High-performance Organic Transistor Ammonia Sensor with Laminated Ultrathin Film Structure

Han CHEN; Qi HU; Long-zhen QIU; Xiao-hong WANG

doi:10.37188/CJL.20210107

您当前的位置：

首页 >

文章列表页 >

High-performance Organic Transistor Ammonia Sensor with Laminated Ultrathin Film Structure

Device Fabrication and Physics | 更新时间：2021-06-18

- High-performance Organic Transistor Ammonia Sensor with Laminated Ultrathin Film Structure
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 6, Pages: 871-879(2021)
- 作者机构：
  
  合肥工业大学光电技术研究院，特种显示技术国家工程实验室，现代显示技术省部共建国家重点实验室培育基地，安徽合肥　 230009
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51703047);Distinguished Youth Foundation of Anhui Province(1808085J03);Fundamental Research Funds for the Central Universities(JZ2018HGPB0276;JZ2020YYPY0091)
- DOI：10.37188/CJL.20210107
  CLC： TP212
- Published：01 June 2021，
  
  Received：23 March 2021，
  
  Revised：06 April 2021，
扫描看全文
Han CHEN, Qi HU, Long-zhen QIU, et al. High-performance Organic Transistor Ammonia Sensor with Laminated Ultrathin Film Structure. [J]. Chinese Journal of Luminescence 42(6):871-879(2021)
DOI：

Han CHEN, Qi HU, Long-zhen QIU, et al. High-performance Organic Transistor Ammonia Sensor with Laminated Ultrathin Film Structure. [J]. Chinese Journal of Luminescence 42(6):871-879(2021) DOI： 10.37188/CJL.20210107.

摘要

研究了基于给-受体共轭聚合物双(2-氧代二氢吲哚-3-亚基) -苯并二呋喃-二酮和联噻吩(PBIBDF-BT) 超薄膜叠层晶体管的电学性能及氨气传感特性。使用相分离方法以及转移-刻蚀步骤制备了不同堆叠层数的PBIBDF-BT超薄膜。系统地研究了PBIBDF-BT超薄膜堆叠层数与器件性能的关系。实验结果表明，单层PBIBDF-BT超薄膜器件对氨气具有良好的传感性能，电学性能较差。超薄膜叠层能够有效提高传感器的电学性能，随着超薄膜叠层数量的增加，器件迁移率不断上升;超薄膜层数增加为3层及更多时迁移率上升趋势变缓，迁移率最大值为0.58 cm

·V

-1

·s

-1

。超薄膜叠层器件氨气传感性能在层数为2层后呈现下降趋势。通过PBIBDF-BT超薄膜叠层方法，制备出在1.0×10

-5

氨气环境下，迁移率为0.23 cm

·V

-1

·s

-1

、源漏电流变化百分比为90.7%、性能良好的OFET氨气传感器。

Abstract

The electrical properties and the ammonia sensing transistor characteristics of ultrathin film laminated transistors based on donor-acceptor conjugated polymer bis(2-oxoindole-3-ylidene)-benzodifuran-dione and bithiophene(PBIBDF-BT) were studied. The PBIBDF-BT ultrathin films with different stacking layers were prepared by phase separation method and transfer-etching step. The relationship between the number of PBIBDF-BT ultrathin film stacks and the performance of the device were systematically studied. Experimental results indicate that the single-layer PBIBDF-BT ultrathin film device has good sensing performance for ammonia

but the electrical performance is poor. Ultrathin film stacking can effectively improve the electrical performance of the device. As the number of ultrathin film stacks increases

the device mobility increased. When the number of ultrathin film layers increases to 3 layers or more

the increasing trend of mobility slows down and the maximum mobility is 0.58 cm

·V

-1

·s

-1

. The ammonia sensing performance of ultrathin film laminate devices shows a downward trend when the number of layers is 2. Through the PBIBDF-BT ultrathin film stacking method

an OFET ammonia gas sensor with good performance was prepared under 1.0×10

-5

ammonia environment

with a mobility of 0.23 cm

·V

-1

·s

-1

the source-drain current change percentage of 90.7%.

关键词

有机超薄膜晶体管给体-受体共轭聚合物氨气检测超薄膜叠层

Keywords

organic ultra-thin film transistordonor-acceptor conjugated polymerammonia gas detectionultrathin film stack

references

YU S H, CHO J, SIM K M, et al. Morphology-driven high-performance polymer transistor-based ammonia gas sensor [J].ACS Appl. Mater. Interfaces, 2016, 8(10):6570-6576.

TRUL A A, SIZOV A S, CHEKUSOVA V P, et al. Organosilicon dimer of BTBT as a perspective semiconductor material for toxic gas detection with monolayer organic field-effect transistors [J].J. Mater. Chem. C, 2018, 6(36):9649-9659.

