Mn掺杂Zn-In-S量子点的制备及发光性质研究

陈肖慧; 刘洋; 华杰; 袁曦; 赵家龙; 李海波

doi:10.3788/fgxb20153610.1113

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Mn掺杂Zn-In-S量子点的制备及发光性质研究

材料合成及性能 | 更新时间：2020-08-12

- Mn掺杂Zn-In-S量子点的制备及发光性质研究
- Preparation and Photoluminescence Properties of Mn Doped Zn-In-S Quantum Dots
- 发光学报 2015年36卷第10期页码：1113-1117
- 作者机构：
  
  1. 东北大学理学院,辽宁沈阳,110819
  2. 吉林师范大学功能材料物理与化学教育部重点实验室,吉林四平,136000
- 作者简介：
- 基金信息：
  
  国家自然科学基金(21371071)();吉林省科技发展计划重点科技攻关项目(20150204067GX)资助()
- DOI：10.3788/fgxb20153610.1113
  中图分类号： O482.31
- 纸质出版日期：2015-10-10，
  
  收稿日期：2015-7-17，
  
  修回日期：2015-8-12，
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陈肖慧, 刘洋, 华杰等. Mn掺杂Zn-In-S量子点的制备及发光性质研究[J]. 发光学报, 2015,36(10): 1113-1117

CHEN Xiao-hui, LIU Yang, HUA Jie etc. Preparation and Photoluminescence Properties of Mn Doped Zn-In-S Quantum Dots[J]. Chinese Journal of Luminescence, 2015,36(10): 1113-1117
陈肖慧, 刘洋, 华杰等. Mn掺杂Zn-In-S量子点的制备及发光性质研究[J]. 发光学报, 2015,36(10): 1113-1117 DOI： 10.3788/fgxb20153610.1113.

CHEN Xiao-hui, LIU Yang, HUA Jie etc. Preparation and Photoluminescence Properties of Mn Doped Zn-In-S Quantum Dots[J]. Chinese Journal of Luminescence, 2015,36(10): 1113-1117 DOI： 10.3788/fgxb20153610.1113.

摘要

制备了Mn掺杂Zn-In-S量子点并研究了Zn/In的量比和反应温度对其发光性质的影响。在Mn掺杂的Zn-In-S量子点的发光谱中观测到一个600 nm发光带。通过改变Zn/In的量比

掺杂量子点的吸收带隙可从3.76 eV(330 nm)调谐到2.82 eV(440 nm)

但600 nm发光峰的波长只有略微移动。这些掺杂量子点的最长荧光寿命为2.14 ms。当反应温度从200 ℃增加到230 ℃时

掺杂量子点的发光强度增加并达到最大值;而继续升高温度至260 ℃时

发光强度迅速减弱。此外

测量了Mn掺杂Zn-In-S量子点的变温发光光谱。发现随着温度的升高

发光峰位发生蓝移

发光强度明显下降。分析认为

Mn掺杂Zn-In-S量子点的600 nm发光来自于Mn

离子的

和

之间的辐射复合。

Abstract

Mn doped Zn-In-S quantum dots (QDs) were prepared and the effect of Zn/In molar ratio and reaction temperature on their photoluminescence properties were studied. A 600 nm photoluminescence band was observed in the doped QDs. The absorption band of the doped QDs could be tuned from 3.76 eV (330 nm) to 2.82 eV (440 nm) by changing the Zn/In ratio while the photoluminescence band around 600 nm only slightly shifted. The longest photoluminescence lifetime in the doped QDs reached up to 2.14 ms. When the reaction temperature increased to 230 ℃ from 200 ℃

the photoluminescence intensity of doped QDs increased and reached the maximum. When the temperature increased to 260 ℃

the photoluminescence intensity rapidly deceased. Further the temperature-dependent photoluminescence spectra of Mn doped Zn-In-S QDs were measured. It was found that the photoluminescence intensity significantly decreased

the photoluminescence peak slightly shifted to higher energy

and the linewidth of the photoluminescence increased with the increasing of temperature. It can be concluded that the emission in Mn doped Zn-In-S QDs originates from the radiative recombination of Mn

ions between

and

energy states.

关键词

掺杂量子点纳米晶Mn:Zn-In-S荧光寿命变温光致发光

Keywords

doped quantum dotsnanocrystalsMn:Zn-In-Sphotoluminescence lifetimetemperature-dependent photoluminescence

references

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Yuan X, Zheng J J, Zen R S, et al. Thermal stability of Mn2+ ion luminescence in Mn-doped core-shell quantum dots [J]. Nanoscale, 2014, 6(1):300-307.

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Zhang W J, Lou Q, Ji W Y, et al. Color-tunable highly bright photoluminescence of cadmium-free Cu-doped Zn-In-S nanocrystals and electroluminescence [J]. Chem. Mater., 2014, 26(2):1204-1212.

Yuan X, Hua J, Zen R, et al. Efficient white light emitting diodes based on Cu-doped Zn-In-S/ZnS core/shell quantum dots [J]. Nanotechnology, 2014, 25(43):435202-1-6.

Zheng J J, Yuan X, Ikezawa M, et al. Efficient photoluminescence of Mn2+ ions in MnS/ZnS core/shell quantum dots [J]. J. Phys. Chem. C, 2009, 113(39):16969-16974.

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Chen X H, Yuan X, Hua J, et al. Shell-dependent thermal stability of CdSe core/shell quantum dot photoluminescence [J]. Chin.J. Lumin.(发光学报), 2014, 35(9):1051-1057 (in Chinese).

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