Long-lasting Phosphorescence in Nb5+ and Sm3+ Codoped YTaO4

Hong-jie WANG; Meng HAN; Chong-yang ZHU; Su ZHANG; Ran PANG; Li-hong JIANG; Cheng-yu LI

doi:10.37188/CJL.20200221

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Long-lasting Phosphorescence in Nb⁵⁺ and Sm³⁺ Codoped YTaO₄

Cover Story | 更新时间：2021-01-12

- Long-lasting Phosphorescence in Nb⁵⁺ and Sm³⁺ Codoped YTaO₄
- Chinese Journal of Luminescence Vol. 42, Issue 1, Pages: 1-9(2021)
- 作者机构：
  
  1.吉林建筑大学材料学院, 吉林长春 130018
  2.中国科学院长春应用化学研究所稀土资源利用国家重点实验室, 吉林长春 130022
- 作者简介：
- 基金信息：
  
  National Key R&D Program of China;Youth Innovation Promotion Association, CAS
- DOI：10.37188/CJL.20200221
  CLC： O482.31;O616;O611.3
- Published：2021-1，
  
  Received：27 July 2020，
  
  Accepted：4 September 2020
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Hong-jie WANG, Meng HAN, Chong-yang ZHU, et al. Long-lasting Phosphorescence in Nb⁵⁺ and Sm³⁺ Codoped YTaO₄. [J]. Chinese Journal of Luminescence 42(1):1-9(2021)
DOI：

Hong-jie WANG, Meng HAN, Chong-yang ZHU, et al. Long-lasting Phosphorescence in Nb⁵⁺ and Sm³⁺ Codoped YTaO₄. [J]. Chinese Journal of Luminescence 42(1):1-9(2021) DOI： 10.37188/CJL.20200221.

摘要

采用高温固相法合成了Nb

、Sm

共掺杂YTaO

长余辉发光材料，通过X射线粉末衍射（XRD）、稳态荧光光谱、漫反射光谱和热释光曲线等多种表征手段研究了材料的结构、荧光和长余辉发光特性。XRD结果表明，共掺杂Nb

和Sm

没有引起YTaO

晶体结构的改变。光谱分析表明，共掺Nb

不仅可大幅提高YTaO

中Sm

的长余辉发光强度，而且可实现长余辉发光颜色的调控。对Sm

和Nb

共掺杂调控长余辉发光特性的机理也进行了分析。

Abstract

The Y

0.98

0.02

TaO

long lasting phosphorescence(LLP) material was synthesized by high temperature solid state reaction

and the co-doping experiment of replacing Ta

with Nb

was also carried out. The results of X-ray powder diffraction spectra shown that the doped ions did not change the crystal structure of YTaO

. Through room temperature steady-state photoluminescence(PL) and long-lasting phosphorescence experiments

it is found that the addition of Nb

can greatly increase the intensity of long-lasting phosphorescence of Sm

in YTaO

and change the emission color of PL and LLP. In this paper

the properties and mechanism of PL and LLP of YTaO

:Sm

are studied

respectively.

关键词

过渡金属复合氧化物长余辉Nb5+Ta5+颜色可调

Keywords

transition metal composite oxidelong-lasting phosphorescenceNb5+Ta5+color tunable

references

BRIXNER L H, CHEN H Y. On the structural and luminescent properties of the M' LnTaO4 rare earth tantalates[J].J. Electrochem. Soc., 1983, 130(12):2435-2443.

WOLTEN G M. The structure of the M'-phase of YTaO4, a third Fergusonite polymorph[J].Acta Crystall., 1968, 24(3):463.

FERGUSON R B. The crystallography of synthetic YTaO4 and fused fergusonite[J].Can. Mineral., 1957, 6(1):72-77.

BLASSE G, BRIL A. Luminescence phenomena in compounds with fergusonite structure[J].J. Lumin., 1970, 3(2):109-131.

