基于新型透明导电电极的有机光伏器件的制备与表征

田苗苗; 李春杰; 贺小光; 于立军; 祁金刚; 曲雪松; 孙晓园; 范翊; 王宁

doi:10.3788/fgxb20133402.0192

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基于新型透明导电电极的有机光伏器件的制备与表征

器件制备及器件物理 | 更新时间：2020-08-12

- 基于新型透明导电电极的有机光伏器件的制备与表征
- Preparation and Characteristics of Organic Solar Cells Based on Novel Transparent Conducting Oxides
- 发光学报 2013年34卷第2期页码：192-196
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室,吉林长春,130033
  2. 长春师范学院物理学院, 吉林长春 130032
  3. 中国科学院长春应用化学研究所高分子物理及化学国家重点实验室,吉林长春,130022
  4. 中国科学院长春应用化学研究所高分子复合材料工程实验室, 吉林长春 130022
- 作者简介：
- 基金信息：
  
  国家自然科学基金(21104077,51202019)();吉林省教育厅"();十二五"();科学技术研究项目(吉教科合字[2012]第226号,吉教科
- DOI：10.3788/fgxb20133402.0192
  中图分类号： TN383+.1
- 纸质出版日期：2013-2-10，
  
  收稿日期：2012-10-28，
  
  修回日期：2012-12-5，
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田苗苗, 李春杰, 贺小光, 于立军, 祁金刚, 曲雪松, 孙晓园, 范翊, 王宁. 基于新型透明导电电极的有机光伏器件的制备与表征[J]. 发光学报, 2013,34(2): 192-196

TIAN Miao-miao, LI Chun-jie, HE Xiao-guang, YU Li-jun, QI Jin-gang, QU Xue-song, SUN Xiao-yuan, FAN Yi, WANG Ning. Preparation and Characteristics of Organic Solar Cells Based on Novel Transparent Conducting Oxides[J]. Chinese Journal of Luminescence, 2013,34(2): 192-196
田苗苗, 李春杰, 贺小光, 于立军, 祁金刚, 曲雪松, 孙晓园, 范翊, 王宁. 基于新型透明导电电极的有机光伏器件的制备与表征[J]. 发光学报, 2013,34(2): 192-196 DOI： 10.3788/fgxb20133402.0192.

TIAN Miao-miao, LI Chun-jie, HE Xiao-guang, YU Li-jun, QI Jin-gang, QU Xue-song, SUN Xiao-yuan, FAN Yi, WANG Ning. Preparation and Characteristics of Organic Solar Cells Based on Novel Transparent Conducting Oxides[J]. Chinese Journal of Luminescence, 2013,34(2): 192-196 DOI： 10.3788/fgxb20133402.0192.

摘要

介绍了一种高功函数的掺杂钛酸镧的氧化铟透明导电阳极并用其制备了有机光伏器件

详细研究了该材料对器件性能的影响

同时对比了ITO为阳极的器件性能。由于ILTO具有较好的掺杂、较高的透过率和高的有效表面功函数等优异的光电特性

与基于ITO的器件相比

ILTO的有机光伏器件的填充因子、短路电流及功率转换效率均得到了优化与提升

填充因子由61.1%提高到63.5%

短路电流由3.26 mA/cm

提高到5.64 mA/cm

功率转换效率由0.91%提高到1.45%。

Abstract

Two heterojunction organic solar cells based different anode (ITO and ILTO) were investigated to compare the power conversion efficiency (PCE) of organic solar cell (OSCs) in two types of devices with different hole-extracting electrodes. Except for a slight decrease in the open circuit voltage (

)

the OSC with an ILTO anode exhibits an obvious increase in short-circuit current (

) and fill factor (

) as comparing with that of the ITO-anode OSC (

=0.412 V

vs.

0.413 V

=5.64 mA穋m

-2

vs.

3.26 mA穋m

-2

=0.635

vs.

0.611). Sequentially

a power conversion efficiency (PCE) of 1.45% in the ILTO-anode OSC is demonstrated while only 0.91% for the ITO-anode OSC is achieved. The improved PCE in the ILTO-anode OSC is mainly attributed to the energy level alignment between the work function of ILTO and the HOMO level of CuPc

and a higher light transmission in the UV region of the ILTO. Our results indicate that a suitable TCO can effectively improve the performance of organic optoelectronic devices.

关键词

透明导电电极有机太阳能电池功函数

Keywords

transparent conductive anodeorganic solar cellwork function

references

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