碱液修饰对硅纳米线阵列电池光谱响应的影响

蒋玉荣; 秦瑞平; 边长贤; 黄静; 胡晓峰; 杨海刚; 马恒; 常方高

doi:10.3788/fgxb20123309.0996

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碱液修饰对硅纳米线阵列电池光谱响应的影响

器件制备及器件物理 | 更新时间：2020-08-12

- 碱液修饰对硅纳米线阵列电池光谱响应的影响
- Effect of Alkali Solution Modifying on The Spectral Response of Silicon Nanowire Arrays Solar Cell
- 发光学报 2012年33卷第9期页码：996-1000
- 作者机构：
  
  1. 河南师范大学物理与信息工程学院,河南新乡,453007
  2. 河南省光伏材料重点实验室,河南新乡,453007
  3. 河南省新乡市第五职业中专,河南新乡,453007
- 作者简介：
- 基金信息：
  
  国家自然科学基金(11074066)();河南省重点科技攻关计划(102102210184)();河南师范大学校青年基金(521)资助项目()
- DOI：10.3788/fgxb20123309.0996
  中图分类号： TB34
- 纸质出版日期：2012-9-10，
  
  收稿日期：2012-5-10，
  
  修回日期：2012-6-24，
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蒋玉荣, 秦瑞平, 边长贤, 黄静, 胡晓峰, 杨海刚, 马恒, 常方高. 碱液修饰对硅纳米线阵列电池光谱响应的影响[J]. 发光学报, 2012,33(9): 996-1000

JIANG Yu-rong, QING Rui-ping, BIAN Chang-xian, HUANG Jing, HU Xiao-feng, YANG Hai-gang, MA Heng, CHANG Fang-gao. Effect of Alkali Solution Modifying on The Spectral Response of Silicon Nanowire Arrays Solar Cell[J]. Chinese Journal of Luminescence, 2012,33(9): 996-1000
蒋玉荣, 秦瑞平, 边长贤, 黄静, 胡晓峰, 杨海刚, 马恒, 常方高. 碱液修饰对硅纳米线阵列电池光谱响应的影响[J]. 发光学报, 2012,33(9): 996-1000 DOI： 10.3788/fgxb20123309.0996.

JIANG Yu-rong, QING Rui-ping, BIAN Chang-xian, HUANG Jing, HU Xiao-feng, YANG Hai-gang, MA Heng, CHANG Fang-gao. Effect of Alkali Solution Modifying on The Spectral Response of Silicon Nanowire Arrays Solar Cell[J]. Chinese Journal of Luminescence, 2012,33(9): 996-1000 DOI： 10.3788/fgxb20123309.0996.

摘要

采用金属催化化学腐蚀法在p型(100)硅基底上制备了硅纳米阵列

然后用碱溶液对纳米线阵列进行修饰。分别研究了碱液修饰对硅纳米线阵列形貌、光电性质的影响。研究表明: 与绒面及纳米线阵列相比

碱修饰30 s硅纳米线阵列的表面分散均匀

反射率降低;光谱响应度显著提高

并且出现最大量子效率对应波长红移现象。最后

详细讨论了碱液修饰硅纳米线阵列电池对光谱响应的影响机制。

Abstract

The vertically aligned silicon nanowire (SiNW) arrays have been fabricated by using an electroless etching method

and then the nanowire arrays were modified by dipped the SiNWs in alkali solution. The effect of alkali solution on the morphology and photoelectric property of SiNWs were studied. The results showed that the spectral response of the modified SiNW arrays cell was obviously improved compared to the bunched SiNWs cell and textured cell. The phenomenon of wavelength red shift for maximum quantum efficiency was discovered

which confirmed that the photoelectric performance can be significantly improved at long wave band by alkali solution modified

but low spectral response at short wave period showed that charge carriers were seriously recombined at silicon nanowires near surface. When the alkali solution modified time increase to 60 s

the photoelectric response was weakened. In addition

the effect mechanism of alkali solution modify on the spectral response of SiNWs cell was tentatively analyzed and interpretation in detail.

关键词

碱液修饰量子效率光谱响应表面复合红移

Keywords

alkali liquor modifiedquantum efficiencyspectral responsesurface recombinationred shift

references

Hu L, Chen G. Analysis of optical absorption in silicon nanowire arrays for photovoltaic applications [J]. Nano Lett., 2007, 7(11):3249-3252.

Muskens O L, Rivas J G, Algra R E, et al. Design of light scattering in nanowire materials for photovoltaic applications [J]. Nano Lett., 2008, 8(9):2638-2642.

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Wu Y, Hu J J, Xu Y, et al. Fabrication of silicon nanowire(SiNW) arrays and application in solar cell [J]. ACTA Energiae Solaris Sinica (太阳能学报), 2006, 27(8):811-818 (in Chinese).

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