YANG Zhi-ping, FANG Heng-jiu, LI Xuan-xuan etc. Syntheis and Luminescence Properties of SrLiAl<sub>3</sub>N<sub>4</sub>:Eu<sup>2+</sup> Red Phosphor[J]. Chinese Journal of Luminescence, 2016,37(1): 1-6
YANG Zhi-ping, FANG Heng-jiu, LI Xuan-xuan etc. Syntheis and Luminescence Properties of SrLiAl<sub>3</sub>N<sub>4</sub>:Eu<sup>2+</sup> Red Phosphor[J]. Chinese Journal of Luminescence, 2016,37(1): 1-6 DOI: 10.3788/fgxb20163701.0001.
red-emitting phosphors were prepared in reducing atmosphere by high temperature solid-state reaction which could be effectively excited by ultraviolet and blue light. Luminescence properties and crystal structure of the phosphors were investigated. X-ray diffraction patterns and scanning electron microscopy image show that the sample is a pure phase of SrLiAl
3
N
4
.
In the excitation spectrum (from 200 to 600 nm)
there are two wide bands and peaks at 267 nm and 474 nm. The emission spectrum shows a wide band with a peak at 654 nm corresponding to the 5d4f transition of Eu
2+
. The effect of the doping concentration of Eu
2+
was investigated. The result shows that the luminescent intensity firstly increases and then decreases with the increasing of Eu
2+
mole fraction
and the best doping mole fraction of Eu
2+
is 0.4%. The concentration quenching will occur if Eu
2+
continue to be doped. The phosphors have good thermal quenching properties and quantum efficiency.
关键词
高温固相法荧光粉红光Eu2+
Keywords
high temperature solid-state reactionphosphorredEu2+
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