不对称卟啉共价固载于硅基介孔薄膜材料模拟RS触发器的研究

李鹏; 范镝; 高颉; 李斌; 韩光喜

doi:10.3788/fgxb20143512.1480

您当前的位置：

首页 >

文章列表页 >

不对称卟啉共价固载于硅基介孔薄膜材料模拟RS触发器的研究

器件制备及器件物理 | 更新时间：2020-08-12

- 不对称卟啉共价固载于硅基介孔薄膜材料模拟RS触发器的研究
- RS Latch Realization by Using Asymmetric Porphyrin Covalently Connecting to Mesoporous Silica Films
- 发光学报 2014年35卷第12期页码：1480-1486
- 作者机构：
  
  1. 发光学及应用国家重点实验室中国科学院长春光学精密机械与物理研究所,吉林长春,130033
  2. 长春市中科软件有限公司,吉林长春,130012
- 作者简介：
- 基金信息：
  
  国家自然科学基金(51172224,51103145,51372240)();吉林省科技发展计划(20100533,201201009)资助项目()
- DOI：10.3788/fgxb20143512.1480
  中图分类号： O625.8
- 纸质出版日期：2014-12-3，
  
  网络出版日期：2014-7-18，
  
  收稿日期：2014-5-26，
  
  修回日期：2014-6-16，
扫描看全文
李鹏, 范镝, 高颉等. 不对称卟啉共价固载于硅基介孔薄膜材料模拟RS触发器的研究[J]. 发光学报, 2014,35(12): 1480-1486

LI Peng, FAN Di, Gao Jie etc. RS Latch Realization by Using Asymmetric Porphyrin Covalently Connecting to Mesoporous Silica Films[J]. Chinese Journal of Luminescence, 2014,35(12): 1480-1486
李鹏, 范镝, 高颉等. 不对称卟啉共价固载于硅基介孔薄膜材料模拟RS触发器的研究[J]. 发光学报, 2014,35(12): 1480-1486 DOI： 10.3788/fgxb20143512.1480.

LI Peng, FAN Di, Gao Jie etc. RS Latch Realization by Using Asymmetric Porphyrin Covalently Connecting to Mesoporous Silica Films[J]. Chinese Journal of Luminescence, 2014,35(12): 1480-1486 DOI： 10.3788/fgxb20143512.1480.

摘要

合成了5-(4-氨基苯基)-10

20-三苯基卟啉(ATPP)

并成功将其以共价嫁接的形式固载于介孔二氧化硅薄膜.基于卟啉化合物对酸碱的特异性响应

实现了对RS触发器逻辑功能的模拟.卟啉化合物被共价固载于介孔薄膜材料使得该分子逻辑器件具有相对较大的表面积、周期性排布的均一孔道结构以及高的光透过性等介孔薄膜材料的优异性质.这种混合多孔结构不但有利于嫁接于介孔材料中的卟啉与酸碱的更有效相互作用

而且还使酸碱输入能够被更加彻底地清除.

Abstract

5-(4-aminophenyl)-10

20-triphenyl-porphyrin (H

ATPP) was prepared and covalently connected to mesoporous silica thin films. Based on the porphyrin compounds's characteristic of being sensitive to acid and base

the molecular logics of RS-latch for sequential logic were achieved. The molecular logics have the advantages of larger surface area

periodic arranged uniform pore structure

and high transmission because of the covalent connection of porphyrin compounds to mesoporous silica. This hybrid mesoporous structure is not only advantageous to the interaction between the inputs and response materials

but also advantageous to the separation of the response materials and inputs without information loss.

关键词

卟啉分子逻辑介孔分子筛薄膜共价接RS触发器

Keywords

porphyrinmolecular logicmesoporous silica thin filmcovalently connectedRS-latch

references

Pischel U. Advanced molecular logic with memory function [J]. Angew. Chem. Int. Ed., 2010, 49(8):1356-1358.

Andrasson J, Pischel U, Straight S D, et al. All-photonic multifunctional molecular logic device [J]. J. Am. Chem. Soc., 2011, 133(30):11641-11648.

Gust D, Andreasson J, Pischel U, et al. Data and signal processing using photochromic molecules [J]. Chem. Commun., 2012, 48(14):1947-1957.

Andreasson J, Pischel U. Smart molecules at work-mimicking advanced logic operations [J]. Chem. Soc. Rev., 2010, 39(1):174-188.

De Ruiter G, Van der Boom M E. Surface-confined assemblies and polymers for molecular logic [J]. Acc. Chem. Res., 2011, 44(8):563-573.

De Silva P A, Gunaratne N H Q, McCoy C P. A molecular photoionic AND gate based on fluorescent signaling [J]. Nature, 1993, 364(6432):42-44.