SOMEYA T, DODABALAPUR A, HUANG J, et al. Chemical and physical sensing by organic field-effect transistors and related devices [J].Adv. Mater., 2010, 22(34):3799-3811.

TORSI L, MAGLIULO M, MANOLI K, et al. Organic field-effect transistor sensors:a tutorial review [J].Chem. Soc. Rev., 2013, 42(22):8612-8628.

ZHANG C C, CHEN P L, HU W P. Organic field-effect transistor-based gas sensors [J].Chem. Soc. Rev., 2015, 44(8):2087-2107.

LI H, SHI W, SONG J, et al. Chemical and biomolecule sensing with organic field-effect transistors [J].Chem. Rev., 2019, 119(1):3-35.

ZANG Y P, ZHANG F J, HUANG D Z, et al. Specific and reproducible gas sensors utilizing gas-phase chemical reaction on organic transistors [J].Adv. Mater., 2014, 26(18):2862-2867.

HAN S J, ZHUANG X M, JIANG Y M, et al. Poly(vinyl alcohol) as a gas accumulation layer for an organic field-effect transistor ammonia sensor [J].Sens. Actuators B:Chem., 2017, 243:1248-1254.

YANG Y, ZHANG G X, LUO H W, et al. Highly sensitive thin-film field-effect transistor sensor for ammonia with the DPP-bithiophene conjugated polymer entailing thermally cleavable tert-butoxy groups in the side chains [J].ACS Appl. Mater. Interfaces, 2016, 8(6):3635-3643.

YANG G, DI C A, ZHANG G X, et al. Highly sensitive chemical-vapor sensor based on thin-film organic field-effect transistors with benzothiadiazole-fused-tetrathiafulvalene [J].Adv. Funct. Mater., 2013, 23(13):1671-1676.

ZHANG S Q, ZHAO Y W, DU X W, et al. Gas sensors based on nano/microstructured organic field-effect transistors [J].Small, 2019, 15(12):1805196-1-16.

GE F, WEI S Y, LIU Z, et al. Tailoring structure and field-effect characteristics of ultrathin conjugated polymer films via phase separation [J].ACS Appl. Mater. Interfaces, 2018, 10(11):9602-9611.

JI S L, WANG H B, WANG T, et al. A high-performance room-temperature NO2 sensor based on an ultrathin heterojunction film [J].Adv. Mater., 2013, 25(12):1755-1760.

LIU X L, LUO X G, NAN H Y, et al. Epitaxial ultrathin organic crystals on graphene for high-efficiency phototransistors [J].Adv. Mater., 2016, 28(26):5200-5205.

ZHU Y Y, XIE Q, SUN Y, et al. High-performance NO2 sensors based on ultrathin heterogeneous interface layers [J].Adv. Mater. Interfaces, 2020, 7(1):1901579.

CHEN H L, DONG S H, BAI M L, et al. Solution-processable, low-voltage, and high-performance monolayer field-effect transistors with aqueous stability and high sensitivity [J].Adv. Mater., 2015, 27(12):2113-2120.

CHEN H M, XING X, ZHU M, et al. Low-voltage, high-performance flexible organic field-effect transistors based on ultrathin single-crystal microribbons [J].ACS Appl. Mater. Interfaces, 2019, 11(37):34188-34195.

FABIANO S, MUSUMECI C, CHEN Z H, et al. From monolayer to multilayer N-channel polymeric field-effect transistors with precise conformational order [J].Adv. Mater., 2012, 24(7):951-956.

FABIANO S, YOSHIDA H, CHEN Z H, et al. Orientation-dependent electronic structures and charge transport mechanisms in ultrathin polymeric n-channel field-effect transistors [J].ACS Appl. Mater. Interfaces, 2013, 5(10):4417-4422.

D'INNOCENZO V, LUZIO A, ABDALLA H, et al. Two-dimensional charge transport in molecularly ordered polymer field-effect transistors [J].J. Mater. Chem. C, 2016, 4(47):11135-11142.

GE F, ZHANG C, YAO H B, et al. Precisely controlling the structure of ultrathin semiconducting films by a laminating method for high-performance organic field-effect transistors [J].ACS Appl. Mater. Interfaces, 2019, 11(51):48147-48154.

ZHANG G B, LI P, TANG L X, et al. A bis(2-oxoindolin-3-ylidene)-benzodifuran-dione containing copolymer for high-mobility ambipolar transistors [J].Chem. Commun., 2014, 50(24):3180-3183.

WANG Q H, ZHU M, WU D, et al. Phototransistors based on a donor-acceptor conjugated polymer with a high response speed [J].J. Mater. Chem. C, 2015, 3(41):10734-10741.

Views

193

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

No data

Related Author

Han CHEN

Qi HU

Long-zhen QIU

Xiao-hong WANG

Related Institution

National Engineering Lab of Special Display Technology， National Key Lab of Advanced Display Technology， Academy of Opto-Electronic Technology， Hefei University of Technology

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