混合碱液法生长的氧化锌晶体表面形貌及光致发光性质

赵兰玲; 王继扬; Robert I BOUGHTON; 李静; 张素芳; 韩树娟

doi:10.3788/fgxb20123309.0917

您当前的位置：

首页 >

文章列表页 >

混合碱液法生长的氧化锌晶体表面形貌及光致发光性质

材料合成及性能研究 | 更新时间：2020-08-12

- 混合碱液法生长的氧化锌晶体表面形貌及光致发光性质
- The Surface Morphology and Photoluminescence Properties of ZnO Crystals Synthesized by Flux Method
- 发光学报 2012年33卷第9期页码：917-922
- 作者机构：
  
  1. 山东大学晶体材料国家重点实验室,山东济南,250100
  2. Center for Material Science Bowling Green State University, Bowling Green OH USA,43403
  3. 衡水学院化学院,河北衡水,053000
- 作者简介：
- 基金信息：
  
  国家重点基础研究计划(11250005271008)();国家自然科学基金(50872066)();国家基础研究(2010CB833103)资助项目()
- DOI：10.3788/fgxb20123309.0917
  中图分类号： O731
- 纸质出版日期：2012-9-10，
  
  收稿日期：2012-5-17，
  
  修回日期：2012-7-23，
扫描看全文
赵兰玲, 王继扬, Robert I BOUGHTON, 李静, 张素芳, 韩树娟. 混合碱液法生长的氧化锌晶体表面形貌及光致发光性质[J]. 发光学报, 2012,33(9): 917-922

ZHAO Lan-ling, WANG Ji-yang, Robert I BOUGHTON, LI Jing, ZHANG Su-fang, HAN Shu-juan. The Surface Morphology and Photoluminescence Properties of ZnO Crystals Synthesized by Flux Method[J]. Chinese Journal of Luminescence, 2012,33(9): 917-922
赵兰玲, 王继扬, Robert I BOUGHTON, 李静, 张素芳, 韩树娟. 混合碱液法生长的氧化锌晶体表面形貌及光致发光性质[J]. 发光学报, 2012,33(9): 917-922 DOI： 10.3788/fgxb20123309.0917.

ZHAO Lan-ling, WANG Ji-yang, Robert I BOUGHTON, LI Jing, ZHANG Su-fang, HAN Shu-juan. The Surface Morphology and Photoluminescence Properties of ZnO Crystals Synthesized by Flux Method[J]. Chinese Journal of Luminescence, 2012,33(9): 917-922 DOI： 10.3788/fgxb20123309.0917.

摘要

从NaOH和LiOH的混合碱液中生长了具有不同六方形貌的淡黄色ZnO晶体。采用X射线粉末衍射的方法对晶体的物相进行了分析

利用光学显微镜和扫描电镜对晶体的形貌进行了表征

同时利用电子探针能谱仪对晶体的组分进行了分析。从晶体的室温光致发光谱图中可以观测到380

445

512

652 nm处存在与晶体结构和缺陷相关的发射峰。

Abstract

Transparent pale yellow ZnO crystals with different hexagonal morphology

such as hexagonal caps and hexagonal lamellae

have been successfully synthesized in molten hydrous NaOH-LiOH. The phase structure of the as-grown crystals was investigated by means of X-ray powder diffraction. Detailed surface morphology of the crystals was studied using optical microscopy and scanning electron microscopy. Elemental analysis of the synthesized crystals was performed using energy dispersive X-ray spectrum. The photoluminescence spectrum was employed to characterize the obtained crystals. Some ultraviolet

blue

green and red emission peaks were observed in the photoluminescence spectrum.

关键词

ZnONaOH-LiOH表面形貌晶体光致发光

Keywords

ZnONaOH-LiOHsurface morphologycrystalphotoluminescence

references

Ushio M, Sumiyoshi Y. Synthesis of ZnO single crystals by the flux method [J]. J. Mater. Sci., 1993, 28(1):218-224.

