Synthesis and Photoelectronic Properties of Novel High-efficiency Bipolar Phosphorescent Host Material

Kai-Peng LIU; Jun SUN; Hong-Ke ZHANG; Mi TIAN; Hai-Xiao HE; Hua-Yuan HU; Dan-Dan YANG; Jian

doi:10.37188/CJL.20200205

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Synthesis and Photoelectronic Properties of Novel High-efficiency Bipolar Phosphorescent Host Material

Synthesis and Properties of Materials | 更新时间：2020-11-10

- Synthesis and Photoelectronic Properties of Novel High-efficiency Bipolar Phosphorescent Host Material
- Chinese Journal of Luminescence Vol. 41, Issue 11, Pages: 1383-1390(2020)
- 作者机构：
  
  西安瑞联新材料股份有限公司, 陕西西安 710077
- 作者简介：
- 基金信息：
  
  National Key R&D Program of China;Key R&D Program of of Shanxi Province
- DOI：10.37188/CJL.20200205
  CLC： O625.6
- Published：2020-11，
  
  Received：14 July 2020，
  
  Accepted：2020-8-21
- 稿件说明：
移动端阅览
KAI-PENG LIU, JUN SUN, HONG-KE ZHANG, et al. Synthesis and Photoelectronic Properties of Novel High-efficiency Bipolar Phosphorescent Host Material. [J]. Chinese journal of luminescence, 2020, 41(11): 1383-1390.
DOI：

KAI-PENG LIU, JUN SUN, HONG-KE ZHANG, et al. Synthesis and Photoelectronic Properties of Novel High-efficiency Bipolar Phosphorescent Host Material. [J]. Chinese journal of luminescence, 2020, 41(11): 1383-1390. DOI： 10.37188/CJL.20200205.

摘要

设计并合成了一种以嘧啶为电子受体、咔唑类衍生物为电子给体的不对称给体-受体-给体（D-A-D）型双极性化合物，即1-（2-（3-（9H-咔唑-9-基）苯基）嘧啶-5-基）-1，3-二氢-3，3-二甲基茚并[2，1-b]咔唑（DMIC-PmPCP），并对其结构进行了核磁表征。化合物DMIC-PmPCP的光电性能测试结果显示其具有较高的三线态能级（2.82 eV）和较平衡的载流子传输性能。以DMIC-PmPCP为主体材料、二（2-甲基-6-苯基吡啶）（2-（[1，1'-联苯]

-3-基）吡啶）合铱（即GD-01）为掺杂材料制作的绿光磷光器件色坐标CIE（0.33，0.62），最大电流效率为70.16 cd·A

-1

。在发光亮度3 000 cd·m

-2

条件下，器件的电流效率为55.08 cd·A

-1

，相比使用常规主体材料1，3-二氢-3，3-二甲基-1-（3-（4，6-二苯基-1，3，5-三嗪-2-基）苯基）茚[2，1-b]咔唑（即DMIC-TRZ）制作的器件，电流效率提高了13.6%。以DMIC-PmPCP为主体材料、Ir（PPy）

为掺杂发光材料的器件也获得了较好的电致发光性能，在3 000 cd·m

-2

条件下电流效率达到52.33 cd·A

-1

。实验结果表明，主体材料具有更好的载流子平衡性对于提高器件性能具有很大帮助。

Abstract

A novel D-A-D bipolar compound with pyrimidine as electron acceptor and carbazole derivative as electron donor

namely 1

3-dihydro-3

3-dimethyl-1-(2-(3-(9-phenyl-9H-carbazol-3-yl)phenyl)pyrimidin-5-yl) indeno[2

1-b]carbazole (DMIC-PmPCP)

was synthesized and characterized by

H NMR. DMIC-PmPCP was used as host material for bis(2-methyl-6-phenylpyridine)(2-([1

1'-biphenyl]-3-yl)pyridine)iridium (GD-01) in fabricating high efficiency phosphorescent organic light emitting diode(OLED). The device gave a green emission with CIE coordinate of (0.33

0.62) and maximum current efficiency of 70.16 cd·A

-1

was obtained. It also exhibits high current efficiency of 55.08 cd·A

-1

at luminance of 3 000 cd·m

-2

which is about 17.4% more than the current efficiency of similar structural OLED with 1

3-dihydro-3

3-di-methyl-1-(3-(4

6-diphenyl-1

5-triazin-2-yl)phenyl) indane[2

1-b]carbazole(DMIC-TRZ) as the host material. DMIC-PmPCP was also used as host material for Tri(2-phenylpyridine)iridium(Ir(PPy)

) in fabricating green PhOLED

the device exhibited high current efficiency of 52.33 cd·A

-1

at luminance of 3 000 cd·m

-2

. The more balanced carrier transport plays a key role for excellent device performance and making DMIC-PmPCP a promising candidate as the host material for green PhOLEDs.

关键词

双极性主体材料绿光有机磷光

Keywords

bipolarhost materialgreen lightorganic phosphorescent

references

[1] GUSTAFSSON G, CAO Y, TREACY G M,et al.. Flexible light-emitting diodes made from soluble conducting polymers[J].Nature, 1992, 357(6378):477-479.

SUN Y R, GIEBINK N C, KANNO H, et al.. Management of singlet and triplet excitons for efficient white organic light-emitting devices[J].Nature, 2006, 440(7086):908-912.

GUO L Y, ZHANG X L, ZHUO M J, et al.. Non-interlayer and color stable WOLEDs with mixed host and incorporating a new orange phosphorescent Iridium complex[J].Org. Electron., 2014, 15(11):2964-2970.

