球形BaZnF4:Yb,Er纳米颗粒的热分解法合成及其上转换发光性质

阿斯娜; 马乌吉斯古楞; 德格吉呼

doi:10.3788/fgxb20143512.1422

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球形BaZnF₄:Yb,Er纳米颗粒的热分解法合成及其上转换发光性质

材料合成及性能 | 更新时间：2020-08-12

- 球形BaZnF₄:Yb,Er纳米颗粒的热分解法合成及其上转换发光性质
- Thermal Decomposition Synthesis and Upconversion Luminescence Properties of Spherical BaZnF₄:Yb,Er Nanoparticles
- 发光学报 2014年35卷第12期页码：1422-1426
- 作者机构：
  
  1. 内蒙古师范大学化学与环境科学学院,内蒙古呼和浩特,010022
  2. 吉林大学集成光电子学国家重点联合实验室,吉林长春,130012
  3. 内蒙古师范大学内蒙古功能材料物理与化学重点实验室,内蒙古呼和浩特,010022
- 作者简介：
- 基金信息：
  
  国家自然科学基金(21261016)();内蒙古自然科学基金(2012MS0209,2013MS0218)();吉林大学集成光电子学国家重点联合实验室开放课题(IOSK
- DOI：10.3788/fgxb20143512.1422
  中图分类号： O482.31
- 纸质出版日期：2014-12-3，
  
  收稿日期：2014-9-11，
  
  修回日期：2014-10-15，
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阿斯娜, 马乌吉斯古楞, 德格吉呼. 球形BaZnF4:Yb,Er纳米颗粒的热分解法合成及其上转换发光性质[J]. 发光学报, 2014,35(12): 1422-1426

BAO Asina, MA Wujisiguleng, DE Gejihu. Thermal Decomposition Synthesis and Upconversion Luminescence Properties of Spherical BaZnF4:Yb,Er Nanoparticles[J]. Chinese Journal of Luminescence, 2014,35(12): 1422-1426
阿斯娜, 马乌吉斯古楞, 德格吉呼. 球形BaZnF4:Yb,Er纳米颗粒的热分解法合成及其上转换发光性质[J]. 发光学报, 2014,35(12): 1422-1426 DOI： 10.3788/fgxb20143512.1422.

BAO Asina, MA Wujisiguleng, DE Gejihu. Thermal Decomposition Synthesis and Upconversion Luminescence Properties of Spherical BaZnF4:Yb,Er Nanoparticles[J]. Chinese Journal of Luminescence, 2014,35(12): 1422-1426 DOI： 10.3788/fgxb20143512.1422.

摘要

采用热分解法制备了BaZnF

:Yb

Er纳米颗粒.通过荧光分光光度计、X射线粉末衍射仪(XRD)和透射电子显微镜(TEM)对样品进行了表征.合成样品的形貌为球形

晶相为四方相

平均粒径为8 nm.当敏化剂Yb

和激活剂Er

的掺杂摩尔分数分别为20%和4%时

样品的发光性能较好.绿光和红光发射对应的辐射跃迁分别为Er

离子的

11/2

15/2

(绿光)和

3/2

15/2

(绿光)

以及Er

离子的

9/2

15/2

(红光).

Abstract

A series of BaZnF

:Er

upconversion luminescence nanoparticles with various doping concentrations were synthesized

via

thermal decomposition method. X-ray diffraction (XRD)

transmission electron microscope (TEM) and fluorescence spectrophotometer were used to investigate the morphology

crystal structure and upconversion properties of the samples. The morphology of the sample is ball shape with an average size about 8 nm. 4%Er

and 20%Yb

are the best doping mole fraction. Red and green emissions were observed for the synthesized samples under 980 nm excitation. The red and green emissions are corresponding to the transitions

11/2

15/2

(Green)

3/2

15/2

(Green) of Er

9/2

15/2

(Red) of Er

ions

respectively.

关键词

稀土掺杂BaZnF4热分解法上转换发光

Keywords

rare earth dopingBaZnF4thermal decompositionupconversion luminescence

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