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材料化学工程国家重点实验室 南京工业大学材料科学与工程学院,江苏 南京,210009
纸质出版日期:2013-3-10,
收稿日期:2012-11-12,
修回日期:2013-1-9,
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丁明烨, 陆春华, 操林海, 黄文娟, 蒋晨飞, 倪亚茹, 许仲梓. 不同玻璃组分对&beta;-NaYF<sub>4</sub>:Yb<sup>3+</sup>,Er<sup>3+</sup>/Tm<sup>3+</sup>粉体的侵蚀性研究及对发光性能的影响[J]. 发光学报, 2013,34(3): 282-291
DING Ming-ye, LU Chun-hua, CAO Lin-hai, HUANG Wen-juan, JIANG Chen-fei, NI Ya-ru, XU Zhong-zi. Effect of Different Glasses on Solubility and Luminescent Properties of &beta;-NaYF<sub>4</sub>:Yb<sup>3+</sup>,Er<sup>3+</sup>/Tm<sup>3+</sup> Microcrystals[J]. Chinese Journal of Luminescence, 2013,34(3): 282-291
丁明烨, 陆春华, 操林海, 黄文娟, 蒋晨飞, 倪亚茹, 许仲梓. 不同玻璃组分对&beta;-NaYF<sub>4</sub>:Yb<sup>3+</sup>,Er<sup>3+</sup>/Tm<sup>3+</sup>粉体的侵蚀性研究及对发光性能的影响[J]. 发光学报, 2013,34(3): 282-291 DOI: 10.3788/fgxb20133403.0282.
DING Ming-ye, LU Chun-hua, CAO Lin-hai, HUANG Wen-juan, JIANG Chen-fei, NI Ya-ru, XU Zhong-zi. Effect of Different Glasses on Solubility and Luminescent Properties of &beta;-NaYF<sub>4</sub>:Yb<sup>3+</sup>,Er<sup>3+</sup>/Tm<sup>3+</sup> Microcrystals[J]. Chinese Journal of Luminescence, 2013,34(3): 282-291 DOI: 10.3788/fgxb20133403.0282.
选用硅酸盐、硼酸盐以及磷酸盐3种常用的玻璃体系
与-NaYF
4
:Yb
3+
Er
3+
/Tm
3+
粉体均匀混合压片后在不同的温度(400~700 ℃)下进行热处理。采用X射线衍射技术和荧光光谱技术等测试手段研究不同玻璃形成体以及碱金属离子对-NaYF
4
:Yb
3+
Er
3+
/Tm
3+
粉体的侵蚀情况以及对发光性能的影响。研究结果表明
在硼酸盐玻璃体系与-NaYF
4
:Yb
3+
Er
3+
/Tm
3+
粉体复合热处理过程中
Li
+
和K
+
离子会取代-NaYF
4
晶体中Na原子的位置。 在相同热处理温度下
不同玻璃体系与-NaYF
4
晶体反应剧烈程度:磷酸盐
>
硼酸盐
>
硅酸盐。
The composites of -NaYF
4
:Yb
3+
Er
3+
/Tm
3+
incorporated in silicate glasses
borate glasses and phosphate glasses were formed into pellets under pressure and annealed under different temperature (400~700 ℃). The effect of different glasses formers and alkali metal ions on solubility and luminescent properties of -NaYF
4
:Yb
3+
Er
3+
/Tm
3+
microcrystals were characterized by X-ray diffraction (XRD)
photoluminescence (PL) spectra. The results show that Li
+
ions and K
+
ions can replace Na
+
ions in -NaYF
4
microcrystals at low heat treatment temperature. The solubility of -NaYF
4
:Yb
3+
Er
3+
/Tm
3+
microcrystals in different glasses systems is investigated as follows: phosphate glasses
>
borate glasses
>
silicate glasses.
&beta-NaYF4离子取代玻璃液侵蚀热处理上转换发光
&beta-NaYF4ionic substitutionsolubilityheat treatmentupconversion
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