn,4+,激活氟化物与铝酸盐荧光粉；然后总结了如何从机理上优化光谱学性能、改善热猝灭性能和湿化学稳定性；最后说明了尚待解决的问题并展望了未来发展趋势。

Abstract

Mn,4+,-doped red phosphors have attracted much attention in the fields of white LED indoor lighting, agricultural plant growth and backlight displaying, due to the advantages of broad-band absorption, narrow-band emission, high color purity and low cost. This work reviews recent progress of Mn,4+, activated typical LED red phosphors. First, the crystal field theory of Mn,4+, is discussed. Then, the research progress of Mn,4+, activated fluorides and aluminates is summarized. Next, how to improve luminescence performance, thermal stability and moisture resistance are discussed theoretically. Finally, the main problems in the development of Mn,4+, doped red phosphors are presented and the future trends are prospected.

关键词

LED光致发光Mn4+红色荧光粉

Keywords

LEDphotoluminescenceMn4+red phosphors

references

SCHUBERT E F, KIM J K. Solid-state light sources getting smart [J].Science, 2005, 308(5726):1274-1278.

LI J H, YAN J, WEN D W, et al. Advanced red phosphors for white light-emitting diodes [J].J. Mater. Chem. C, 2016, 4(37):8611-8623.

ZHANG X J, YU J B, WANG J, et al. All-inorganic light convertor based on phosphor-in-glass engineering for next-generation modular high-brightness white LEDs/LDs [J].ACS Photonics, 2017, 4(4):986-995.

CHEN W T, SHEU H S, LIU R S, et al.Cation-size-mismatch tuning of photoluminescence in oxynitride phosphors [J].J. Am. Chem. Soc., 2012, 134(19):8022-8025.

ZHANG X J, TSAI Y T, WU S M, et al. Facile atmospheric pressure synthesis of high thermal stability and narrow-band red-emitting SrLiAl3N4∶Eu2+ phosphor for high color rendering index white light-emitting diodes [J].ACS Appl. Mater. Interfaces, 2016, 8(30):19612-19617.

FELDMANN C, JÜSTEL T, RONDA C R, et al. Inorganic luminescent materials:100 years of research and application [J].Adv. Funct. Mater., 2003, 13(7):511-516.

DAICHO H, IWASAKI T, ENOMOTO K, et al. A novel phosphor for glareless white light-emitting diodes [J].Nat. Commun., 2012, 3(1):1132-1-8.

ZEUNER M, SCHMIDT P J, SCHNICK W. One-pot synthesis of single-source precursors for nanocrystalline LED phosphors M2Si5N8∶Eu2+ (M=Sr, Ba) [J].Chem. Mater., 2009, 21(12):2467-2473.

XIE R J, HIROSAKI N. Silicon-based oxynitride and nitride phosphors for white LEDs—a review [J].Sci. Technol. Adv. Mater., 2007, 8(7-8):588-600.

STEIGERWALD D A, BHAT J C, COLLINS D, et al. Illumination with solid state lighting technology [J].IEEE J. Sel. Top. Quantum Electron., 2002, 8(2):310-320.

HUANG X Y. Red phosphor converts white LEDs [J].Nat. Photonics, 2014, 8(10):748-749.

ZHAO M, ZHANG Q Y, XIA Z G. Narrow-band emitters in LED backlights for liquid-crystal displays [J].Mater. Today, 2020, 40:246-265.

UHEDA K, HIROSAKI N, YAMAMOTO Y, et al. Luminescence properties of a red phosphor, CaAlSiN3∶Eu2+, for white light-emitting diodes [J].Electrochem. Solid-State Lett., 2006, 9(4):H22-H25.

LI Y Q, VAN STEEN J E J, VAN KREVEL J W H, et al. Luminescence properties of red-emitting M2Si5N8∶Eu2+(M=Ca, Sr, Ba) LED conversion phosphors [J].J. Alloys Compd., 2006, 417(1-2):273-279.

PUST P, WEILER V, HECHT C, et al. Narrow-band red-emitting Sr[LiAl3N4]∶Eu2+ as a next-generation LED-phosphor material [J].Nat. Mater., 2014, 13(9):891-896.

SCHMIECHEN S, SCHNEIDER H, WAGATHA P, et al. Toward new phosphors for application in illumination-grade white pc-LEDs:the nitridomagnesosilicates Ca[Mg3SiN4]∶Ce3+, Sr[Mg3SiN4]∶Eu2+, and Eu[Mg3SiN4] [J].Chem. Mater., 2014, 26(8):2712-2719.

