高Tb3+离子含量磁光玻璃的Faraday效应及发光性能

刘盼; 殷海荣; 张红林; 郭宏伟

doi:10.3788/fgxb20153603.0293

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高Tb³⁺离子含量磁光玻璃的Faraday效应及发光性能

材料合成及性能 | 更新时间：2020-08-12

- 高Tb³⁺离子含量磁光玻璃的Faraday效应及发光性能
- Faraday Effect and Luminescence Properties of Magneto-optical Glasses With High Tb³⁺ Content
- 发光学报 2015年36卷第3期页码：293-298
- 作者机构：
  
  1. 陕西科技大学材料科学与工程学院,陕西西安,710021
  2. 咸阳非金属矿研究设计院有限公司研发设计中心,陕西咸阳,712021
- 作者简介：
- 基金信息：
  
  国际科技合作计划(2009DFR50520)();国家自然科学基金(51472151)();陕西省教育厅产业化项目(2013JC-22)资助()
- DOI：10.3788/fgxb20153603.0293
  中图分类号： O482.31
- 纸质出版日期：2015-3-3，
  
  收稿日期：2014-11-27，
  
  修回日期：2015-1-11，
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刘盼, 殷海荣, 张红林等. 高Tb3+离子含量磁光玻璃的Faraday效应及发光性能[J]. 发光学报, 2015,36(3): 293-298

LIU Pan, YIN Hai-rong, ZHANG Hong-lin etc. Faraday Effect and Luminescence Properties of Magneto-optical Glasses With High Tb3+ Content[J]. Chinese Journal of Luminescence, 2015,36(3): 293-298
刘盼, 殷海荣, 张红林等. 高Tb3+离子含量磁光玻璃的Faraday效应及发光性能[J]. 发光学报, 2015,36(3): 293-298 DOI： 10.3788/fgxb20153603.0293.

LIU Pan, YIN Hai-rong, ZHANG Hong-lin etc. Faraday Effect and Luminescence Properties of Magneto-optical Glasses With High Tb3+ Content[J]. Chinese Journal of Luminescence, 2015,36(3): 293-298 DOI： 10.3788/fgxb20153603.0293.

摘要

采用高温熔融法制备了高Tb

离子含量的GeO

-B

-SiO

系统磁光玻璃

测试了其Verdet常数和发光性能

探究了玻璃的Faraday效应、发光性能及光学碱度。研究结果表明:Verdet常数和光学碱度均随着Tb

含量的增加而线性增大

当Tb

摩尔分数为70%时

Verdet常数达到-5 000 minT

-1

(632.8 nm)

所有磁光玻璃样品随Tb

含量变化均发出明亮的黄绿光。由于浓度猝灭效应

高Tb

含量缩短了Tb

离子间距

增强了交叉弛豫效应

降低了发光强度和荧光寿命。

Abstract

GeO

-B

-SiO

magneto-optical glasses with high Tb

content were prepared by high temperature melting technique. The effect of Tb

content on the Faraday effect

luminescent properties and optical basicity was studied. The results show that Verdet constant and optical basicity increase with the increasing of Tb

content. All samples emit bright greenish-yellow luminescence

and the glass has a higher Verdet constant of -5 000 minT

-1

at 632.8 nm when the mole fraction of Tb

is 70%. The distances among Tb

ions become shorter with the increasing of Tb

content due to the concentration quenching effect

therefore

the cross-relaxation effect is enhanced

and the effective luminous intensity and lifetime decrease.

关键词

磁光玻璃光学碱度Tb3+光致发光

Keywords

magneto-optical glassoptical basicityTb3+photoluminescence

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