阳离子对Er3+掺杂硼酸盐玻璃结构和发光特性的影响

周永亮; 张晓松; 冯志军; 凌志; 李岚

doi:10.3788/fgxb20123306.0606

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阳离子对Er³⁺掺杂硼酸盐玻璃结构和发光特性的影响

材料合成及性能研究 | 更新时间：2020-08-12

- 阳离子对Er³⁺掺杂硼酸盐玻璃结构和发光特性的影响
- Influence on The Structure and Luminescence Properties of Er³⁺-doped Borate Glass for Cation
- 发光学报 2012年33卷第6期页码：606-610
- 作者机构：
  
  天津理工大学材料物理研究所天津,300384
- 作者简介：
- 基金信息：
  
  "973"项目、国家自然科学基金(60877029,60977035)资助项目()
- DOI：10.3788/fgxb20123306.0606
  中图分类号： TN304.81
- 纸质出版日期：2012-6-10，
  
  网络出版日期：2012-6-10，
  
  收稿日期：2012-2-29，
  
  修回日期：2012-4-4，
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周永亮, 张晓松, 冯志军, 凌志, 李岚. 阳离子对Er3+掺杂硼酸盐玻璃结构和发光特性的影响[J]. 发光学报, 2012,(6): 606-610

ZHOU Yong-liang, ZHANG Xiao-song, FENG Zhi-jun, LING Zhi, LI Lan. Influence on The Structure and Luminescence Properties of Er3+-doped Borate Glass for Cation[J]. Chinese Journal of Luminescence, 2012,(6): 606-610
周永亮, 张晓松, 冯志军, 凌志, 李岚. 阳离子对Er3+掺杂硼酸盐玻璃结构和发光特性的影响[J]. 发光学报, 2012,(6): 606-610 DOI： 10.3788/fgxb20123306.0606.

ZHOU Yong-liang, ZHANG Xiao-song, FENG Zhi-jun, LING Zhi, LI Lan. Influence on The Structure and Luminescence Properties of Er3+-doped Borate Glass for Cation[J]. Chinese Journal of Luminescence, 2012,(6): 606-610 DOI： 10.3788/fgxb20123306.0606.

摘要

针对Si/Al掺杂量增大使BaO-(1-x)SiO

-xAl

-B

-0.005Er

(x=0

0.5

摩尔分数)玻璃样品的1 540 nm红外发光和540 nm上转换发光强度呈现相反的变化趋势

讨论了阳离子掺杂对稀土离子周边对称性和电负性变化与荧光行为的内在关系。红外傅里叶透射光谱显示

不同掺杂浓度下样品的最大声子能量没有明显变化

说明光谱随掺杂浓度的变化与玻璃体系的最大声子能量无关。根据Judd-Ofelt理论计算了

13/2

和

3/2

能级的光学参数

通过比较两能级的跃迁几率(A)、寿命(

)、荧光分支比(β)和受激发射截面(σ)等光学参数

发现

13/2

能级和

3/2

能级的相关参数呈现相反的趋势。最后测试了样品

13/2

能级下1 540 nm的寿命

进一步从电负性角度考虑了样品的发光效率。理论计算和实验结果相符。

Abstract

With the Si/Al doping quantity increasing

the intensity of the BaO-(1-x)SiO

-xAl

-B

-0.005Er

(x=0

0.5

mole fraction) glass samples show the opposite trend at 1 540 nm infrared emitting and 540 nm up-conversion luminescence. We discuss the internal relation between the rare earth ion’s peripheral micro structure and fluorescence behavior. The process of electron transition for up-conversion and infrared emitting are illustrated by the energy diagram.Infrared FTIR transmission spectra show that the maximum phonon energy does not significantly change with the doping concentration. This indicates that the change of spectrum in different concentration is not derived from the influence of the maximum phonon energy. The calculation by Judd-Ofelt theroy shows that the local symmetry around rare earth ions varies with doping quantity of Al

/Si

. Radiative decay rates(A)

the radiative lifetime(τ)

fluorescence branching ratios(β)

and stimulated emission cross section(σ) for 540 nm and 1.54 μm are calculated. The results show that the changes are opposite. Finally

the fluorescence decaying curves of

13/2

15/2

for Er

in the borate glass samples are characterized

which is consistent with the experimental results.

