CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+) 荧光粉的制备与光谱调控

董晓睿; 付作岭; 王长庚; 张方程

doi:10.3788/fgxb20143511.1311

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CaZrO₃:Ln (Ln=Pr³⁺, Sm³⁺, Tb³⁺, Dy³⁺, Tm³⁺) 荧光粉的制备与光谱调控

材料合成及性能 | 更新时间：2020-08-12

- CaZrO₃:Ln (Ln=Pr³⁺, Sm³⁺, Tb³⁺, Dy³⁺, Tm³⁺) 荧光粉的制备与光谱调控
- Synthesis and Spectral Tuning of CaZrO₃:Ln (Ln=Pr³⁺, Sm³⁺, Tb³⁺, Dy³⁺, Tm³⁺)
- 发光学报 2014年35卷第11期页码：1311-1316
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所,吉林长春,中国,130033
  2. 吉林大学物理学院,吉林长春,130021
  3. 东北电力大学理学院,吉林吉林,132012
- 作者简介：
- 基金信息：
  
  东北电力大学博士科研启动基金(BSJXM-201314)();吉林省科技发展计划(20130522173JH)资助项目()
- DOI：10.3788/fgxb20143511.1311
  中图分类号： O482.31
- 纸质出版日期：2014-11-3，
  
  收稿日期：2014-8-12，
  
  修回日期：2014-9-16，
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董晓睿, 付作岭, 王长庚等. CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+) 荧光粉的制备与光谱调控[J]. 发光学报, 2014,35(11): 1311-1316

DONG Xiao-rui, FU Zuo-ling, WANG Chang-geng etc. Synthesis and Spectral Tuning of CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+)[J]. Chinese Journal of Luminescence, 2014,35(11): 1311-1316
董晓睿, 付作岭, 王长庚等. CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+) 荧光粉的制备与光谱调控[J]. 发光学报, 2014,35(11): 1311-1316 DOI： 10.3788/fgxb20143511.1311.

DONG Xiao-rui, FU Zuo-ling, WANG Chang-geng etc. Synthesis and Spectral Tuning of CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+)[J]. Chinese Journal of Luminescence, 2014,35(11): 1311-1316 DOI： 10.3788/fgxb20143511.1311.

摘要

采用高温固相法合成了稀土离子Pr

、Sm

、Tb

、Dy

、Tm

掺杂的正交相CaZrO

荧光粉。利用X射线粉末衍射(XRD)对样品的结构进行表征

并通过荧光光谱对其发光性质进行了研究。在适当近紫外或蓝光激发下

CaZrO

:Pr

产生很强的绿光发射

CaZrO

:Sm

可发射550~700 nm的红橙光

在CaZrO

中可获得良好的蓝光发射。研究结果表明

通过改变CaZrO

中的掺杂离子可实现其发光颜色的调控

稀土离子掺杂CaZrO

荧光粉是很有潜力的新型发光材料。

Abstract

The orthorhombic CaZrO

(

=Pr

) were successfully synthesized by solid-state reaction method. The crystalline structure of the samples were characterized by X-ray diffraction (XRD). The luminescence properties were investigated using photoluminescence spectra. Under appropriate near UV- or blue light-radiation

CaZrO

:Pr

showed strong green light emission

CaZrO

:Sm

showed well reddish orange light in the range of 550-700 nm

and CaZrO

:Tm

generated well blue light emission. The results indicate that spectral tuning can be realized by adjusting active ions in CaZrO

thus rare earth ions-doped CaZrO

phosphors can be exploited as new luminescence materials.

关键词

CaZrO3稀土离子发光性质光谱调控

Keywords

CaZrO3rare earth ionsoptical propertiesspectral tuning

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