基于带隙可调的MAPbI(3-x)Brx钙钛矿电池

魏清渤; 归阿敏; 高静楠; 周盼; 付峰

doi:10.3788/fgxb20194004.0491

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基于带隙可调的MAPbI_(3-x)Br_x钙钛矿电池

器件制备及器件物理 | 更新时间：2020-08-12

- 基于带隙可调的MAPbI_(3-x)Br_x钙钛矿电池
- MAPbI_(3-x)Br_x Perovskite Solar Cells Based on Adjustable Band Gap
- 发光学报 2019年40卷第4期页码：491-496
- 作者机构：
  
  延安大学化学与化工学院陕西省化学反应工程重点实验室,陕西延安,716000
- 作者简介：
- 基金信息：
  
  国家自然科学基金（21663030，21766039）;陕西省科技统筹创新工程项目（2017TSCL-N-7-3）;陕西省教育厅基金（15JS120）;延安大学博士科研启动基金（YDBK2017-14）;延安大学自然科学基金（YDQ2018-15）资助项目
- DOI：10.3788/fgxb20194004.0491
  中图分类号： O472
- 纸质出版日期：2019-4-5，
  
  网络出版日期：2018-9-21，
  
  收稿日期：2018-6-8，
  
  修回日期：2018-9-13，
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魏清渤, 归阿敏, 高静楠等. 基于带隙可调的MAPbI(3-x)Brx钙钛矿电池[J]. 发光学报, 2019,40(4): 491-496

WEI Qing-bo, GUI A-min, GAO Jing-nan etc. MAPbI(3-x)Brx Perovskite Solar Cells Based on Adjustable Band Gap[J]. Chinese Journal of Luminescence, 2019,40(4): 491-496
魏清渤, 归阿敏, 高静楠等. 基于带隙可调的MAPbI(3-x)Brx钙钛矿电池[J]. 发光学报, 2019,40(4): 491-496 DOI： 10.3788/fgxb20194004.0491.

WEI Qing-bo, GUI A-min, GAO Jing-nan etc. MAPbI(3-x)Brx Perovskite Solar Cells Based on Adjustable Band Gap[J]. Chinese Journal of Luminescence, 2019,40(4): 491-496 DOI： 10.3788/fgxb20194004.0491.

摘要

采用一步溶液法制备了MAPbI

（3-

）

钙钛矿太阳电池，研究了MABr掺杂含量变化对薄膜形貌及光电性能的影响。研究结果表明，在MAPbI

（3-

）

体系中，随着MABr含量的增加，钙钛矿层晶粒尺寸明显增大；紫外-可见吸收光谱和稳态荧光测试表明峰位发生蓝移；构筑的MAPbI

（3-

）

电池器件的开路电压

=1.02 V，光电转换效率 PCE为12.68%。

Abstract

The MAPbI

(3-

)

perovskite solar cell was deposited in one-step solution approach. This study focuses on the influence of MABr on the morphology

optical absorption and photovoltaic performances. The results show that the surface of the deposited CH

PbI

(3-

)

became rougher and the grain sizes larger with the MABr concentration increasing. UV-Vis-NIR spectra and photoluminescence peak of CH

PbI

(3-

)

film blue shifted with increasing of the MABr concentration. The MAPbI

(3-

)

solar cells exhibite open circuit voltage of 1.02 V with power conversion efficiency of 12.68%.

关键词

有机/无机杂化钙钛矿形貌电池

Keywords

organic-inorganic hybridperovskitemorphologysolar cell

references

KOJIMA A,TESHIMA K,SHIRAI Y S,et al.. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J]. J. Am. Chem. Soc., 2009,131(17):6050-6051.

IM J H,LEE C R,LEE J W,et al.. 6.5% efficient perovskite quantum-dot-sensitized solar cell[J]. Nanoscale, 2011, 3(10):4088-4093.

KIM H S,LEE C R,IM J H,et al.. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J]. Sci. Rep., 2012,2:591.

LEE M,TEUSCHER J,MIYASAKA T,et al.. Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J]. Science, 2012,338(6107):643-647.

BURSCHKA J,PELLET N,MOON S J,et al.. Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J]. Nature, 2013,499:316-319.

STRANKS S D,EPERON G E,GRANCINI G,et al.. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J]. Science, 2013,342(6156):341-344.

YANG D,YANG R X,ZHANG J,et al.. High efficiency flexible perovskite solar cells using superior low temperature TiO2[J]. Energy Environ. Sci., 2015,8(11):3208-3214.