VERSTRAETE R, SIJBOM H F, JOOS J J, et al. Red Mn4+-doped fluoride phosphors:why purity matters [J].ACS Appl. Mater. Interfaces, 2018, 10(22):18845-18856.

CHEN D Q, ZHOU Y, ZHONG J S. A review on Mn4+ activators in solids for warm white light-emitting diodes [J].RSC Adv., 2016, 6(89):86285-86296.

BLASSE G, GRABMAIER B C. Luminescent Materials [M].Berlin: Springer, 1994.

周亚运, 王玲燕, 邓婷婷, 等. Mn4+掺杂氟化物窄带发射红色荧光粉的研究进展[J].中国科学:技术科学, 2017, 47(11):1111-1125.

ZHOU Y Y, WANG L Y, DENG T T, et al. Recent advances in Mn4+-doped fluoride narrow-band red-emitting phosphors [J].Sci. Sinica Technol., 2017, 47(11):1111-1125. (in Chinese)

ADACHI S. Photoluminescence properties of Mn4+-activated oxide phosphors for use in white-LED applications:a review [J].J. Lumin., 2018, 202:263-281.

ADACHI S. Photoluminescence spectra and modeling analyses of Mn4+-activated fluoride phosphors:a review [J].J. Lumin., 2018, 197:119-130.

ADACHI S. Crystal-field and Racah parameters of Mn4+ ion in red and deep red-emitting phosphors:fluoride versus oxide phosphor [J].J. Lumin., 2020, 218:116829.

BRIK M G, CAMARDELLO S J, SRIVASTAVA A M, et al. Spin-forbidden transitions in the spectra of transition metal ions and nephelauxetic effect [J].ECS J. Solid State Sci. Technol., 2016, 5(1):R3067-1-11.

ZHU H M, LIN C C, LUO W Q, et al. Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes [J].Nat. Commun., 2014, 5(1):4312-1-10.

PAULUSZ A G. Efficient Mn(Ⅳ) emission in fluorine coordination [J].J. Electrochem. Soc., 1973, 120(7):942-947.

ADACHI S, TAKAHASHI T. Photoluminescent properties of K2GeF6∶Mn4+ red phosphor synthesized from aqueous HF/KMnO4 solution [J].J. Appl. Phys., 2009, 106(1):013516-1-6.

ARAI Y, TAKAHASHI T, ADACHI S. Photoluminescent properties of K2SnF6·H2O∶Mn4+ red phosphor [J].Opt. Mater., 2010, 32(9):1095-1101.

XU Y K, ADACHI S. Properties of Na2SiF6∶Mn4+ and Na2GeF6∶Mn4+ red phosphors synthesized by wet chemical etching [J].J. Appl. Phys., 2009, 105(1):013525-1-6.

ADACHI S, TAKAHASHI T. Direct synthesis and properties of K2SiF6∶Mn4+ phosphor by wet chemical etching of Si wafer [J].J. Appl. Phys., 2008, 104(2):023512-1-3.

LIN C C, MEIJERINK A, LIU R S. Critical red components for next-generation white LEDs [J].J. Phys. Chem. Lett., 2016, 7(3):495-503.

DENG T T, SONG E H, ZHOU Y Y, et al. Ultrafast green ion-exchange and short lifetime of efficient (NH4)3SiF7∶Mn4+ millimeter-sized single crystal for backlight displays [J].J. Alloys Compd., 2020, 847:156550-1-10.

XI L Q, PAN Y X, ZHU M M, et al. Abnormal site occupancy and high performance in warm WLEDs of a novel red phosphor, NaHF2∶Mn4+, synthesized at room temperature[J].Dalton Trans., 2017, 46(40):13835-13844.

WANG J Y, LANG T C, FANG S Q, et al. Discovery of an environmentally friendly water-soluble luminous material with interstitial site occupancy [J].ACS Susta. Chem. Eng., 2021, 9(7):2717-2726.

XU H P, HONG F, CHEN Z Y, et al. Green route, room-temperature synthesis and luminescence properties of a non-rare-earth doping Zn2+ based narrow-band red phosphor for WLEDs [J].J. Lumin., 2019, 216:116695.

ZHU Y W, CAO L Y, BRIK M G, et al. Facile synthesis, morphology and photoluminescence of a novel red fluoride nanophosphor K2NaAlF6∶Mn4+ [J].J. Mater. Chem. C, 2017, 5(26):6420-6426.

