Fe3O4纳米粒子对P3HT:PCBM电池的影响

王丽娟; 范思大; 张梁; 张沛沛; 李占国; 孙丽晶

doi:10.3788/fgxb20183910.1410

您当前的位置：

首页 >

文章列表页 >

Fe₃O₄纳米粒子对P3HT:PCBM电池的影响

器件制备及器件物理 | 更新时间：2020-08-12

- Fe₃O₄纳米粒子对P3HT:PCBM电池的影响
- Effect of Fe₃O₄ Nanoparticles on P3HT: PCBM Solar Cells
- 发光学报 2018年39卷第10期页码：1410-1416
- 作者机构：
  
  1. 长春工业大学化学工程学院,吉林长春,130012
  2. 长春理工大学高功率半导体激光国家重点实验室,吉林长春,130022
- 作者简介：
- 基金信息：
  
  国家自然科学基金（21403016）();吉林省教育厅项目（JJKH20170556KJ）();吉林省科技厅重点攻关项目（20170204014SF）资助()
- DOI：10.3788/fgxb20183910.1410
  中图分类号： O649
- 纸质出版日期：2018-10-5，
  
  网络出版日期：2018-2-9，
  
  收稿日期：2018-1-26，
  
  修回日期：2018-3-12，
扫描看全文
王丽娟, 范思大, 张梁等. Fe3O4纳米粒子对P3HT:PCBM电池的影响[J]. 发光学报, 2018,39(10): 1410-1416

WANG Li-juan, FAN Si-da, ZHANG Liang etc. Effect of Fe3O4 Nanoparticles on P3HT: PCBM Solar Cells[J]. Chinese Journal of Luminescence, 2018,39(10): 1410-1416
王丽娟, 范思大, 张梁等. Fe3O4纳米粒子对P3HT:PCBM电池的影响[J]. 发光学报, 2018,39(10): 1410-1416 DOI： 10.3788/fgxb20183910.1410.

WANG Li-juan, FAN Si-da, ZHANG Liang etc. Effect of Fe3O4 Nanoparticles on P3HT: PCBM Solar Cells[J]. Chinese Journal of Luminescence, 2018,39(10): 1410-1416 DOI： 10.3788/fgxb20183910.1410.

摘要

为了提高太阳能电池的性能，研究磁性纳米粒子在外加磁场的作用下对聚合物太阳能电池有源层P3HT:PCBM成膜及太阳能电池性能的影响。本文采用热分解法制备了磁性Fe

纳米粒子，将不同质量分数的Fe

纳米粒子掺入到P3HT:PCBM溶液中，旋涂后在外加磁场的作用下自组成膜。通过TEM、XRD对制备的Fe

纳米粒子进行表征，并利用偏光显微镜、原子力显微镜对成膜质量进行探究。结果表明，采用热分解法制备的Fe

纳米粒子直径在10 nm左右，在外加磁场作用下，Fe

纳米粒子对成膜有一定的调控作用。当Fe

纳米粒子掺杂质量分数为1%时，太阳能电池器件的开路电压增加3.77%，短路电流增加24.93%，光电转换效率提高7.82%。

Abstract

To improve the properties of polymer solar cells

the effect of magnetic nanoparticles on the P3HT:PCBM films as the active layer and the properties of polymer solar cells under the external magnetic field were investigated. The Fe

magnetic nanoparticles were prepared by thermal decomposition. The Fe

nanoparticles of different mass fraction were added to P3HT:PCBM solution.The as-casting films by spin coating method were put into the external magnetic field and the self-assembled Fe

+P3HT:PCBM films were formed. Fe

nanoparticles were characterized by TEM and XRD

and the surface morphology of films was investigated by polarizing microscope(POM) and atomic force microscope(AFM). The results show that Fe

nanoparticles are about 10 nm in diameter

and have a certain regulating effect on building film of P3HT:PCBM. When Fe

nanoparticles are added with a mass fraction 1%

the open circuit voltage(

) of the solar cells increases by 3.77%

the short-circuit current(

) increases by 24.93%

and the photoelectric conversion efficiency(PCE) increases by 7.82%.

