Er∶YbF3转光薄膜的制备及衬底温度对其光学性能的影响

张影; 王如志; 王祥夫; 曲铭浩; 李开宇; 颜晓红; 严辉

doi:10.3788/fgxb20123309.0979

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Er∶YbF₃转光薄膜的制备及衬底温度对其光学性能的影响

器件制备及器件物理 | 更新时间：2020-08-12

- Er∶YbF₃转光薄膜的制备及衬底温度对其光学性能的影响
- Preparation of Er∶YbF₃ Light Conversion Film and Its Effect of Substrate Temperature on Optical Properties
- 发光学报 2012年33卷第9期页码：979-984
- 作者机构：
  
  1. 北京工业大学材料科学与工程学院北京,100124
  2. 南京航空航天大学理学院,江苏南京,210016
- 作者简介：
- 基金信息：
  
  国家自然科学基金(51032002,11074017,11174021)();北京市"学术创新团队建设计划"(PHR201007101)();北京市科技新星计划(200
- DOI：10.3788/fgxb20123309.0979
  中图分类号： O482.31
- 纸质出版日期：2012-9-10，
  
  收稿日期：2012-6-8，
  
  修回日期：2012-6-24，
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张影, 王如志, 王祥夫, 曲铭浩, 李开宇, 颜晓红, 严辉. Er∶YbF3转光薄膜的制备及衬底温度对其光学性能的影响[J]. 发光学报, 2012,33(9): 979-984

ZhANG Ying, WANG Ru-zhi, WANG Xiang-fu, QU Ming-hao, LI Kai-yu, YAN Xiao-hong, YAN Hui. Preparation of Er∶YbF3 Light Conversion Film and Its Effect of Substrate Temperature on Optical Properties[J]. Chinese Journal of Luminescence, 2012,33(9): 979-984
张影, 王如志, 王祥夫, 曲铭浩, 李开宇, 颜晓红, 严辉. Er∶YbF3转光薄膜的制备及衬底温度对其光学性能的影响[J]. 发光学报, 2012,33(9): 979-984 DOI： 10.3788/fgxb20123309.0979.

ZhANG Ying, WANG Ru-zhi, WANG Xiang-fu, QU Ming-hao, LI Kai-yu, YAN Xiao-hong, YAN Hui. Preparation of Er∶YbF3 Light Conversion Film and Its Effect of Substrate Temperature on Optical Properties[J]. Chinese Journal of Luminescence, 2012,33(9): 979-984 DOI： 10.3788/fgxb20123309.0979.

摘要

采用脉冲激光沉积(PLD)方法在Si(100)衬底上成功制备了具有上下转换的Er∶YbF

转光薄膜。研究发现

所制备的Er∶YbF

转光薄膜实现了上下转换两种机制的结合

能有效地把紫外光和红外光转换到非晶硅太阳能电池最佳响应范围内的656 nm处。进一步分析了衬底温度对薄膜相结构及光学性能影响的物理机制。当衬底温度高于500 ℃时

薄膜会随着温度的升高而结晶性变强

但有杂相生成。研究结果表明

Er∶YbF

转光薄膜的光学性能在衬底温度为500 ℃时最佳

有望应用到非晶硅太阳能电池上使其光电效率提高。

Abstract

The light conversion film Er∶YbF

which has not only the up-conversion property but also the down-conversion property

was successfully prepared on Si (100) substrat. The effect of substrate temperature on films structural and optical properties was further studied. The results showed that the film achieves combination of up-conversion and down-conversion. It can effectively convert ultraviolet light and near infrared light into 656 nm which is the best response range to amorphous silicon. With increasing temperature

the crystallinity of the films were improved

but when substrate temperature exceeds 500 ℃

the impurity phases are found in the films. These results showed that optical properties of films with 500 ℃ were optimal. Moreover

the light conversion Er∶YbF

film may improve photoelectric conversion efficiency of amorphous silicon solar cell.

关键词

太阳能电池上转换下转换Er∶YbF3薄膜衬底温度

Keywords

solar cellsup-conversiondown-conversionEr∶YbF3 filmssubstrate temperature

references

Zhao J H, Wang A H, Green M A, et al. 19.8% efficient "honeycomb" textured multicrystalline and 24.4% monocrystalline silicon solar cells [J]. Appl. Phys. Lett., 1998, 73(14):1991-1993.

Green M A, Emery K, Hishikawa Y, et al. Solar cell efficiency tables(version 39) [J]. Progress in Photovoltaics:Research Applications, 2012, 20(1):12-20.

Bondi R, Lee S, Hwang G. Role of structural disorder in optical absorption in silicon [J]. Phys. Rev. B, 2010, 82(11):115214-1-12.

Aarts L, Jaeqx S, van der Ende B M, et al. Downconversion for the Er3+, Yb3+ couple in KPb2Cl5:A low-phonon frequency host [J]. J. Lumin., 2011, 131(4):608-613.