MING H, LIU L L, HE S A, et al. An ultra-high yield of spherical K2NaScF6∶Mn4+ red phosphor and its application in ultra-wide color gamut liquid crystal displays [J].J. Mater. Chem. C, 2019, 7(24):7237-7248.

KIM M, PARK W B, BANG B, et al. A novel Mn4+-activated red phosphor for use in light emitting diodes, K3SiF7∶Mn4+ [J].J. Am. Ceram. Soc., 2017, 100(3):1044-1050.

LIN H, HU T, HUANG Q M, et al. Non-rare-earth K2XF7∶Mn4+(X=Ta, Nb):a highly-efficient narrow-band red phosphor enabling the application in wide-color-gamut LCD [J].Laser Photonics Rev., 2017, 11(6):1700148-1-10.

FANG M H, YANG T H, LESNIEWSKI T, et al. Hydrogen-containing Na3HTi1-xMnxF8 narrow-band phosphor for light-emitting diodes [J].ACS Energy Lett., 2019, 4(2):527-533.

DONG X L, PAN Y X, JIA Y J, et al. Improved luminescence properties of a novel red dodec-fluoride phosphor Ba3Sc2F12∶Mn4+ with extraordinary thermal stability for WLED application [J].J. Mater. Chem. C, 2020, 8(18):6299-6305.

SIJBOM H F, VERSTRAETE R, JOOS J J, et al. K2SiF6∶Mn4+ as a red phosphor for displays and warm-white LEDs:a review of properties and perspectives [J].Opt. Mater. Express, 2017, 7(9):3332-3365.

HUANG L, ZHU Y W, ZHANG X J, et al. HF-free hydrothermal route for synthesis of highly efficient narrow-band red emitting phosphor K2Si1-xF6∶xMn4+ for warm white light-emitting diodes [J].Chem. Mater., 2016, 28(5):1495-1502.

LIAO C X, CAO R P, MA Z J, et al. Synthesis of K2SiF6∶Mn4+ phosphor from SiO2 powders via redox reaction in HF/KMnO4 solution and their application in warm-white LED [J].J. Am. Ceram. Soc., 2013, 96(11):3552-3556.

WEI L L, LIN C C, FANG M H, et al. A low-temperature co-precipitation approach to synthesize fluoride phosphors K2MF6∶Mn4+(M=Ge, Si) for white LED applications [J].J. Mater. Chem. C, 2015, 3(8):1655-1660.

WANG Z L, ZHOU Y Y, LIU Y, et al. Highly efficient red phosphor Cs2GeF6∶Mn4+ for warm white light-emitting diodes [J].RSC Adv., 2015, 5(100):82409-82414.

JIANG X Y, PAN Y X, HUANG S M, et al. Hydrothermal synthesis and photoluminescence properties of red phosphor BaSiF6∶Mn4+ for LED applications [J].J. Mater. Chem. C, 2014, 2(13):2301-2306.

YOSHIMURA K, FUKUNAGA H, IZUMI M, et al. White LEDs using the sharp β-sialon∶Eu phosphor and Mn-doped red phosphor for wide-color gamut display applications [J].J. Soc. Inf. Display, 2016, 24(7):449-453.

SHI D X, LIANG Z B, ZHANG X, et al. Synthesis, structure and photoluminescence properties of a novel Rb2NaAlF6∶Mn4+ red phosphor for solid-state lighting [J].J. Lumin., 2020, 226:117491.

ZHOU Y Y, YU C K, SONG E H, et al. Three birds with one stone:K2SiF6∶Mn4+ single crystal phosphors for high-power and laser-driven lighting [J].Adv. Opt. Mater., 2020, 8(23):2000976.

WANG Y J, YU C K, ZHOU Y Y, et al. Mn4+ doped narrowband red phosphors with short fluorescence lifetime and high color stability for fast-response backlight display application [J].J. Alloys Compd., 2021, 855:157347.

TAKAHASHI T, ADACHI S. Mn4+-activated red photoluminescence in K2SiF6 phosphor [J].J. Electrochem. Soc., 2008, 155(12):E183-E188.

WU Q Y, LIAO C X, PAN J Q, et al. HF-free molten salt route for synthesis of highly efficient and water-resistant K2SiF6∶Mn4+ for warm white LED [J].J. Am. Ceram. Soc., 2020, 103(12):6901-6912.

STOLL C, BANDEMEHR J, KRAUS F, et al. HF-free synthesis of Li2SiF6∶Mn4+:a red-emitting phosphor [J].Inorg. Chem., 2019, 58(9):5518-5523.

