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Luminescence Properties of Dy3+ Doped Lanthanum Fluoride Crystal by Multi-crucible Temperature Gradient Technology
- Chinese Journal of Luminescence Vol. 42, Issue 2, Pages: 158-164(2021)
- 作者机构：
1.杭州医学院 医学影像学院, 浙江 杭州 310053
2.云南大学 物理与天文学院, 云南 昆明 650500
3.安徽省繁昌第一中学, 安徽 芜湖 241200
4.同济大学 物理科学与工程学院, 上海 200092
5.昆明物理研究所, 云南 昆明 650223
- 作者简介：
- 基金信息：National Natural Science Foundation of China;the Opening Project of State Key Laboratory of Key Laboratory of Transparent Opto-functional Inorganic Materials, Chinese Academy of Science
DOI：10.37188/CJL.20200330
CLC：
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Fang-fang RUAN, Long YANG, Guang HU, et al. Luminescence Properties of Dy3+ Doped Lanthanum Fluoride Crystal by Multi-crucible Temperature Gradient Technology. [J]. Chinese Journal of Luminescence 42(2):158-164(2021)
Fang-fang RUAN, Long YANG, Guang HU, et al. Luminescence Properties of Dy3+ Doped Lanthanum Fluoride Crystal by Multi-crucible Temperature Gradient Technology. [J]. Chinese Journal of Luminescence 42(2):158-164(2021) DOI： 10.37188/CJL.20200330.
摘要
采用多坩埚温度梯度法（Multi-crucible temperature gradient technology，MC-TGT）制备了Dy,3+,掺杂氟化镧（Dy,3+,：LaF,3,）晶体。通过电感耦合等离子体发射光谱仪、透射光谱、吸收光谱、荧光光谱等手段对Dy,3+,在LaF,3,晶体中的实际掺杂浓度、中红外透过光谱、可见光波段光谱特性等进行了研究。实验结果表明，Dy,3+,在LaF,3,晶体中的分凝系数约为0.8；格位浓度随着Dy,3+,掺杂浓度提高而增加，2% Dy：LaF,3,晶体中的格位浓度达5.90×10,20, ions·cm,-3,。在1% Dy：LaF,3,晶体中，采用400 nm光激发，发光中心波长位于601 nm的发射谱带强度最大，位于511 nm的发射峰最宽，半高宽达152 nm；改用450 nm光激发，最强发射峰移至677 nm，最宽发射峰位于568 nm处。提高Dy,3+,掺杂浓度到2%，采用400 nm或450 nm光激发，发光中心波长均位于478 nm和571 nm。在透射光谱2.5~9 μm范围内，Dy：LaF,3,晶体（厚度为0.96 mm）红外波段透过率达85%以上。Dy：LaF,3,晶体有望在可见光、中红外等激光领域得到应用。
Abstract
Novel Dy,3+, doped LaF,3, crystals is synthesized by multi-crucible temperature gradient technology(MC-TGT). The crystallographic sites concentration is up to 5.90×10,20, ions·cm,-3, for 2%Dy:LaF,3, following the segregation coefficient of 0.8 measured by inductively coupled plasma emission spectrometer. The photoluminescence spectra of 1%Dy:LaF,3, show the strongest wavelength peaked at 601 nm and the widest wavelength band centering at 511 nm under excitation wavelength of 400 nm. By changing the excitation wavelength to 450 nm, the strongest wavelength shifts to 677 nm and the widest wavelength band shifts to 568 nm in 1%Dy:LaF,3, respectively. In the case of 2%Dy:LaF,3, two main central wavelengths at 478 nm and 571 nm are observed under excitation wavelength of 400 nm or 450 nm. The optical quality of as-grown Dy,3+,:LaF,3, crystal is characterized by transmission spectra at the range of 2.5-11 μm. The optical transmission of Dy:LaF,3, crystal with thickness of 0.96 mm reaches over 85%, indicating a high-optical quality in the range of 2.5-9 μm. Thus, Dy:LaF,3, has great application potentials in visible and mid-infrared laser.
关键词
温度梯度法镝离子氟化镧晶体中红外透过光谱荧光光谱
Keywords
temperature gradient technologyDy3+LaF3 crystalmid-infrared transmission spectraphotoluminescence
references
沈德元, 范滇元.中红外激光器[M].北京:国防工业出版社, 2015.
