Tm3+ ,Yb3+共掺微晶玻璃蓝色上转换荧光的温度特性

郑龙江; 高晓阳; 徐伟; 张治国

doi:10.3788/fgxb20123309.0944

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Tm³⁺ ,Yb³⁺共掺微晶玻璃蓝色上转换荧光的温度特性

材料合成及性能研究 | 更新时间：2020-08-12

- Tm³⁺ ,Yb³⁺共掺微晶玻璃蓝色上转换荧光的温度特性
- Temperature Characteristic of Blue Up-conversion Emission in Tm³⁺,Yb³⁺ Codoped Oxyfluoride Glass Ceramic
- 发光学报 2012年33卷第9期页码：944-948
- 作者机构：
  
  1. 燕山大学河北省测试计量技术及仪器重点实验室,河北秦皇岛,066004
  2. 哈尔滨工业大学凝聚态科学与技术研究所,黑龙江哈尔滨,150001
- 作者简介：
- 基金信息：
  
  国家自然科学基金(61071202)资助项目()
- DOI：10.3788/fgxb20123309.0944
  中图分类号： O433
- 纸质出版日期：2012-9-10，
  
  收稿日期：2012-5-17，
  
  修回日期：2012-7-12，
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郑龙江, 高晓阳, 徐伟, 张治国. Tm3+ ,Yb3+共掺微晶玻璃蓝色上转换荧光的温度特性[J]. 发光学报, 2012,33(9): 944-948

ZHENG Long-jiang, GAO Xiao-yang, XU Wei, ZHANG Zhi-guo. Temperature Characteristic of Blue Up-conversion Emission in Tm3+,Yb3+ Codoped Oxyfluoride Glass Ceramic[J]. Chinese Journal of Luminescence, 2012,33(9): 944-948
郑龙江, 高晓阳, 徐伟, 张治国. Tm3+ ,Yb3+共掺微晶玻璃蓝色上转换荧光的温度特性[J]. 发光学报, 2012,33(9): 944-948 DOI： 10.3788/fgxb20123309.0944.

ZHENG Long-jiang, GAO Xiao-yang, XU Wei, ZHANG Zhi-guo. Temperature Characteristic of Blue Up-conversion Emission in Tm3+,Yb3+ Codoped Oxyfluoride Glass Ceramic[J]. Chinese Journal of Luminescence, 2012,33(9): 944-948 DOI： 10.3788/fgxb20123309.0944.

摘要

制备了Tm

共掺氟氧化物微晶玻璃

在980 nm二极管激光器泵浦下研究了其上转换发光。发现将前驱玻璃进行热处理后

源于Tm

的

能级到基态

跃迁所产生的蓝色上转换荧光在463 nm和476 nm出现明显劈裂。在此基础上分析了该劈裂蓝色上转换荧光在303~623 K范围内的温度特性。结果表明:Tm

共掺氟氧化物微晶玻璃蓝色上转换荧光可应用于光学测温

其测温最大灵敏度为4.2×10

-4

-1

相应温度为352 K。

Abstract

codoped oxyfluoride ceramic glass was prepared and their up-conversion luminescence property was studied under the pump of 980 nm diode laser. In the luminescence spectra of annealed samples

stark splits of luminescence were observed at 463 nm and 476 nm. Temperature property of this split was studied between 303 K and 623 K. The results indicate that Tm

codoped oxyfluoride ceramic glass could be used for temperature measurement according to luminescence intensity ratio. The best sensitivity is 4.2?10

-4

-1

at 352 K.

关键词

Tm3+微晶玻璃蓝色上转换荧光温度

Keywords

Tm3+oxyfluoride glass ceramicblue upconversionabsolute temperature

references

Liu L H, Wang J, Xin L, et al. Applied study and development of fiber-optic temperature sensor [J]. J. Scientific Instrument (仪器仪表学报), 2003, 24(5):547-550 (in Chinese).

Zhou G L, Ee S L, Deng W Y. Development and application of optical fiber temperature sensor [J]. Optical Communication Technology (光通信技术), 2007, 31(6):54-57 (in Chinese).

Andrea C, Joao F P, Luiz Antonio de O, et al. Infrared to visible frequency upconversion temperature sensor based on Er3+-doped PLZT transparent ceramics [J]. Solid State Communication, 2006, 137(1-2):1-5.

Sidiroglou F, Wade S A, Dragomir N M, et al. Effects of high-temperature heat treatment on Nd3+-doped optical fibers for use in fluorescence intensity ratio based temperature sensing [J]. Review of Scientific Instruments, 2003, 74(7):3524-3530.

Gonzalez P H, Luis S L, Perez S G, et al. Analysis of Er3+ and Ho3+ codoped sluoroindate glasses as wide range temperature sensor [J]. Materials Research Bulletin, 2011, 46:1051-1054.

Vineet K R, Rai D K, Rai S B. Pr3+ doped lithium tellurite glass as a temperature sensor [J]. Sensors and Actuators A, 2006, 128:14-17.

Wang R, Han P Z, Yu X C, et al. Properties of Er3+/Yb3+ co-doped phosphate glass-ceramics [J]. Chin. J. Lumin. (发光学报), 2010, 31(6):800-805 (in Chinese).

Jiang Q Y, Li C X, Ye R G, et al. Luminescence and energy transfer of Ce3+/Sm3+ co-doped glass and glass ceramics containing Zn2SiO4 nanocrystals for white LEDs [J]. Chin. J. Lumin.(发光学报), 2012, 33(4):371-376 (in Chinese).

Chen Z, Liu Z Y, Zhao D, et al. Effect of reactants concentration on NaYF4∶Yb3+,Tm3+ crystalline phase [J]. Chin. J. Lumin.(发光学报), 2011, 32(9):853-857 (in Chinese).

Wei X, Chen J M, Peng W, et al. Intense red upconversion luminescence from Tm3+,Yb3+codoped transparent glass ceramic [J]. Optics Lett., 2012, 37(2):205-207.

Zhang L, Zhang J J, Qi C H, et al. Energy transfer and upconversion in Tm3+,Yb3+ co-doped AlF3-based fluoride glass [J]. Chinese Journal of Lasers (中国激光), 2000, 27(5):460-465 (in Chinese).

Pollnau M, Gamelin D R, Luthi S R, et al. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems [J]. Physical Review, 2000, 61(5):3337-3346.

Mao L L, Lin H, Zhang Y, et al. Blue up-conversion in Yb3+ and Tm3+ co-doped KY(WO4)2 [J]. Chin. J. Lasers (中国激光), 2007, 34(5):710-714 (in Chinese).

Bao Y L, Zhao Z, Fu Y J. Temperature sensing based on fluorescence intensity ratio of rare earth doped fiber [J]. Optical Fiber and Electric Cable (光纤与光缆及其应用技术), 2010, 5(5):1-4 (in Chinese ).

Xu W, Li C G, Cao B S, et al. Optical temperature sensor based on up-conversion fluorescence emission in Yb3+∶Er3+ co-doped ceramics glass [J]. Chin. Phys. B, 2010, 19(12):127804-1-4.

Wade S A, Collins S F, Baxter G W. Fluorescence intensity ratio technique for optical fiber point temperature sensing [J]. Appl. Phys., 2003, 94(8):4743-4756.

Sergio F L L, Ulises R, Lalla E, et al. Temperature sensor based on the Er3+ green upconverted emission in a fuorotellurite glass [J]. Sensors and Actuators B: Chemical, 2011, 158:208-213.

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