LI H, LIU Y, TANG S, et al. Luminescence properties of Mn4+ with high 2Eg level energy in the polyfluoride Na3Li3Sc2F12 [J].Dalton Trans., 2020, 49(33):11613-11617.

MENG S Q, ZHOU Y Y, WAN W, et al. Facile in situ synthesis of zeolite-encapsulating Cs2SiF6∶Mn4+ for application in WLEDs [J].J. Mater. Chem. C, 2019, 7(5):1345-1352.

JANG M K, CHO Y S, HUH Y D. Preparation of red-emitting BaSiF6∶Mn4+ phosphors for three-band white LEDs [J].Opt. Mater., 2020, 101:109734-1-5.

LI Q Y, YU L, WU W P, et al. Novel BaGe1-xSixF6∶Mn4+ (0⇐x⇒1) red phosphors for warm white LEDs:hydrothermal synthesis and photoluminescence properties [J].J. Alloys Compd., 2021, 852:156995.

HONG F, PANG G, DIAO L J, et al. Local structure modulation of Mn4+-doped Na2Si1-yGeyF6 red phosphors for enhancement of emission intensity, moisture resistance, thermal stability and application in warm pc-WLEDs [J].Dalton Trans., 2020, 49(39):13805-13817.

DONG Q Z, GUO C J, HE L, et al. Improving the moisture resistance and luminescent properties of K2TiF6∶Mn4+ by coating with CaF2 [J].Mater. Res. Bull., 2019, 115:98-104.

LIU Y M, WANG T M, TAN Z R, et al. Novel emission bands of Na2TiF6∶Mn4+ phosphors induced by the cation exchange method [J].Ceram. Int., 2019, 45(5):6243-6249.

WANG L Y, SONG E H, ZHOU Y Y, et al. An efficient and stable narrow band Mn4+-activated fluorotitanate red phosphor Rb2TiF6∶Mn4+ for warm white LED applications [J].J. Mater. Chem. C, 2018, 6(32):8670-8678.

FANG S Q, HAN T, LANG T C, et al. Synthesis of a novel red phosphor K2 xBa1-xTiF6∶Mn4+ and its enhanced luminescence performance, thermal stability and waterproofness [J].J. Alloys Compd., 2019, 808:151697.

HONG F, YANG L, XU H P, et al. A red-emitting Mn4+ activated phosphor with controlled morphology and two-dimensional luminescence nanofiber film:synthesis and application for high-performance warm white light-emitting diodes (WLEDs) [J].J. Alloys Compd., 2019, 808:151551.

LANG T C, HAN T, FANG S Q, et al. Improved phase stability of the metastable K2GeF6∶Mn4+ phosphors with high thermal stability and water-proof property by cation substitution [J].Chem. Eng. J., 2020, 380:122429.

HONG F, XU H P, PANG G, et al. Moisture resistance, luminescence enhancement, energy transfer and tunable color of novel core-shell structure BaGeF6∶Mn4+ phosphor [J].Chem. Eng. J., 2020, 390:124579.

JIA Y J, PAN Y X, ZHU J W, et al. In situ organic solvent-free synthesis of a novel red emitting Mn4+ doped KRbGeF6 phosphor at the room temperature [J].Dalton Trans., 2020, 49(38):13226-13232.

JIANG C Y, PENG M Y, SRIVASTAVA A M, et al. Mn4+-doped heterodialkaline fluorogermanate red phosphor with high quantum yield and spectral luminous efficacy for warm-white-light-emitting device application [J].Inorg. Chem., 2018, 57(23):14705-14714.

ZHANG L, XI L Q, PAN Y X, et al. Synthesis and improved photoluminescence of hexagonal crystals of Li2ZrF6∶Mn4+ for warm WLED application [J].Dalton Trans., 2018, 47(46):16516-16523.

HONG F, XU H P, YANG L, et al. Mn4+ nonequivalent-doped Al3+-based cryolite high-performance warm WLED red phosphors [J].New J. Chem., 2019, 43(37):14859-14871.

LIU Y M, WANG T M, ZHANG X Z, et al. Synthesis, luminescence properties and nephelauxetic effect of Nano stick phosphors K3AlF6∶Mn4+ for warm white LED [J].J. Mater. Sci.: Mater. Electron., 2019, 30(2):1870-1877.

DENG T T, SONG E H, ZHOU Y Y, et al. Implementation of high color quality, high luminous warm WLED using efficient and thermally stable Rb3AlF6∶Mn4+ as red color converter [J].J. Alloys Compd., 2019, 795:453-461.