SHEN D Y, FAN D Y. Mid-infrared Lasers [M]. Beijing:National Defense Industry Press, 2015. (in Chinese)
王燕, 李坚富, 游振宇, 等. 2.5~5.0μm波段中红外激光晶体的生长和性能研究[J].中国科学(技术科学), 2016, 46(9):894-909.
WANG Y, LI J F, YOU Z Y, et al.. Bulk crystal growth and characterization of 2.5-5.0μm mid-infrared laser crystals[J].Sci. China Phys. Mech. Astron., 2010, 53(6):1054-1059. (in Chinese)
DUAN X M, SHEN Y J, GAO J, et al.. Active Q-switching operation of slab Ho:SYSO laser wing-pumped by fiber coupled laser diodes[J].Opt. Express, 2019, 27(8):11455-11461.
YANG K J, FENG T L, ZHAO S Z, et al.. Spectral and laser performance of a Tm3+:ScYSiO5 crystal[J].J. Alloys Compd., 2017, 712:412-417.
ZHENG L H, XU J, SU L B,et al.. Crystal structure and optical study of Tm:Sc2SiO5 single crystal[J].Appl. Phys. Lett., 2010, 96(12):121908.
DUAN X M, LI L J, ZHENG L H, et al.. Efficient intracavity-pumped Ho:SSO laser with cascaded in-band pumping scheme[J].Infrared Phys. Technol., 2018, 94:7-10.
ZHAO Y G, WANG Y C, ZHANG X Z, et al.. 87 fs mode-locked Tm, Ho:CaYAlO4 laser at~2043 nm[J]Opt. Lett., 2018, 43(4):915-918.
MA W W, QIAN X B, WANG J Y, et al.. Highly efficient dual-wavelength mid-infrared CW laser in diode end-pumped Er:SrF2 single crystals[J].Sci. Rep., 2016, 6(1):36635.
MA W W, SU L B, XU X D, et al.. Improved 2.79μm continuous-wave laser performance from a diode-end pumped Er, Pr:CaF2 crystal[J].J. Alloys Compd., 2017, 695:3370-3375.
SERRANO D, KARLSSON J, ZHENG L, et al.. Satellite line mapping in Eu3+-Ce3+ and Pr3+-Ce3+ codoped Y2SiO5[J].J. Lumin., 2016, 170:102-107.
FERRIER A, VELÁZQUEZ M, DOUALAN J L, et al.. Spectroscopic investigation and mid-infrared luminescence properties of the Pr3+-doped low phonon single crystals CsCdBr3, KpB2Cl5 and Tl3PbBr5[J].J. Lumin., 2009, 129(12):1905-1907.
MAJEWSKI M R, JACKSON S D. Highly efficient mid-infrared dysprosium fiber laser[J].Opt. Letters, 2016, 41(10):2173-2176.
JOHNSON L F, GUGGENHEIM H J. Laser emission at 3μ from Dy3+ in BaY2F8[J].Appl. Phys. Lett., 1973, 23(2):96-98.
WOODWARD R I, MAJEWSKI M R, BHARATHAN G, et al.. Watt-level dysprosium fiber laser at 3.15μm with 73% slope efficiency[J].Opt. Lett., 2018, 43(7):1471-1474.
HÖMMERICH U, NYEIN E, FREEMAN J A, et al.. Crystal growth and optical properties of Dy-doped potassium lead bromide(KPb2Br5)[J].J. Cryst. Growth, 2006, 287(2):230-233.
CHEN G Z, YIN J G, ZHANG L H, et al.. Optical properties of Dy3+ ion in PbF2 laser crystal[J].Laser Phys. Lett., 2013, 10(11):115801.
LI S M, ZHANG L H, ZHANG P X, et al.. Spectroscopic characterizations of Dy:LaF3 crystal[J].Infrared Phys. Technol., 2017, 87:65-71.
NOSTRAND M C, PAGE R H, PAYNE S A, et al.. Optical properties of Dy3+-and Nd3+-doped KPb2Cl5[J].J. Opt. Soc. Am. B, 2001, 18(3):264-276.