LAMMERS M J J, BLASSE G. Energy transfer phenomena in Tb3+-activated gadolinium tantalate(GdTaO4)[J].Mater. Res. Bull., 1984, 19(6):759-768.

BLASSE G, BRIXNER L H. Ultraviolet emission from ABO4-type niobates, tantalates and tungstates[J].Chem. Phys. Lett., 1990, 173(5-6):409-411.

BLASSE G. Vibrational spectra of yttrium niobate and tantalite[J].J. Solid State Chem., 1973, 7(2):169-171.

SCHIPPER W J, HOOGENDORP M F, BLASSE G. The luminescence and X-ray storage properties of Pr3+ and Ce3+ in YNbO4 and M'-YTaO4[J].J. Alloys Compd., 1993, 202(1-2):283-287.

BUTH A H, BLASSE G. Luminescence and energy transfer in yttrium niobate(YNbO4)[J].Phys. Status Solidi A, 1981, 64(2):669-676.

REN Y D, LIU Y H, YANG R. A series of color tunable yellow-orange-red-emitting SrWO4:RE(Sm3+, Eu3+-Sm3+) phosphor for near ultraviolet and blue light-based warm white light emitting diodes[J].Superlattices Microstruct., 2016, 91:138-147.

JU Z H, WEI R P, MA J X, et al.. A novel orange emissive phosphor SrWO4:Sm3+ for white light-emitting diodes[J].J. Alloys Compd., 2010, 507(1):133-136.

YANG L Z, YU X B, YANG S P, et al.. Preparation and luminescence properties of LED conversion novel phosphors SrZnO2:Sm[J].Mater. Lett., 2008, 62(6-7):907-910.

LI X, YANG Z P, GUAN L, et al.. Fabrication and luminescence properties of red emitting phosphor Y2O2S:Sm3+ for white LED by combustion method[J].J. Alloys Compd., 2008, 464(1-2):565-568.

LI Q F, ZHANG S N, LIN W X, et al.. A warm white emission of Bi3+-Eu3+ and Bi3+-Sm3+ codoping Lu2Ge2O7 phosphors by energy transfer of Bi3+-sensitized Eu3+/Sm3+[J].Spectrochim. Acta Part A, Mol. Biomol. Spectrosc., 2019, 228:117755.

ÐAČANIN L R, LUKIĆPETROVIĆ S R, PETROVIĆ D M, et al.. Temperature quenching of luminescence emission in Eu3+-and Sm3+-doped YNbO4 powders[J].J. Lumin., 2014, 151:82-87.

WANG X, LI X P, SHEN R S, et al.. Optical transition and luminescence properties of Sm3+-doped YNbO4 powder phosphors[J].J. Am. Ceram. Soc., 2020, 103(2):1037-1045.

KORZENIOWSKI K, SOBCZYK M. A study of optical properties of Sm3+-doped M'-type structure YTaO4 powders synthesized by the disodium tetraborate flux method[J].J. Alloys Compd., 2018, 753:717-724.

DAANIN FAR L, LUKIĆ-PETROVIĆ S R, DORDEVIĆ V, et al.. Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4[J].Sens. Actuators A-Phys., 2018, 270:89-96.

王洪杰, 朱重阳, 张粟, 等. YXO4(X=Nb, V)的结构与基质发光[J].高等学校化学学报, 2019, 40(12):2448-2455.

WANG H J, ZHU C Y, ZHANG S, et al.. Structure and host luminescence of YXO4(X=Nb, V)[J].Chem. J. Chin. Univ., 2019, 40(12):2448-2455. (in Chinese)

王洪杰, 朱重阳, 张粟. YXO4(X=Ta, Nb)的结构与基质发光[J].吉林建筑大学学报, 2020, 37(1):72-76.

WANG H J, ZHU C Y, ZHANG S. Structure and luminescence properties of YXO4(X=Ta, Nb)[J].J. Jilin Jianzhu Univ., 2020, 37(1):72-76. (in Chinese)

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Related Institution

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Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China

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