Langford S J, Yann T. Molecular logic: A half-subtractor based on tetraphenylporphyrin [J]. J. Am. Chem. Soc., 2003, 125(37):11198-11199.

Margulies D, Melman G, Shanzer A. Fluorescein as a model molecular calculator with reset capability [J]. Nat. Mater., 2005, 4(10):768-771.

Pischel U. Chemical approaches to molecular logic elements for addition and subtraction [J]. Angew. Chem. Int. Ed., 2007, 46(22):4026-4040.

Andreasson J, Straight S D, Moore T A, et al. Molecular all-photonic encoder-decoder [J]. J. Am. Chem. Soc., 2008, 130(33):11122-11128.

Ceroni P, Bergamini G, Balzani V. Old molecules, new concepts: [Ru(bpy)3] 2+ as a molecular encoder-decoder [J]. Angew. Chem. Int. Ed., 2009, 48(45):8516-8518.

Amelia M, Baroncini M, Credi A. A simple unimolecular multiplexer/demultiplexer [J]. Angew. Chem. Int. Ed., 2008, 47(33):6240-6243.

Raymo F M, Alvarado R J, Giordani S, et al. Memory effects based on intermolecular photoinduced proton transfer [J]. J. Am. Chem. Soc., 2003, 125(8):2361-2364.

Baron R, Onopriyenko A, Katz E, et al. An electrochemical/photochemical information processing system using a monolayer-functionalized electrode [J]. Chem. Commun., 2006(20):2147-2149.

Pita M, Strack G, MacVittie K, et al. Set-reset flip-flop memory based on enzyme reactions: Toward memory systems controlled by biochemical pathways [J]. J. Phys. Chem. B, 2009, 113(49):16071-16076.

Periyasamy G, Collin J P, Sauvage J P, et al. Electrochemically driven sequential machines: An implementation of copper rotaxanes [J]. Chem. Eur. J., 2009, 15(6):1310-1313.

Pischel U, Andreasson J. A simplicity-guided approach toward molecular set-reset memories [J]. New J. Chem., 2010, 34(12):2701-2703.

De Ruiter G, Van der Boom M E. Sequential logic and random access memory (RAM): A molecular approach [J]. J. Mater. Chem., 2011, 21(44):17575-17581.

Remn P, Blter M, Li S, et al. An all-photonic molecule-based D flip-flop [J]. J. Am. Chem. Soc., 2011, 133(51):20742-20745.

De Ruiter G, Tartakovsky E, Oded N, et al. Sequential logic operations with surface-confined polypyridyl complexes displaying molecular random access memory features [J]. Angew. Chem. Int. Ed., 2010, 49(1):169-172.

Sanchez C, Lebeau B, Chaput F, et al. Optical properties of functional hybrid organic-inorganic nanocomposites [J]. Adv. Mater., 2003, 15(23):1969-1994.

De la Luz V, Garcia-Sanchez M A, Campero A. Luminescent porphyrinosilica obtained by the sol-gel method [J]. J. Non-Cryst. Solids, 2007, 353(22-23):2143-2149.

Lu Y F, Ganguli R, Drewien C A, et al. Continuous formation of supported cubic and hexagonal mesoporous films by sol gel dip-coating [J]. Nature, 1997, 389(6649):364-368.

Kruper W J, Chamberlin T A, Kochanny M. Regiospecific aryl nitration of meso-substituted tetraarylporphyrinsA simple route to bifunctional porphyrins [J]. J. Org. Chem., 1989, 54(11):2753-2756.

Lei B F, Li B, Zhang H R, et al. Mesostructured silica chemically doped with Ru-Ⅱ as a superior optical oxygen sensor [J]. Adv. Funct. Mater., 2006, 16(14):1883-1891.

Tao S Y, Li G T, Zhu H S. Metalloporphyrins as sensing elements for the rapid detection of trace TNT vapor [J]. J. Mater. Chem., 2006, 16(46):4521-4528.hanny M. Regiospecific aryl nitration of meso-substituted tetraarylporphyrins - a simple route to bifunctional porphyrins[J]. J. Org. Chem., 1989, 54 (11): 2753-2756.

Lei B F, Li B, Zhang H R, et al., Mesostructured silica chemically doped with Ru-II as a superior optical oxygen sensor[J]. Adv. Funct. Mater., 2006, 16 (14): 1883-1891.

Tao S Y, Li G T, Zhu H S. Metalloporphyrins as sensing elements for the rapid detection of trace TNT vapor[J]. J. Mater. Chem., 2006, 16 (46): 4521-4528.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

不对称卟啉共价固载于硅基介孔薄膜材料模拟反馈回路的研究

卟啉掺杂MEH-PPV的发光性能

皮肤的光学性质研究

方酸菁染料在电致发光层中的能量传递研究