NaGdF4∶Yb3+/Ho3+/Ce3+共掺杂体系中红光和绿光比率增强设计

张礼刚; 赵谡玲; 徐征; 马丽红; 李晨璞; 薛红丹; 王甫丽; 刘朴

doi:10.3788/fgxb20194007.0829

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NaGdF₄∶Yb³⁺/Ho³⁺/Ce³⁺共掺杂体系中红光和绿光比率增强设计

材料合成及性能 | 更新时间：2020-08-12

- NaGdF₄∶Yb³⁺/Ho³⁺/Ce³⁺共掺杂体系中红光和绿光比率增强设计
- Effective Enhancement of Red to Green Ratio in NaGdF₄: Yb³⁺/Ho³⁺/Ce³⁺ Nanoparticle System
- 发光学报 2019年40卷第7期页码：829-834
- 作者机构：
  
  1. 北京交通大学教育部发光与光信息重点实验室, 北京 100044
  2. 北京交通大学光电子技术研究所, 北京 100044
  3. 河北建筑工程学院理学院, 河北张家口 075000
- 作者简介：
- 基金信息：
  
  国家高技术研究发展计划（863计划）（2013AA032205）();国家重点研发计划（2016YFB0401302）();国家自然科学基金（11474018，6177
- DOI：10.3788/fgxb20194007.0829
  中图分类号： TP394.1;TH691.9
- 纸质出版日期：2019-7-5，
  
  网络出版日期：2018-11-5，
  
  收稿日期：2018-7-17，
  
  修回日期：2018-10-16，
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张礼刚, 赵谡玲, 徐征等. NaGdF4∶Yb3+/Ho3+/Ce3+共掺杂体系中红光和绿光比率增强设计[J]. 发光学报, 2019,40(7): 829-834

ZHANG Li-gang, ZHAO Su-ling, XU Zheng etc. Effective Enhancement of Red to Green Ratio in NaGdF4: Yb3+/Ho3+/Ce3+ Nanoparticle System[J]. Chinese Journal of Luminescence, 2019,40(7): 829-834
张礼刚, 赵谡玲, 徐征等. NaGdF4∶Yb3+/Ho3+/Ce3+共掺杂体系中红光和绿光比率增强设计[J]. 发光学报, 2019,40(7): 829-834 DOI： 10.3788/fgxb20194007.0829.

ZHANG Li-gang, ZHAO Su-ling, XU Zheng etc. Effective Enhancement of Red to Green Ratio in NaGdF4: Yb3+/Ho3+/Ce3+ Nanoparticle System[J]. Chinese Journal of Luminescence, 2019,40(7): 829-834 DOI： 10.3788/fgxb20194007.0829.

摘要

稀土离子掺杂氟化物纳米材料的红色上转换发光在彩色显示、生物成像、医学诊断、防伪标记等领域具有很大的应用潜力，尤其是小粒径的红色上转换纳米晶在医学诊断和生物成像等领域具有重要的应用价值。采用熔剂热方法成功地合成了一系列NaGd

0.78-

:Yb/Ho/Ce

（

=0%，5%，10%，15%，20%，30%）上转换发光纳米晶，利用X射线粉末衍射仪（XRD）、透射电镜（TEM）、扫描电镜（SEM）以及荧光光谱仪等仪器对产物的物相结构、形貌和荧光性质进行了表征与研究，样品形貌均一，分散性好，呈现六角相，粒径大约在15~40 nm，随着Ce

掺杂量的增大，粒径有所增大。在980 nm红外光照射下，随着Ce

掺杂量的增加，Ho

红色光上转换显著增强，绿色光减弱，红色光和绿色光的比率从0.122 4增加到3.219 3，增加了将近26倍，产生了强烈的红色光，实现了绿色到红色的转换。最后，详细讨论了Ho

和Ce

离子之间可能的上转换发光机制。

Abstract

The red upconversion luminescence of lanthanide-doped fluoride nanocrystals has great potential applications in the fields of color display

biological imaging

biomedicine

anti-counterfeiting

especially the small size red upconversion nanocrystals have important application in biomedicine and biological imaging. In this work

a series of NaGd

0.78-

:Yb/Ho/Ce

(

=0%

10%

15%

20%

30%) upconversion fluorescent nanocrystals were successfully synthesized by solvothermal process. The phase structure

morphology and fluorescence properties of the products were characterized and studied by using X ray powder diffractometer(XRD)

transmission electron microscopy(TEM)

scanning electron microscopy(SEM) and fluorescence spectrometer. The product has uniform morphology and good dispersibility

showing hexagonal phase. The particle size is about 15-40 nm. With the increase of Ce

doping

the particle size increases. Under the excitation wavelength of 980 nm

the upconversion of Ho

red light increased significantly

the green light weakened with the increase of concentration of Ce

from 0% to 30%

the ratio of red light and green light increased from 0.122 4 to 3.219 3

increased by nearly 26 times

which realized the conversion of green to red. Finally

the possible upconversion emission mechanism between Ho

and Ce

ions is discussed in detail.

关键词

四氟钆钠上转换发光铈离子

Keywords

NaGdF4upconvensitionCe ions

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