采用MoO3阳极缓冲层的钙钛矿太阳能电池研究

王俊; 禹豪; 张继华; 张小文; 王红航; 易子川; 刘黎明

doi:10.3788/fgxb20183903.0322

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采用MoO₃阳极缓冲层的钙钛矿太阳能电池研究

器件制备及器件物理 | 更新时间：2020-08-12

- 采用MoO₃阳极缓冲层的钙钛矿太阳能电池研究
- Study on Perovskite Solar Cells with MoO₃ Anode Buffer Layer
- 发光学报 2018年39卷第3期页码：322-328
- 作者机构：
  
  1. 电子科技大学电子薄膜与集成器件国家重点实验室,四川成都,610054
  2. 桂林电子科技大学广西信息材料重点实验室,广西桂林,541004
  3. 电子科技大学中山学院电子薄膜与集成器件国家重点实验室中山分室,广东中山,528402
- 作者简介：
- 基金信息：
  
  国家自然科学基金（61565003，51362031）();广西信息材料重点实验室开放课题（151003-K）();广东省引进创新创业团队项目（2013C102）();
- DOI：10.3788/fgxb20183903.0322
  中图分类号： O484.3
- 纸质出版日期：2018-3-5，
  
  网络出版日期：2017-10-25，
  
  收稿日期：2017-7-24，
  
  修回日期：2017-10-7，
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王俊, 禹豪, 张继华等. 采用MoO3阳极缓冲层的钙钛矿太阳能电池研究[J]. 发光学报, 2018,39(3): 322-328

WANG Jun, YU Hao, ZHANG JI-hua etc. Study on Perovskite Solar Cells with MoO3 Anode Buffer Layer[J]. Chinese Journal of Luminescence, 2018,39(3): 322-328
王俊, 禹豪, 张继华等. 采用MoO3阳极缓冲层的钙钛矿太阳能电池研究[J]. 发光学报, 2018,39(3): 322-328 DOI： 10.3788/fgxb20183903.0322.

WANG Jun, YU Hao, ZHANG JI-hua etc. Study on Perovskite Solar Cells with MoO3 Anode Buffer Layer[J]. Chinese Journal of Luminescence, 2018,39(3): 322-328 DOI： 10.3788/fgxb20183903.0322.

摘要

采用热蒸发法沉积无毒、稳定、价廉的无机氧化物MoO

，将其作为钙钛矿电池的阳极缓冲层。结果表明，MoO

阳极缓冲层的引入有利于增强光吸收层到阳极的空穴提取效率，使电池的短路电流密度（

）和填充因子（FF）均有较大幅度提高，取得了9.96%的平均光电转换效率（PCE）。此外，实验发现，MoO

阳极缓冲层可以阻挡酸性的PEDOT∶PSS对ITO的腐蚀，有利于增强电池的稳定性。

Abstract

The inorganic oxide MoO

thin films were prepared by thermal evaporation deposition method

and used as an anode buffer layer for PHJ perovskite solar cells. The results show that the MoO

anode buffer layer can enhance the hole extraction efficiency from the light absorption layer to the anode

and benefit the improvement of the short-circuit current (

) density and the fill factor (FF) of the solar cells. An average power conversion efficiency (PCE) of 9.96% is achieved finally for the solar cells with a MoO

anode buffer layer. In addition

the results also show that the MoO

anode buffer layer can hinder the corrosion of ITO by acidic PEDOT:PSS and improve the stability of the solar cells.

关键词

钙钛矿太阳能电池阳极缓冲层MoO3无机氧化物

Keywords

perovskite solar cellsanode interface modificationMoO3inorganic oxide

references

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