MING H, ZHANG J F, LIU L L, et al. Luminescent properties of a Cs3AlF6∶Mn4+ red phosphor for warm white light-emitting diodes [J].ECS J. Solid State Sci. Technol., 2018, 7(9):R149-R155.

HUMAYOUN U B, KWON S B, SAMI S K, et al. (NH4)3AlF6∶Mn4+ a novel red phosphor-Facile synthesis, structure and luminescence characteristics [J].J. Alloys Compd., 2019, 776:594-598.

HONG F, XU H P, PANG G, et al. Optical characteristics, morphology evolution and thermal stability of novel red-emitting Mn4+-activated K2LiAl1-yGayF6 solid solution phosphors for high-performance warm WLED [J].J. Alloys Compd., 2020, 824:153818.

LIANG Z B, YANG Z F, XIE X L, et al. Electronic and optical properties of a novel fluoroaluminate red phosphor Cs2NaAl3F12∶Mn4+ with high color purity for white light-emitting diodes [J].Dalton Trans., 2019, 48(33):12459-12465.

LI D, PAN Y X, LIN Y, et al. Comparative investigation on solvent-related morphology and luminescence properties of a novel red phosphor NaRbSnF6∶Mn4+ for WLEDs application [J].J. Lumin., 2020, 228:117577.

DENG T T, WEI J R, GUO R F, et al. Investigation into chemical function in a Mn4+-activated Li-phase cryolite synthesis for green synthetic design [J].J. Alloys Compd., 2020, 819:153005-1-10.

ZHU M M, PAN Y X, WU M M, et al. Synthesis and improved photoluminescence of a novel red phosphor LiSrGaF6∶Mn4+ for applications in warm WLEDs [J].Dalton Trans., 2018, 47(37):12944-12950.

XU H P, HONG F, PANG G, et al. Co-precipitation synthesis, luminescent properties and application in warm WLEDs of Na3GaF6∶Mn4+ red phosphor [J].J. Lumin., 2020, 219:116960.

SHI D X, XIE X L, PU H Q, et al. Communication-luminescence properties of a novel l Rb2KGaF6∶Mn4+ red-emitting phosphor for solid-state lighting [J].ECS J. Solid State Sci. Technol., 2020, 9(12):126001.

MING H, LIU S F, LIU L L, et al. Highly regular, uniform K3ScF6∶Mn4+ phosphors:facile synthesis, microstructures, photoluminescence properties, and application in light-emitting diode devices [J].ACS Appl. Mater. Interfaces, 2018, 10(23):19783-19795.

WANG Y J, ZHOU Y Y, SONG E H. Ammonium salt conversion towards Mn4+ doped (NH4)2NaScF6 narrow-band red-emitting phosphor [J].J. Alloys Compd., 2019, 811:151945.

ZHU Y W, HUANG L, BRIK M G, et al. Anomalous photoluminescence from a K2LiInF6∶Mn4+ phosphor [J].J. Mater. Chem. C, 2020, 8(24):8085-8090.

MING H, ZHANG J F, LIU S F, et al. A green synthetic route to K2NbF7∶Mn4+ red phosphor for the application in warm white LED devices [J].Opt. Mater., 2018, 86:352-359.

JIA Y J, PAN Y X, LI Y Q, et al. Improved moisture-resistant and luminescence properties of a red phosphor based on dodec-fluoride K3RbGe2F12∶Mn4+ through surface modification [J].Inorg. Chem., 2021, 60(1):231-238.

KUMADA N, YANAGIDA S, TAKEI T, et al. Hydrothermal synthesis and crystal structure of new red phosphors, KNaMF7∶Mn4+ (M:Nb, Ta) [J].Mater. Res. Bull., 2019, 115:170-175.

HE S A, XU F F, HAN T T, et al. A Mn4+-doped oxyfluoride phosphor with remarkable negative thermal quenching and high color stability for warm WLEDs [J].Chem. Eng. J., 2020, 392:123657-1-10.

HU T, LIN H, CHENG Y, et al. A highly-distorted octahedron with a C2v group symmetry inducing an ultra-intense zero phonon line in Mn4+-activated oxyfluoride Na2WO2F4 [J].J. Mater. Chem. C, 2017, 5(40):10524-10532.

CAI P Q, QIN L, CHEN C L, et al. Luminescence, energy transfer and optical thermometry of a novel narrow red emitting phosphor:Cs2WO2F4∶Mn4+ [J].Dalton Trans, 2017, 46(41):14331-14340.

