新型蓝紫光荧光分子N2-烷基-1,2,3-三氮唑的光谱性质

石晓濛; 吕雯雯; 敖慧龙; 贺信淳; 胡庆霞; 王飞军; 赵敏

doi:10.3788/fgxb20183910.1378

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新型蓝紫光荧光分子N²-烷基-1,2,3-三氮唑的光谱性质

材料合成及性能 | 更新时间：2020-08-12

- 新型蓝紫光荧光分子N²-烷基-1,2,3-三氮唑的光谱性质
- Photophysical Properties of A New UV/Blue-light-emitting Fluorescence Molecule N²-Alkyl-1, 2, 3-triazole
- 发光学报 2018年39卷第10期页码：1378-1384
- 作者机构：
  
  华东理工大学化学与分子工程学院上海,200237
- 作者简介：
- 基金信息：
  
  国家自然科学基金面上项目（21372075）();浦江人才计划（16PJD017）资助项目()
- DOI：10.3788/fgxb20183910.1378
  中图分类号： O482.31;O626.26
- 纸质出版日期：2018-10-5，
  
  网络出版日期：2018-4-16，
  
  收稿日期：2017-12-26，
  
  修回日期：2018-3-3，
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石晓濛, 吕雯雯, 敖慧龙等. 新型蓝紫光荧光分子N2-烷基-1,2,3-三氮唑的光谱性质[J]. 发光学报, 2018,39(10): 1378-1384

SHI Xiao-meng, LYU Wen-wen, AO Hui-long etc. Photophysical Properties of A New UV/Blue-light-emitting Fluorescence Molecule N2-Alkyl-1, 2, 3-triazole[J]. Chinese Journal of Luminescence, 2018,39(10): 1378-1384
石晓濛, 吕雯雯, 敖慧龙等. 新型蓝紫光荧光分子N2-烷基-1,2,3-三氮唑的光谱性质[J]. 发光学报, 2018,39(10): 1378-1384 DOI： 10.3788/fgxb20183910.1378.

SHI Xiao-meng, LYU Wen-wen, AO Hui-long etc. Photophysical Properties of A New UV/Blue-light-emitting Fluorescence Molecule N2-Alkyl-1, 2, 3-triazole[J]. Chinese Journal of Luminescence, 2018,39(10): 1378-1384 DOI： 10.3788/fgxb20183910.1378.

摘要

采用对甲苯磺酸催化合成

-烷基-1，2，3-三氮唑和

-烷基-1，2，3-三氮唑。两种产物均有紫外吸收，但只有

-烷基-1，2，3-三氮唑有荧光。研究了在

位和

位引入不同取代基后化合物的紫外可见吸收光谱和荧光激发发射光谱。结果表明，

位是甲苯基或

位是吸电子取代基的荧光强度最高，荧光量子产率高达79%，调节

位取代基可以更好地提升荧光性能（荧光发射波长300~440 nm，Stokes位移49~70 nm）。

-烷基-1，2，3-三氮唑良好的蓝紫光荧光性能使其具有潜在应用价值。

Abstract

-alkyl-1

3-triazoles and

-alkyl-1

3-triazoles were prepared

and their photophysical properties were investigated. Both type of 1

3-triazoles have strong photo absorptions at near 250 nm

however only

-alkyl-1

3-triazoles give fluorescence emissions. From the screen of the photophysical properties of different substituted

-alkyl-1

3-triazoles at

-or

-sites

it is found that

-alkyl-1

3-triazoles bearing rich electron benzyl group at

-site or poor electron phenyl group in

-site have the strong fluorescent intensity

and the quantum yields are up to 79% with 300-440 nm of fluorescent emissions and 49-70 nm of Stokes shifts. The photophysical properties of

-alkyl-1

3-triazoles show their potent application in the development of fluorescent materieals.

关键词

N2-烷基-123-三氮唑荧光强度量子产率

Keywords

N2-alkyl-123-triazolefluorescent intensityquantum yield

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