低温制备二氧化钛纳米薄膜及其光伏性能研究

马帅; 曹磊; 张一梅

doi:10.3788/fgxb20143511.1322

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低温制备二氧化钛纳米薄膜及其光伏性能研究

材料合成及性能 | 更新时间：2020-08-12

- 低温制备二氧化钛纳米薄膜及其光伏性能研究
- Research on The Photovoltaic Properties of Low-temperature Processed Titanium Oxide Nanoporous Membranes
- 发光学报 2014年35卷第11期页码：1322-1330
- 作者机构：
  
  青岛科技大学材料科学与工程学院,山东青岛,266042
- 作者简介：
- 基金信息：
  
  青岛市博士后应用研究项目资助()
- DOI：10.3788/fgxb20143511.1322
  中图分类号： O484.4;TM615;TM914.4
- 纸质出版日期：2014-11-3，
  
  收稿日期：2014-8-29，
  
  修回日期：2014-9-17，
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马帅, 曹磊, 张一梅. 低温制备二氧化钛纳米薄膜及其光伏性能研究[J]. 发光学报, 2014,35(11): 1322-1330

MA Shuai, CAO Lei, ZHANG Yi-mei. Research on The Photovoltaic Properties of Low-temperature Processed Titanium Oxide Nanoporous Membranes[J]. Chinese Journal of Luminescence, 2014,35(11): 1322-1330
马帅, 曹磊, 张一梅. 低温制备二氧化钛纳米薄膜及其光伏性能研究[J]. 发光学报, 2014,35(11): 1322-1330 DOI： 10.3788/fgxb20143511.1322.

MA Shuai, CAO Lei, ZHANG Yi-mei. Research on The Photovoltaic Properties of Low-temperature Processed Titanium Oxide Nanoporous Membranes[J]. Chinese Journal of Luminescence, 2014,35(11): 1322-1330 DOI： 10.3788/fgxb20143511.1322.

摘要

研究一种易实现的低温合成TiO

薄膜电极的方法。实验采用氨水、盐酸和去离子水分别作为无机粘结剂、无水乙醇作为分散剂来合成TiO

浆料

重点研究了粘结剂/分散剂质量比对薄膜制备的影响。采用合成的TiO

电极进行全固态染料敏化太阳能电池的组装。综合浆料粘稠度测试、薄膜形貌表征以及电池时域/频域光电测试等结果

分析了宏观光伏特性与微观载流子输运机制。最终得到最佳的无机粘结剂/分散剂质量比

相应电池的光电转换效率达到1.45%。

Abstract

In this contribution

a simple method for synthesizing the TiO

nanoporous electrodes processed at low temperature was explored. Specifically

three types of inorganic binders

i.e.

ammonia

hydrochloric acid and deionized water

mixed with ethanol as dispersant were used to prepare the TiO

pastes. The effects of the mass ratio between the inorganic binders and dispersant on film properties were particularly studied. Moreover

the complete all-solid-state dye-sensitized solar cells were fabricated based on prepared TiO

electrodes. Combining the viscosity test of TiO

paste and the micro-morphology measurement to the photoelectric characterization in time-/frequency-domain

the comprehensive analysis presents the interrelation between macroscopic photovoltaic performance and microscopic charge carrier transport mechanisms. Eventually the optimal inorganic binder and its mass ratio

versus

dispersant has been found out

and the maximum power conversion efficiency of the corresponding cell can reach up to 1.45%.

关键词

二氧化钛低温制备光阳极全固态染料敏化太阳能电池光电转换效率

Keywords

titanium oxidelow-temperature processedphotoelectrodeall-solid-state dye-sensitized solar cellspower conversion efficiency

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