关键词

Fe3O4纳米粒子聚合物太阳能电池表面形貌P3HT:PCBM

Keywords

Fe3O4 nanoparticlespolymer solar cellssurface morphologyP3HT:PCBM

references

GUNES S, NEUGEBAUER H, SARICIFTCI N S. Conjugated polymer-based organic solar cells[J]. Chem. Rev., 2007, 107(4):1324-1338.

THOMPSON B C, FRECHET J M. Polymer-fullerene composite solar cells[J]. Angew. Chem. Int. Ed., 2008, 47:58-77.

TANG C W. Two-layer organic photovoltaic cell[J]. Appl. Phys. Lett., 1986, 48(2):183-185.

MA W L, YANG C Y, GONG X, et al.. Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology[J]. Adv. Funct. Mater., 2005, 15:1617-1622.

LI G, SHROTRIYA V, HUANG J, et al.. High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends[J]. Nat. Mater., 2005, 4(11):864-868.

KIM Y, COOK S, TULADHAR S M, et al.. A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells[J]. Nat. Mater., 2006, 5(3):197-203.

ZHAO Y, XIE Z, QU Y, et al.. Solvent-vapor treatment induced performance enhancement of poly(3-hexylthiophene):methanofullerene bulk-heterojunction photovoltaic cells[J]. Appl. Phys. Lett., 2007, 90(4):043504-3.

LIU D, YANG B, JANG B, et al.. Molecular design of a wide-band-gap conjugated polymer for efficient fullerene-free polymer solar cells[J]. Energy Environment. Sci., 2013, 6(1):1-3.

LI S, YE L, ZHAO W, et al.. Energy-level modulation of small-molecule electron acceptors to achieve over 12% efficiency in polymer solar cells[J]. Adv. Mater., 2016, 28(42):9423-9429.

SARICIFTCI N S, SMILOWITZ L, HEEGER A J, et al.. Photoinduced electron transfer from a conducting polymer to buckminsterfullerene[J]. Science, 1992, 258(27):1474-1476.

PO R, CARBONERA C, BERNARDI A, et al.. The role of buffer layers in polymer solar cells[J]. Energy Environment. Sci., 2011, 4(2):285-310.

NOZIK A J. Quantum dot solar cells[J]. Physica E, 2002, 14(1):115-120.

JELTSCH KF, SCHADEL M, BONEKAMP J B, et al.. Efficiency enhanced hybrid solar cells using a blend of quantum dots and nanorods[J]. Adv. Funct. Mater., 2012, 22(2):397-404.

LI M, NI W, KAN B, et al.. Graphene quantum dots as the hole transport layer material for high-performance organic solar cells[J]. Phys. Chem. Chem. Phys., 2013, 15(43):18973-18978.

ESKANDARI M, AHMADI V, YOUSEFI RAD M, et al.. Plasmon enhanced CdS-quantum dot sensitized solar cell using ZnO nanorods array deposited with Ag nanoparticles as photoanode[J]. Physica E:Low-dimens. Syst. Nanostruct., 2015,68:202-209.

WANG D H, KIM D Y, CHOI K W, et al.. Enhancement of donor-acceptor polymer bulk heterojunction solar cell power conversion efficiencies by addition of Au nanoparticles[J]. Angew. Chem. Int. Ed., 2011, 50(24):5519-5523.

LI Y, HU Y, ZHAO Y, et al.. An electrochemical avenue to green-luminescent graphene quantum dots as potential electron-acceptors for photovoltaics[J]. Adv. Mater., 2011, 23(6):776-780.