LIANG Z B, YANG Z F, TANG H J, et al. Synthesis, luminescence properties of a novel oxyfluoride red phosphor BaTiOF4∶Mn4+ for LED backlighting [J].Opt. Mater., 2019, 90:89-94.

MING H, ZHANG J F, LIU L L, et al. A novel Cs2NbOF5∶Mn4+ oxyfluoride red phosphor for light-emitting diode devices [J].Dalton Trans., 2018, 47(45):16048-16056.

DONG X L, PAN Y X, LI D, et al. A novel red phosphor of Mn4+ ion-doped oxyfluoroniobate BaNbOF5 for warm WLED applications [J].CrystEngComm, 2018, 20(37):5641-5646.

ZHANG Y T, QIAO X, WAN J, et al. Facile synthesis of monodisperse YAG∶Ce3+ microspheres with high quantum yield via an epoxide-driven sol-gel route [J].J. Mater. Chem. C, 2017, 5(35):8952-8957.

WAN J, ZHANG Y T, WANG Y, et al. Facile synthesis of monodisperse SrAl2O4∶Eu2+ cage-like microspheres with an excellent luminescence quantum yield [J].J. Mater. Chem. C, 2018, 6(13):3346-3351.

KANG H G, PARK J K, KIM C H, et al. Luminescence properties of MAl12O19∶Mn4+ (M=Ca, Sr, Ba) for UV LEDs[J].J. Ceram. Soc. Jpn., 2009, 117(1365):647-649.

ZHENG Y J, ZHANG H M, ZHANG H R, et al. Co-substitution in Ca1-xYxA112-xMgxO19 phosphors:local structure evolution, photoluminescence tuning and application for plant growth LEDs [J].J. Mater. Chem. C, 2018, 6(15):4217-4224.

MURATA T, TANOUE T, IWASAKI M, et al. Fluorescence properties of Mn4+ in CaAl12O19 compounds as red-emitting phosphor for white LED [J].J. Lumin., 2005, 114(3-4):207-212.

LIU Z, YUWEN M H, LIU J Q, et al. Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19∶Mn4+ nanofiber phosphors [J].Ceram. Int., 2017, 43(7):5674-5679.

CHEN Y B, WU K L, HE J, et al. A bright and moisture-resistant red-emitting Lu3Al5O12∶Mn4+, Mg2+ garnet phosphor for high-quality phosphor-converted white LEDs [J].J. Mater. Chem. C, 2017, 5(34):8828-8835.

SUN Q, WANG S Y, DEVAKUMAR B, et al. CaYAlO4∶Mn4+, Mg2+:an efficient far-red-emitting phosphor for indoor plant growth LEDs [J].J. Alloys Compd., 2019, 785:1198-1205.

HU J X, HUANG T H, ZHANG Y P, et al. Enhanced deep-red emission from Mn4+/Mg2+ co-doped CaGdAlO4 phosphors for plant cultivation [J].Dalton Trans., 2019, 48(7):2455-2466.

CHEN D Q, ZHOU Y, XU W, et al. Enhanced luminescence of Mn4+:Y3Al5O12 red phosphor via impurity doping [J].J. Mater. Chem. C, 2016, 4(8):1704-1712.

ZHU Y J, QIU Z X, AI B Y, et al. Significant improved quantum yields of CaAl12O19∶Mn4+ red phosphor by co-doping Bi3+ and B3+ ions and dual applications for plant cultivations [J].J. Lumin., 2018, 201:314-320.

ZHAO Y, SHI L, HAN Y J, et al. Luminescent properties of Zn2+-doped CaAl12O19∶Mn4+ deep-red phosphor for indoor plant cultivation [J].Ceram. Int., 2019, 45(7):8265-8270.

LI Y N, XIAO Z H, XU L Z, et al. Fluorescence enhancement mechanism in phosphor CaAl12O19:Mn4+ modified with alkali-chloride [J].Micro Nano Lett., 2013, 8(5):254-257.

XU Y D, ZHANG Y, WANG L, et al. Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19∶Mn4+ phosphors [J].J. Mater. Sci:Mater. Electron., 2017, 28(16):12032-12038.

SHU W, JIANG L L, XIAO S G, et al. GeO2 dopant induced enhancement of red emission in CaAl12O19∶Mn4+ phosphor [J].Mater. Sci. Eng. B, 2012, 177(2):274-277.