YANG Z,CAI B,ZHOU B,et al.. An up-scalable approach to CH3NH3PbI3 compact films for high-performance perovskite solar cells[J]. Nano Energy, 2015,15:670-678.

LIU M Z,JOHNSTON M B,SNAITH H J. Efficient planar heterojunction perovskite solar cells by vapour deposition[J]. Nature, 2013,501(7467):395-398.

GONZALEZ-PEDRO V,JUAREZ-PEREZ E J,ARSYAD W S,et al.. General working principles of CH3NH3PbX3 perovskite solar cells[J]. Nano Lett., 2014,14(2):888-893.

LIU D Y,KELLY T L. Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J]. Nat. Photon., 2014,8(2):133-138.

WOJCIECHOWSKI K,SALIBA M,LEIJTENS T,et al.. Sub-150℃ processed meso-superstructured perovskite solar cells with enhanced efficiency[J]. Energy Environ. Sci., 2014,7(3):1142-1147.

ZHOU H P,CHEN Q,LI G,et al.. Interface engineering of highly efficient perovskite solar cells[J]. Science, 2014,345(6196):542-546.

ZI W,JIN Z,LIU S,et al.. Flexible perovskite solar cells based on green, continuous roll-to-roll printing technology[J]. J. Energy Chem., 2018,27(4):971-989.

LIU Y C,YANG Z,CUI D,et al.. Two-inch-sized perovskite CH3NH3PbX3(X=Cl,Br,I) crystals:growth and characterization[J]. Adv. Mater., 2015,27(25):5176-5183.

WEI Q,YANG Z,YANG D,et al.. The effect of transparent conductive oxide on the performance CH3NH3PbI3 perovskite solar cell without electron/hole selective layers[J]. Sol. Energy, 2016,135:654-661.

GONZALEZ-CARRERO S,GALIAN R E,PREZ-PRIETO J. Maximizing the emissive properties of CH3NH3PbBr3 perovskite nanoparticles[J]. J. Mater. Chem. A, 2015,3(17):9187-9193.

KIM H B,IM I,YOON Y,et al.. Enhancement of photovoltaic properties of CH3NH3PbBr3 heterojunction solar cells by modifying mesoporous TiO2 surfaces with carboxyl groups[J]. J. Mater. Chem. A, 2015,3(17):9264-9270.

KIM Y H,CHO H,HEO J H,et al.. Multicolored organic/inorganic hybrid perovskite light-emitting diodes[J]. Adv. Mater., 2015,27(7):1248-1254.

LEWIS D J,O'BRIEN P. Ambient pressure aerosol-assisted chemical vapour deposition of (CH3NH3)PbBr3,an inorganic-organic perovskite important in photovoltaics[J]. Chem. Commun., 2014,50(48):6319-6321.

RYU S,NOH J H,JEON N J,et al.. Voltage output of efficient perovskite solar cells with high open-circuit voltage and fill factor[J]. Energy Environ. Sci., 2014,7(8):2614-2618.

CHEN Q,ZHOU H P,FANG Y H,et al.. The optoelectronic role of chlorine in CH3NH3PbI3(Cl)-based perovskite solar cells[J]. Nat. Commun., 2015,6:7269.

XIE Y,SHAO F,WANG Y M,et al.. Enhanced performance of perovskite CH3NH3PbI3 solar cell by using CH3NH3I as additive in sequential deposition[J]. ACS Appl. Mater. Interfaces, 2015,7(23):12937-12942.

SHI J J,LUO Y H,WEI H Y,et al.. Modified two-step deposition method for high-efficiency TiO2/CH3NH3PbI3 heterojunction solar cells[J]. ACS Appl. Mater. Interfaces, 2014,6(12):9711-9718.

LIU D Y,YANG J L,KELLY T L. Compact layer free perovskite solar cells with 13.5% efficiency[J]. J. Am. Chem. Soc., 2014,136:17116-17122.

SUN S Y,SALIM T,MATHEWS N,et al.. The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells[J]. Energy Environ. Sci., 2014,7(1):399-407.

REN X,YANG D,YANG Z,et al.. Solution-processed Nb:SnO2 electron transport layer for efficient planar perovskite solar cells[J]. ACS Appl. Mater. Interfaces, 2017,9(3):2421-2429.

YANG D,YANG R X,WANG K,et al.. High efficiency planar-type perovskite solar cells with negligible hysteresis using EDTA-complexed SnO2[J]. Nat. Commun., 2018,9(1):3239.

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