WANG Y, LI J F, ZHU Z J, et al.. Mid-infrared emission in Dy:YAlO3 crystal[J].Opt. Mater. Express, 2014, 4(6):1104-1111.
HEUER A M, VON BRUNN P, HUBER G, et al.. Dy3+:Lu2O3 as a novel crystalline oxide for mid-infrared laser applications[J].Opt. Mater. Express, 2018, 8(11):3447-3455.
XU X D, HU Z W, LI R J,et al.. Optical spectroscopy of Dy3+-doped CaGdAlO4 single crystal for potential use in solid-state yellow lasers[J].Opt. Mater., 2017, 66:469-473.
FUJIMOTO Y, ISHⅡ O, YAMAZAKI M. Yellow laser oscillation in Dy3+-doped waterproof fluoro-aluminate glass fibre pumped by 398.8 nm GaN laser diodes[J].Electron. Lett., 2010, 46(8):586-587.
WANG Y Q, ZHU Z J, LI J F, et al.. Spectral assessment analysis of Dy3+-doped Ca3La2(BO3)4 crystal:a candidate for solid state yellow lasers[J].Laser Phys., 2014, 24(4):045804-1-5.
HU Z W, XU X D, WANG J, et al.. Fabrication and spectral properties of Dy:Y2O3 transparent ceramics[J].J. Eur. Ceram. Soc., 2018, 38(4):1981-1985.
HUSSAIN S, GIANG T T H, YU J S. UV excitation band induced novel Na3Gd(VO4)2:RE3+(RE3+=Eu3+ or Dy3+ or Sm3+) double vanadate phosphors for solid-state lightning applications[J].J. Alloys Compd., 2018, 739:218-226.
CHEN Y, CHEN G H, LIU X Y, et al.. Tunable luminescence mediated by energy transfer in Tm3+/Dy3+ co-doped phosphate glasses under UV excitation[J].Opt. Mater., 2017, 73:535-540.
HAN L, SONG J, LIU W Z, et al.. Preparation and luminescent properties of Tm3+-Dy3+ co-doped phosphate glass for white light-emitting-diode applications[J].J. Lumin., 2020, 227:117559.
SUN X Y, HAN T T, WU D L, et al.. Investigation on luminescence properties of Dy3+-, Eu3+-doped, and Eu3+/Dy3+-codoped SrGd2O4 phosphors[J].J. Lumin., 2018, 204:89-94.
KUMAR V, PANDEY A, NTWAEABORWA O M, et al.. Structural and luminescence properties of Eu3+/Dy3+ embedded sodium silicate glass for multicolour emission[J].J. Alloys Compd., 2017, 708:922-931.
ZOU Y Z. Growth of high quality large Nd:YAG crystals by Temperature Gradient Technique(TGT)[J].J. Cryst. Growth, 1986, 78(1):31-35.
沈永宏, 闫冬梅, 王琦.多孔体坩埚生长氟化钙晶体[J].光学精密工程, 2007, 15(10):1474-1477.
SHENY H, YAN D M, WANG Q. Calcium fluoride crystal growth with multi-hole-crucible[J].Opt. Precision Eng., 2007, 15(10):1474-1477. (in Chinese)
吕志新, 刘占国, 王立华.用Bridgman-Stockbarger技术多坩埚生长氟化钙晶体的研究[J].光学精密工程, 1990(5):26-32.
LU Z X, LIU Z G, WANG L H. A study of the growth of CaF2 crystal in multi-crucibles by Bridgman-Stockbarger technique[J].Opt. Precision Eng., 1990(5):26-32. (in Chinese)
HU M Y, WANG Y, ZHU Z J, et al.. Investigation of mid-IR luminescence properties in Dy3+/Tm3+-codoped LaF3 single crystals[J].J. Lumin., 2019, 207:226-230.
ZHANG Y, XU J Y, LU B L. Spectroscopic properties of Dy3+:Bi4Si3O12 single crystal[J].J. Alloys Compd., 2014, 582:635-639.
GAO X Q, FANG G Y, WANG Y, et al.. Visible and mid-infrared spectral performances of Dy3+:CaF2 and Dy3+/Y3+:CaF2 crystals[J].J. Alloys Compd., 2021, 856:158083.
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