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辽宁工业大学 化学与环境工程学院, 辽宁 锦州 121001
纸质出版日期:2012-7-10,
网络出版日期:2012-7-10,
收稿日期:2012-4-12,
修回日期:2012-4-26,
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吴红梅, 郭宇. 新型锌离子荧光探针(5-(二甲基氨基)-<em>N</em>-(4-(2-(2-喹啉亚甲基)甲酰肼基)苯基)萘-1-磺酰胺)的研究[J]. 发光学报, 2012,33(7): 790-795
WU Hong-mei, GUO Yu. Synthesis of(E)-5-(dimethylamino)-<em>N</em>-(4-(2-(quinolin-2-ylmethylene)- hydrazinecarbonyl)phenyl) naphthalene-1-sulfonamide for Detection of Zinc Ion[J]. Chinese Journal of Luminescence, 2012,33(7): 790-795
吴红梅, 郭宇. 新型锌离子荧光探针(5-(二甲基氨基)-<em>N</em>-(4-(2-(2-喹啉亚甲基)甲酰肼基)苯基)萘-1-磺酰胺)的研究[J]. 发光学报, 2012,33(7): 790-795 DOI: 10.3788/fgxb20123307.0790.
WU Hong-mei, GUO Yu. Synthesis of(E)-5-(dimethylamino)-<em>N</em>-(4-(2-(quinolin-2-ylmethylene)- hydrazinecarbonyl)phenyl) naphthalene-1-sulfonamide for Detection of Zinc Ion[J]. Chinese Journal of Luminescence, 2012,33(7): 790-795 DOI: 10.3788/fgxb20123307.0790.
以丹磺酰胺为荧光基团设计合成了新型Zn
2+
荧光探针DW1(5-(二甲基氨基)-
N
-(4-(2-(2-喹啉亚甲基)甲酰肼基)苯基)萘-1-磺酰胺)。通过紫外光谱、荧光光谱及电喷雾质谱研究了DW1对Zn
2+
的选择性识别作用。结果表明
DW1与Zn
2+
结合后荧光显著增强
荧光发射光谱由545 nm蓝移至515 nm
量子产率达到0.32
且对Zn
2+
具有较高的选择性
受常见离子的干扰较小。光谱滴定和ESI-MS谱表明DW1与Zn
2+
以1∶1的化学计量数形成配合物
平衡常数
K
=1.75×10
4
(mol/L)
-1
。
A novel dansyl sulfonamide-based fluorescence probe
(E)-5-(dimethylamino)-
N
-(4-(2-(quinolin-2-ylmethylene)hydrazinecarbonyl)phenyl)naphthalene-1-sulfonamide (DW1) was synthesized for detection of Zn
2+
. UV-Vis
fluorescence and ESI-MS spectra of DW1 were measured to investigate the selective recognition. The results show that the fluorescence intensity increase significantly with high quantum yield (
Φ
f
=0.32) and blue-shift emission from 545 nm to 515 nm after the coordination of DW1 with Zn
2+
manifesting DW1 could detect Zn
2+
sensitively. Moreover
the selective and competitive fluorescent experiments show that DW1 is highly selective for recognition of Zn
2+
over other common metal ions. Spectrophotometric titration and ESI-MS spectrum indicate the formation of a 1∶1 DW1-Zn
2+
complex and the association constant
K
was calculated as 1.75×10
4
(mol/L)
-1
.
荧光探针锌离子丹磺酰胺蓝移
fluorescence probezinc iondansyl sulfonamideblue shift
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