Thangavel R, Sabarinathan V, Ramasamy S, et al. Investigation on the growth of zinc oxide crystals from molten hydrous KOH solution and on the impedance analysis of zinc oxide crystals [J]. Materials Letters, 2007, 61(19-20):4090-4093.

Ohshima E, Ogino H, Niikura I, et al. Growth of the 2-in-size bulk ZnO single crystals by the hydrothermal method [J]. J. Cryst. Growth, 2004, 260(1-2):166-170.

Sekiguchi T, Miyashita S, Obara K, et al. Hydrothermal growth of ZnO single crystals and their optical characterization [J]. J. Cryst. Growth, 2000, 214/215(2):72-76.

Yanets L N, Lyutin V I. Status of hydrothermal growth of bulk ZnO: Latest issues and advantages [J]. J. Cryst. Growth, 2008, 310(5):993-999.

Ehrentraut D, Sato H, Miyamoto M, et al. Fabrication of homoepitaxial ZnO films by low-temperature liquid-phase epitaxy [J]. J. Cryst. Growth., 2006, 287(2):367-371.

Lin X Z, Li J, Wu Q H. ZnO films grown by the vapor transport method [J]. Chin. J. Lumin.(发光学报), 2010, 31(2):189-193 (in English).

Look D C, Reynolds D C, Sizelove J R, et al. Electrical properties of bulk ZnO [J]. Solid State Commum., 1998, 105(6):399-401.

Klimm D, Ganschow S, Schulz D, et al. The growth of ZnO crystals from the melt [J]. J. Cryst. Growth, 2008, 310(12):3009-3013.

Li Q W, Bian J M, Wang J W, et al. Optical properties of Co-doped ZnO nanorods synthesized by a hydrothermal method [J]. Chin. J. Lumin.(发光学报), 2010, 31(2):253-257 (in Chinese).

Xu C X, Sun X W, Yuen C, et al. Ultraviolet amplified spontaneous emission from self-oragonized network of zinc oxide nanofibers [J]. Appl. Phys. Lett., 2005, 86(1):011118-1-3.

Wang J, Gao L. Synthesis of uniform rod-like, multi-pod-like ZnO whiskers and their photoluminescence properties [J]. J. Cryst. Growth, 2004, 262(1-4):290-294.

van Dijken A, Meulenkamp E A, Vanmaekelbergh D, et al. Identification of the transition responsible for the visible emission in ZnO using quantum size effects [J]. J. Lumin., 2000, 90(3-4):123-128.

Wang M H, Zhu G P, Xu C X. Investigation on fabrication and photoluminescence property of an individual ZnO hexagonal microneedle [J]. Chin. J. Lumin.(发光学报), 2010, 31(1):105-108 (in Chinese).

Jiang X F, Li X L, Cao J F, et al. Stimulated emission property of novel ZnO nanoneedle pumped by two-photon [J]. Chin. J. Lumin.(发光学报), 2010, 31(1):109-113 (in Chinese).

Vanheusden K, Warren W L, Seager C H, et al. Mechanisms behind green photoluminescence in ZnO phosphor powders [J]. J. Appl. Phys., 1996, 79(10):7983-7989.

Lin B, Fu Z, Jia Y. Green luminescent center in undoped zinc oxide films deposited on silicon substrates [J]. Appl. Phys. Lett., 2001, 79(7):943-945.

Zhuang H Z, Li J L, Wang J, et al. Novel zinc oxide hexagonal prisms induced by polar surfaces [J]. Materials Characterization, 2011, 62(6):93-598.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

高质量ZnO及BeZnO薄膜的发光性质

Cu掺杂ZnO纳米材料的制备及表征

Mg掺杂ZnO纳米晶的低温共沉淀法制备及光学性质

ZnO六方纳米管晶体的制备与光致发光性能

ZnO薄膜表面和边缘的发光特性