KONG L, LIU Y Y, DONG L P, et al. Enhanced red luminescence in CaAl12O19∶Mn4+ via doping Ga3+ for plant growth lighting [J].Dalton Trans., 2020, 49(6):1947-1954.

FANG S Q, LANG T C, HAN T, et al. Zero-thermal-quenching of Mn4+ far-red-emitting in LaAlO3 perovskite phosphor via energy compensation of electrons’ traps [J].Chem. Eng. J., 2020, 389:124297.

ZHANG Y L, HUANG Y D, LI M H, et al. Tuning the luminescence properties of Mn4+-activated CaYAlO4 phosphor by co-doping cations for indoor plant cultivation [J].J. Am. Ceram. Soc., 2020, 103(8):4373-4383.

LI X, LI W H, HOU B F, et al. Investigation of enhanced far-red emitting phosphor GdAlO3∶Mn4+ by impurity doping for indoor plant growth LEDs [J].Phys. B: Phys. Condens. Matter, 2020, 581:411953.

HU J X, ZHAO Y, CHEN B J, et al. An investigation of Mn4+ doped BeAl2O4 single crystal for WLEDs application [J].Ceram. Int., 2018, 44(16):20220-20226.

JI H P, HOU X H, MOLOKEEV M S, et al. Ultrabroadband red luminescence of Mn4+ in MgAl2O4 peaking at 651 nm [J].Dalton Trans., 2020, 49(17):5711-5721.

TRUNG D Q, TU N, QUANG N V, et al. Non-rare-earth dual green and red-emitting Mn-doped ZnAl2O4 phosphors for potential application in plan-growth LEDs [J].J. Alloys Compd., 2020, 845:156326.

TIAN C, LIN H, ZHANG D W, et al. Mn4+ activated Al2O3 red-emitting ceramic phosphor with excellent thermal conductivity [J].Opt. Express, 2019, 27(22):32666-32678.

SUN L L, DEVAKUMAR B, LIANG J, et al. Simultaneously enhanced far-red luminescence and thermal stability in Ca3Al4ZnO10∶Mn4+ phosphor via Mg2+ doping for plant growth lighting [J].J. Alloys Compd., 2019, 785:312-319.

SASAKI T, FUKUSHIMA J, HAYASHI Y, et al. Synthesis and photoluminescence properties of a novel Sr2Al6O11∶Mn4+ red phosphor prepared with a B2O3 flux [J].J. Lumin., 2018, 194:446-451.

GU S M, XIA M, ZHOU C, et al. Red shift properties, crystal field theory and nephelauxetic effect on Mn4+-doped SrMgAl10-yGayO17 red phosphor for plant growth LED light [J].Chem. Eng. J., 2020, 396:125208.

CAO R, AN C S, TIAN L H. Photoluminescence properties of novel deep red-emission phosphor BaZn1.06Al9.94O17∶Mn4+ [J].J. Lumin., 2019, 210:66-69.

WANG B, LIN H, HUANG F, et al. Non-rare-earth BaMgAl10-2xO17∶xMn4+, xMg2+:a narrow-band red phosphor for use as a high-power warm w-LED [J].Chem. Mater., 2016, 28(10):3515-3524.

ZHONG Y, ZHOU Y, ZHOU C, et al. Two targets with one strategy:insights into the role of aluminum atoms on the luminescence properties and thermal stability in Mn4+-doped calcium aluminozincate phosphor [J].J. Alloys Compd., 2020, 849:156567.

WU Y B, ZHUANG Y X, XIE R J, et al. Novel Mn4+ doped red phosphors composed of MgAl2O4 and CaAl12O19 phases for light-emitting diodes [J].Dalton Trans., 2020, 49(11):3606-3614.

ZHU Y T, LI C X, DENG D G, et al. A high-sensitivity dual-mode optical thermometry based on one-step synthesis of Mn2+:BaAl12O19-Mn4+:SrAl12O19 solid solution phosphors [J].J. Alloys Compd., 2021, 853:157262.

XIONG F B, LIN L X, LIN H F, et al. Synthesis and photoluminescence of Mn4+ in M4Al14O25(M=Sr or Mg) compounds as red-light phosphors for white LED [J].Opt. Laser Technol., 2019, 117:299-303.

WANG B, LIN H, XU J, et al. CaMg2Al16O27∶Mn4+-based red phosphor:a potential color converter for high-powered warm W-LED [J].ACS Appl. Mater. Interfaces, 2014, 6(24):22905-22913.

