以AgCl和1,2-二(4-吡啶)乙烷为原料合成的二维无机-有机杂化聚合物的晶体结构及荧光性质

谢安; 骆耿耿

doi:10.3788/fgxb20123311.1192

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以AgCl和1,2-二(4-吡啶)乙烷为原料合成的二维无机-有机杂化聚合物的晶体结构及荧光性质

材料合成及性能研究 | 更新时间：2020-08-12

- 以AgCl和1,2-二(4-吡啶)乙烷为原料合成的二维无机-有机杂化聚合物的晶体结构及荧光性质
- Crystal Structure and Luminescent Property of 2D Hybrid Silver Chloride with 1,2-Bis(4-pyridyl)Ethane
- 发光学报 2012年33卷第11期页码：1192-1197
- 作者机构：
  
  1. 厦门理工学院材料科学与工程系,福建厦门,361024
  2. 华侨大学材料科学与工程学院,福建厦门,361021
- 作者简介：
- 基金信息：
  
  国家自然科学基金(11204258,21201066)();福建省自然科学基金杰出青年项目(2012J06024)();福建省自然科学基金(2011J05142,201
- DOI：10.3788/fgxb20123311.1192
  中图分类号： O469;O756;O613.42
- 纸质出版日期：2012-11-10，
  
  收稿日期：2012-7-5，
  
  修回日期：2012-9-7，
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谢安, 骆耿耿. 以AgCl和1,2-二(4-吡啶)乙烷为原料合成的二维无机-有机杂化聚合物的晶体结构及荧光性质[J]. 发光学报, 2012,(11): 1192-1197

XIE An, LUO Geng-geng. Crystal Structure and Luminescent Property of 2D Hybrid Silver Chloride with 1,2-Bis(4-pyridyl)Ethane[J]. Chinese Journal of Luminescence, 2012,(11): 1192-1197
谢安, 骆耿耿. 以AgCl和1,2-二(4-吡啶)乙烷为原料合成的二维无机-有机杂化聚合物的晶体结构及荧光性质[J]. 发光学报, 2012,(11): 1192-1197 DOI： 10.3788/fgxb20123311.1192.

XIE An, LUO Geng-geng. Crystal Structure and Luminescent Property of 2D Hybrid Silver Chloride with 1,2-Bis(4-pyridyl)Ethane[J]. Chinese Journal of Luminescence, 2012,(11): 1192-1197 DOI： 10.3788/fgxb20123311.1192.

摘要

以AgCl与柔性配体1

2-二(4-吡啶)乙烷(bpe)为原料

在1:1的甲醇-水混合溶剂中超声反应合成了一个新的无机-有机杂化聚合物[Ag

(BPE)

]

(

)

并对该配合物进行了元素分析、红外光谱分析、热重分析、发光测试以及晶体结构研究。配合物属于三斜晶系

空间群

a=0.998 8(2) nm

b=1.115 1(2) nm

c=1.269 5(3) nm

α=64.27(3)°

β=85.71(3)°

γ=86.70(3)°

V=1.269 7(5) nm

Z=2。单晶结构分析表明

该化合物

含有一维的(Ag

)

链

双氮配体BPE进一步连接该一维链形成了二维双层结构。固体发光性能测试表明

该化合物在385 nm光激发下能发出峰值为525 nm的黄光。此外

热分析表明

该化合物热稳定性可达到170℃。

Abstract

Using the flexible dipyridyl ligand 1

2-bis(4-pyridyl)ethane (bpe)

a hybrid silver chloride [Ag

-(bpe)

]

(1) has been synthesized by ultrasonic method. The experimental results indicate that it belongs to triclinic system with space group P1. The structure of complex

features 1D (Ag

)

chains

which are further linked by bipodal spacers bpe to form a 2D bilayer structure. In addition

the complex 1 shows a strong yellow emission band that peaks at 525 nm (λ

=385 nm) in the solid state at room temperature

and it is thermally stable below 170℃.

关键词

配位聚合物12-二(4-吡啶)乙烷超声合成发光性质

Keywords

references

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