邹凤君, 范思大, 谢强, 等. 掺杂石墨烯量子点对P3HT:PCBM太阳能电池的影响[J]. 发光学报, 2016, 37(9):1082-1089. ZOU F J, FAN S D, XIE Q, et al.. Effect of doping graphene quantum dots on the performance of P3HT:PCBM solar cells[J]. Chin. J. Lumin., 2016, 37(9):1082-1089. (in Chinese)

ZHANG D H, LI G D, LI J X, et al.. One-pot synthesis of Ag-Fe3O4 nanocomposite:a magnetically recyclable and efficient catalyst for epoxidation of styrene[J]. Chem. Commun., 2008, 29(29):3414-3416.

AO Y, XU J, SHEN X, et al.. Magnetically separable composite photocatalyst with enhanced photocatalytic activity[J]. J. Hazard. Mater., 2008, 160(2-3):295-300.

WU Z S, YANG S, SUN Y, et al.. 3D nitrogen-doped graphene aerogel-supported Fe3O4 nanoparticles as efficient electrocatalysts for the oxygen reduction reaction[J]. J. Am. Chem. Soc., 2012, 134(22):9082-9085.

SHI D, CHO H S, HUTH C, et al.. Conjugation of quantum dots and Fe3O4 on carbon nanotubes for medical diagnosis and treatment[J]. Appl. Phys. Lett., 2009, 95(22):223702-1-3.

JORDAN A, SCHOLZ R, MAIER-HAU K, et al.. Presentation of a new magnetic feld therapy system for the treatment of human solid tumors with magnetic fluid hyperthermia[J]. J. Magnet. Magnetic Mater., 2001, 225:118-126.

LU C W, HUNG Y, HSIAO J K, et al.. Bifunctional magnetic silica nanoparticles for highly efficient human stem cell labeling[J]. Nano Lett., 2007, 7(1):149-154.

CHANG C F, LIN P H, HOLL W. Aluminum-type superparamagnetic adsorbents:synthesis and application on fluoride removal[J]. Colloids Surf. A:Physicochem. Eng. Aspects, 2006, 280(1-3):194-202.

TSENG J Y, CHANG C Y, CHEN Y H, et al.. Synthesis of micro-size magnetic polymer adsorbent and its application for the removal of Cu(Ⅱ) ion[J]. Colloids Surf. A:Physicochem. Eng. Aspects, 2007, 295(1-3):209-216.

YANG S, CAO C, LI G, et al.. Improving the electrochemical performance of Fe3O4 nanoparticles via a double protection strategy through carbon nanotube decoration and graphene networks[J]. Nano Res., 2014, 8(4):1339-1347.

GUO X Y, YI P F, WANG W J, et al.. Effects of polyethylene glycol on agarose-based magnetic polymer electrolyte for dye-sensitized solar cell[J]. Adv. Mater. Res., 2013, 652-654:860-864.

HAN F, MA L, SUN Q, et al.. Rationally designed carbon-coated Fe3O4 coaxial nanotubes with hierarchical porosity as high-rate anodes for lithium ion batteries[J]. Nano Res., 2014, 7(11):1706-1717.

LI H, LI Y, ZHANG Y, et al.. Facile synthesis of carbon-coated Fe3O4 core-shell nanoparticles as anode materials for lithium-ion batteries[J]. J. Nanopart. Res., 2015, 17(9):1-9.

JIAO J, QIU W, TANG J, et al.. Synthesis of well-defined Fe3O4 nanorods/N-doped graphene for lithium-ion batteries[J]. Nano Res., 2016, 9(5):1256-1266.

YAVUZ C T, MAYO J T, YU W W, et al.. Low-field magnetic separation of monodisperse Fe3O4 nanocrystals[J]. Science, 2006, 314(5801):964-967.

PARK J, AN K, HWANG Y, et al.. Ultra-large-scale syntheses of monodisperse nanocrystals[J]. Nat. Mater., 2004, 3(12):891-895.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

聚合物太阳能电池中石墨烯量子点掺杂材料的优化

PbSe量子点调控的聚合物太阳能电池性能

旋涂法制备WO₃薄膜电致变色性能

氯化铯甲醇溶液对有机聚合物太阳能电池的影响

掺杂石墨烯量子点对P3HT:PCBM太阳能电池性能的影响