WU Y B, ZHUANG Y X, LV Y, et al. A high-performance non-rare-earth deep-red-emitting Ca14-xSrxZn6Al10O35∶Mn4+ phosphor for high-power plant growth LEDs [J].J. Alloys Compd., 2019, 781:702-709.

XIA Z G, LIU Q L. Progress in discovery and structural design of color conversion phosphors for LEDs [J].Prog. Mater. Sci., 2016, 84:59-117.

DONG L P, ZHANG L, JIA Y C, et al. Enhancing luminescence and controlling the Mn valence state of Gd3Ga5-x-δAlx-y+δO12∶yMn phosphors by the design of the garnet structure [J].ACS Appl. Mater. Interfaces, 2020, 12(6):7334-7344.

ZHONG Y, GAI S J, XIA M, et al. Enhancing quantum efficiency and tuning photoluminescence properties in far-red-emitting phosphor Ca14Ga10Zn6O35∶Mn4+ based on chemical unit engineering [J].Chem. Eng. J., 2019, 374:381-391.

SENDEN T, VAN DIJK-MOES R J A, MEIJERINK A. Quenching of the red Mn4+ luminescence in Mn4+-doped fluoride LED phosphors [J].Light: Sci. Appl., 2018, 7(1):8-1-13.

BLASSE G. Energy transfer in oxidic phosphors [J].Phys. Lett. A, 1968, 28(6):444-445.

HUANG D Y, DANG P P, LIAN H Z, et al. Luminescence and energy-transfer properties in Bi3+/Mn4+-codoped Ba2GdNbO6 double-perovskite phosphors for white-light-emitting diodes [J].Inorg. Chem., 2019, 58(22):15507-15519.

WEI Y, YANG H, GAO Z Y, et al. Strategies for designing antithermal-quenching red phosphors [J].Adv. Sci., 2020, 7(8):1903060-1-9.

NAIR G B, SWART H C, DHOBLE S J. A review on the advancements in phosphor-converted light emitting diodes (pc-LEDs):phosphor synthesis, device fabrication and characterization [J].Prog. Mater. Sci., 2020, 109:100622-1-36.

DORENBOS P. Charge transfer bands in optical materials and related defect level location [J].Opt. Mater., 2017, 69:8-22.

GAI S J, ZHU H F, GAO P X, et al. Structure analysis, tuning photoluminescence and enhancing thermal stability on Mn4+-doped La2-xYxMgTiO6 red phosphor for agricultural lighting [J].Ceram. Int., 2020, 46(12):20173-20182.

HUANG D C, ZHU H M, DENG Z H, et al. Moisture-resistant Mn4+-doped core-shell-structured fluoride red phosphor exhibiting high luminous efficacy for warm white light-emitting diodes [J].Angew. Chem. Int. Ed., 2019, 58(12):3843-3847.

HUANG L, LIU Y, YU J B, et al. Highly stable K2SiF6∶Mn4+@K2SiF6 composite phosphor with narrow red emission for white LEDs [J].ACS Appl. Mater. Interfaces, 2018, 10(21):18082-18092.

YU H J, WANG B C, BU X Y, et al. A facile in situ surface-coating passivation strategy for improving the moisture resistance of Mn4+-activated fluoride red phosphor [J].Ceram. Int., 2020, 46(11):18281-18286.

Views

283

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Mn⁴⁺-doped Red-emitting Fluoride Phosphors with Intense Zero Phonon Line

Luminescence Performance of Colloidal Quantum Dots Regulated by Band Edge Mode in One-dimensional Photonic Crystals

Photoluminescence and Temperature Sensing Properties of Color-tunable CsLa（WO₄）₂∶Pr³⁺ Phosphors

Mn⁴⁺-doped Red-emitting Oxyfluoride Phosphors with Intense Zero Phonon Line

Related Author

No data

Related Institution

State Key Laboratory of Silicon Materials & School of Materials Science and Engineering， Zhejiang University， H angzhou

Key Laboratory of Advanced Energy Catalytic and Functional Material Preparation of Zhengzhou City， School of Materials Science and Engineering， Zhengzhou University

School of Materials Science and Engineering， Zhengzhou University （Luoyang Campus）

Intelligent Manufacturing， Luoyang Institute of Science and Technology

State Key Laboratory of Luminescence and Applications， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Research Progress of Mn4+ Activated Typical LED Red Phosphors

DOI：10.37188/CJL.20210148

摘要

Abstract

关键词

Keywords

references

Research Progress of Mn⁴⁺ Activated Typical LED Red Phosphors