MENG L Q, WANG H, WEI X F, et al.. White organic light emitting diodes based on a yellow thermally activated delayed fluorescent emitter and blue fluorescent emitter[J].RSC Adv., 2015, 5(73):59137-59141.

杨婷婷, 许慧侠, 王华, 等.一种基于咔唑的新型磷光主体材料的合成及光电性能[J].物理化学学报, 2013, 29(6):1351-1356.

YANG T T, XU H X, WANG H, et al.. Synthesis and photoelectric properties of a new phosphorescent host material based on carbazole[J].Acta Phys.-Chim. Sinica, 2013, 29(6):1351-1356. (in Chinese)

SHIH P I, CHIEN C H, CHUANG C Y, et al.. Novel host material for highly efficient blue phosphorescent OLEDs[J].J. Mater. Chem., 2007, 17(17):1692-1698.

孙军, 张玉祥, 赵卫华, 等.基于7-(9H-carbazol-9-yl)-N, N-diphenyl-9, 9'-spirobi[fluoren]-2-amine主体材料的高效红色电致磷光器件[J].发光学报, 2014, 35(3):327-331.

SUN J, ZHANG Y X, ZHAO W H, et al.. Highly efficient red electrophosphorescent devices based on 7-(9H-carbazol-9-yl)-N, N-diphenyl-9, 9'-spirobi[fluoren]-2-amine host material[J].Chin. J. Lumin., 2014, 35(3):327-331. (in Chinese)

孙军, 张玉祥, 梅学义, 等.基于1, 3, 5-tri(9H-carbazol-9-yl)benzene主体材料的高效蓝色电致磷光器件[J].发光学报, 2011, 32(6):581-586.

SUN J, ZHANG Y X, MEI X Y, et al.. Highly efficient blue phosphorescent OLEDs based on 1, 3, 5-tri(9H-carbazol-9-yl) benzene host material[J].Chin. J. Lumin., 2011, 32(6):581-586. (in Chinese)

DUAN Y, MAZZEO M, CHENG G, et al.. High-efficiency red phosphorescent electroluminescence devices based on mixed p/n host matrices[J].Opt. Lett., 2010, 35(19):3174-3176.

VADAGAONKAR K S, YANG C J, ZENG W H, et al.. Triazolopyridine hybrids as bipolar host materials for green phosphorescent organic light-emitting diodes (OLEDs)[J].Dyes Pigm., 2019, 160:301-314.

BAO L Y, ZHU J N, SONG W X, et al.. New carbazole-based bipolar hosts for efficient green phosphorescent organic light-emitting diodes[J].Org. Electron., 2020, 83:105672.

GAO Z J, YE T H, XU J J,et al.. Carbazole/benzimidazole-based bipolar molecules as the hosts for phosphorescent and thermally activated delayed fluorescence emitters for efficient OLEDs[J].ACS Omega, 2020, 5(18):10553-10561.

GONG X, TONG M H, BRUNETTI F G, et al.. Bulk heterojunction solar cells with large open-circuit voltage:electron transfer with small donor-acceptor energy offset[J].Adv. Mater., 2011, 23(20):2272-2277.

SUN Y M, TAKACS C J, COWAN S R, et al.. Efficient, air-stable bulk heterojunction polymer solar cells using MoOx as the anode interfacial layer[J].Adv. Mater., 2011, 23(19):2226-2230.

ZHANG D D, DUAN L, LI C, et al.. High-efficiency fluorescent organic light-emitting devices using sensitizing hosts with a small singlet-triplet exchange energy[J].Adv. Mater., 2014, 26(29):5050-5055.

李红燕, 张玉祥, 张宏科, 等.不同主体材料对红色磷光OLED器件性能的影响[J].发光学报, 2009, 30(5):585-589.

LI H Y, ZHANG Y X, ZHANG H K, et al.. Effect of a series of host material on optoelectronic performance of red phosphorescent OLED[J].Chin. J. Lumin., 2009, 30(5):585-589. (in Chinese)

WU T L, HUANG M J, LIN C C, et al.. Diboron compound-based organic light-emitting diodes with high efficiency and reduced efficiency roll-off[J].Nat. Photonics, 2018, 12(4):235-240.

马治军, 雷霆, 裴坚, 等.蓝色有机电致磷光主体材料[J].化学进展, 2013, 25(6):961-974.

MA Z J, LEI T, PEI J, et al.. Blue host materials for phosphorescent organic light-emitting diodes[J].Prog. Chem., 2013, 25(6):961-974. (in Chinese)

WANG Y M, DUAN K K, LI G X, et al.. Oxadiazole derivatives as bipolar host materials for high-performance blue and green phosphorescent organic light-emitting diodes[J].RSC Adv., 2019, 9(55):32010-32016.

孙冠楠, 许海, 刘晓冬, 等.芴-含氮芳杂环共聚物的载流子注入特性[J].物理化学学报, 2010, 26(9):2529-2534.

SUN G N, XU H, LIU X D, et al.. Carrier injection property of fluorene-aromatic nitrogen heterocycle copolymers[J].Acta Phys.-Chim. Sinica, 2010, 26(9):2529-2534. (in Chinese)

ZHANG D D, ZHAO C G, ZHANG Y G,et al.. Highly efficient full-color thermally activated delayed fluorescent organic light-emitting diodes:extremely low efficiency roll-off utilizing a host with small singlet-triplet splitting[J].ACS Appl. Mater. Interfaces, 2017, 9(5):4769-4777.

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