关键词

硼酸盐玻璃红外发光上转换发光Judd-Ofelt理论

Keywords

borate glassinfrared luminescenceup-conversion luminescenceJudd-Ofelt theory

references

Banyasz I, Berneschi S, Khanh N Q, et al. Structural and functional characterisation of slab waveguides written in Er3+-doped tellurite glass,CaF2,Bi4(GeO4)3 and Bi12GeO20 crystals via implantation of MeV N+ ions [J]. Mater. Sci. Eng., 2011, 15(1):1757-1762.

Wang Yang, Zhang Jisen, Lv Shaozhe, et al. Durability and near-infrared photolum inescence of Er3+-doped (ZnO)1- x-y(P2O5)x(B2O3)em>y glass systems [J]. Chin. J. Lumin.(发光学报), 2010, 31(6):796-799 (in English).

John A C, Fiorenzo V, Boyer J C. Enhancement of red emission (4F9/2→4I15/2) via upconversion in bulk and nanocrystalline cubic Y2O3:Er3+ [J]. J. Phys. Chem. B, 2002, 106(6):1181-1187.

Castillo J D, Yanes A C, Ramos J M, et al. Sol-gel preparation and white up-conversion luminescence in rare-earth doped PbF2 nanocrystals dissolved in silica glass [J]. J. Sol-Gel Sci. Technol., 2010, 53(3):509-514.

Radzhabov E, Istomin A, Nepomnyashikh A, et al. Exciton interaction with impurity in barium fluoride crystals [J]. Nucl. Instrum. Methods Phys. Res. Sect. A, 2005, 537(1):71-75.

Zhu X W, Masubuchi Y, Motohashi T, et al. The z value dependence of photoluminescence in Eu2+ doped-SiAlON(Si6-zAlem>zOem>zN8-z) with 1≤z≤4 [J]. J. Alloys Compd., 2010, 489(1):157-161.

Riedener T, Karl K, Hans U G. Upconversion luminescence in Er3+-doped RbGd2Cl7 and RbGd2Br7 [J]. Inorg.Chem., 1995, 34(10):2745-2752.

Yang Z M, Xu S Q, Dai S X, et al. Thermal stability and optical transition of Er3+ in sodium-lead-germanate glasses [J]. J. Mater. Sci., 2004, 39(11):3641-3646.

Pan Z D, Steven H M. Raman spectra and thermal analysis of a new lead-tellurium-germanate glass system [J]. J. Non-Cryst. Solids., 1997, 210(1):130-135.

Gerhards M, Schiwek M, Unterberg C, et al. OH stretching vibrations in aromatic cations:IR/PIRI spectroscopy [J]. Chem. Phys. Lett., 1998, 297(5-6):515-522.

Yu Xiaobo, Zhao Xin, Li Changmin, et al. Infrared spectrum estimation for maximum phonon energy in optical glasses [J]. J. Dalian. Poly. Univ.( 大连工业大学学报), 2008, 27(2):155-157 (in Chinese).

Ghosh A, Debnath R. Judd-Ofelt analysis of Er+3 activated lead free fluoro-tellurite glass [J]. Opt. Mater., 2009, 31(4):604-608.

Yun Y H, Bray P J. Optical absorption in an equimolar barium borosilicate glass containing titanium ions [J]. J. Non-Cryst. Solids, 1978, 28(3):337-345.

Pradeesh K, OtonC J, Agotiya V K, et al. Optical properties of Er3+ doped alkali chlorophosphate glasses for optical amplifiers [J]. Opt. Mater., 2008, 31(2):155-160.

Nandi P, Jose G, Jayakrishnan C, et al. Femtosecond laser written channel waveguides in tellurite glass [J]. Opt. Express, 2006, 14(25):12145-12150.

Wetenkamp L, West G F, Tobben H. Co-doping effects in erbium3+ and holmium3+ doped ZBLAN glasses [J]. J. Non-Cryst. Solids, 1992, 140(1):25-30.

Ebendor H, Ehrta D, Bettinelli M, et al. Effect of glass composition on Judd-Ofelt parameters and radiative decay rates of Er3+ in fluoride phosphate and phosphate glasses [J]. J. Non-Cryst. Solids, 1998, 240(1-3):66-78.

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