Trupke T, Green M A, Wurfel P. Improving solar cell efficiencies by down-conversion of high-energy photons [J]. J. Appl. Phys., 2002, 92(3):1668-1674.

de Wild J, Rath J K, Meijerink A, et al. Enhanced near-infrared response of a-Si∶H solar cells with β-NaYF4∶Yb3+(18%), Er3+(2%) upconversion phosphors [J]. Solar Energy Materials and Solar Cells, 2010, 94(12):2395-2398.

Wang X, Bu Y, Xiao S, et al. Upconversion in Ho3+-doped YbF3 particle prepared by coprecipitation method [J]. Appl. Phys. B, 2008, 93(4):801-807.

Bednarkiewicz A, Wawrzynczyk D, Gagor A, et al. Giant enhancement of upconversion in ultra-small Er3+/Yb3+∶NaYF4 nanoparticles via laser annealing [J]. Nanotechnology, 2012, 23(14):145705-1-8.

Li C X, Quan Z W, Yang P P, et al. Shape controllable synthesis and upconversion properties of NaYbF4/NaYbF4∶Er3+ and YbF3/YbF3∶Er3+ microstructures [J]. J. Mater. Chem., 2008, 18(12):1353-1361.

Li K Y, Wang R Z, Qu M H, et al. Downconversion materials preparation and the research of conversion efficiency in Pr3+, Yb3+ co-doped YPO4 [J]. Chin. J. Lumin.(发光学报), 2012, 33(5):486-491 (in Chinese).

Zhou Y H, Lu S C. Luminescent properties Er3+ and Er3+/Yb3+ doped nanocrystalline CaWO4 [J]. Chin. J. Lumin.(发光学报), 2010, 31(3):247-252 (in Chinese).

Wang X F, Yan X H. Ultraviolet and infrared photon-excited synergistic effect in Er3+-doped YbF3 phosphors [J]. Opt. Lett., 2011, 36(22):4353-4355.

Kennedy M, Ristau D, Niederwald H S. Ion beam-assisted deposition of MgF2 and YbF3 films [J]. Thin Solid Films, 1998, 333(1-2):191-195.

Wang Y, Zhang Y G, Chen W L, et al. Optical properties and residual stress of YbF3 thin films [J]. Appl. Opt., 2008, 47(13):c319-323.

Garapon C, Guy S, Skasasian S, et al. Nd3+-doped LiYF4 thin films prepared by pulsed laser deposition [J]. Appl. Phys. A, 2008, 91(3):493-499.

Liu M, Lee C, Kaneko M, et al. Microstructure related properties of lanthanum fluoride films deposited by molybdenum boat evaporation at 193 nm [J]. Thin Solid Films, 2005, 492(1-2):45-51.

Cruzvicente S, Martinezgamez M, Kiryanov A, et al. The luminescent properties of Er-Yb-doped fluorophosphate fiber glass preforms at high temperatures [J]. Opt. Mater., 2005, 27(10):1563-1566.

Perea A, Gonzalo J, Afonso C N, et al. On the growth of LiF films by pulsed laser deposition [J]. Appl.Surf. Sci., 1999, 138:533-537.

Han J G. Recent progress in thin film processing by magnetron sputtering with plasma diagnostics [J]. J. Phys. D: Appl. Phys., 2009, 42(4):043001-1-16.

Rashidian Vaziri M R, Hajiesmaeilbaigi F, Maleki M H. Monte Carlo simulation of the subsurface growth mode during pulsed laser deposition [J]. J. Appl. Phys., 2011, 110(4):043304-1-12.

Aarts L, Ende B V D, Reid M F, et al. Downconversion for solar cells in YF3∶Pr3+, Yb3+ [J]. Spectroscopy Letters, 2010, 43(5):373-381.

Shalav A, Richards B S, Green M A. Luminescent layers for enhanced silicon solar cell performance: Up-conversion [J]. Energy Mater. Sol. Cells, 2007, 91(9):829-842.

Ren Q, Dai R C, Shen Y H, et al. Color design based on upconversion luminescence of NaYF4∶Yb3+, Er3+ [J]. Chin.J. Lumin.(发光学报), 2010, 31(1):69-74 (in Chinese).

Ribeiro C T M, Zanatta A R, Nunes L A O, et al. Optical spectroscopy of Er3+ and Yb3+co-doped fluoroindate glasses [J]. J. Appl. Phys., 1998, 83(4):2256-1-5.

Reddy A S, Figueiredo N M, Cavaleiro A. Nanocrystalline SnO2 and Au∶SnO2 thin films prepared by direct current magnetron reactive sputtering [J]. Vacuum, 2012, 86(9):1323-1327.

Lee J H, Yeo B W, Park B O. Effects of the annealing treatment on electrical and optical properties of ZnO transparent conduction films by ultrasonic spraying pyrolysis [J]. Thin Solid Films, 2004, 457(2):333-337.

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