用于中红外光纤激光器的高Pr<sup>3+</sup>掺杂硒化物硫系玻璃和光纤制备及其光谱特性

许晨煜; 崔健; 许彦涛; 肖旭升; 崔晓霞; 郭海涛

doi:10.37188/CJL.20220088

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用于中红外光纤激光器的高Pr³⁺掺杂硒化物硫系玻璃和光纤制备及其光谱特性

材料合成及性能 | 更新时间：2022-10-19

- 用于中红外光纤激光器的高Pr³⁺掺杂硒化物硫系玻璃和光纤制备及其光谱特性
  增强出版
- Fabrication and Spectroscopic Properties of Heavily Pr³⁺ Doped Selenide Chalcogenide Glass and Fiber for Mid-infrared Fiber Laser
- 发光学报 2022年43卷第6期页码：851-861
- 作者机构：
  
  1.中国科学院西安光学精密机械研究所瞬态光学与光子技术国家重点实验室，陕西西安　710119
  2.中国科学院大学，北京　100049
- 作者简介：
  
  [ "许晨煜（1998-），男，陕西咸阳人，硕士研究生，2019年于四川大学获得学士学位，主要从事稀土掺杂硫系玻璃光纤材料的研究。" ]
- 基金信息：
  
  National Natural Science Foundation of China(62005312;62090065;61935006);Chinese Academy of Sciences Interdisciplinary Innovation Team Project(JCTD‑2018‑19)
- DOI：10.37188/CJL.20220088
  中图分类号： O482.31
- 纸质出版日期：2022-06-05，
  
  收稿日期：2022-03-15，
  
  修回日期：2022-03-27，
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许晨煜,崔健,许彦涛等.用于中红外光纤激光器的高Pr³⁺掺杂硒化物硫系玻璃和光纤制备及其光谱特性[J].发光学报,2022,43(06):851-8611.

XU Chen-yu,CUI Jian,XU Yan-tao,et al.Fabrication and Spectroscopic Properties of Heavily Pr³⁺ Doped Selenide Chalcogenide Glass and Fiber for Mid-infrared Fiber Laser[J].Chinese Journal of Luminescence,2022,43(06):851-861.
许晨煜,崔健,许彦涛等.用于中红外光纤激光器的高Pr³⁺掺杂硒化物硫系玻璃和光纤制备及其光谱特性[J].发光学报,2022,43(06):851-8611. DOI： 10.37188/CJL.20220088.

XU Chen-yu,CUI Jian,XU Yan-tao,et al.Fabrication and Spectroscopic Properties of Heavily Pr³⁺ Doped Selenide Chalcogenide Glass and Fiber for Mid-infrared Fiber Laser[J].Chinese Journal of Luminescence,2022,43(06):851-861. DOI： 10.37188/CJL.20220088.

摘要

为了研发用于3~5 μm波段光纤激光器的增益介质，制备了重量百分比为0～0.4%不同浓度Pr

离子掺杂的Ge

20.8

63.2

硒化物硫系玻璃。通过多级棒管法，重量百分比为0.2%的Pr

离子掺杂玻璃被成功拉制成阶跃型双包层光纤，损耗最低为2.95 dB/m（位于6.58 μm处）。采用电子探针显微分析（EPMA）、X射线衍射（XRD）、差示扫描量热（DSC）、场发射透射电子显微镜（FE⁃TEM）、透射光谱和中红外荧光光谱分析了玻璃中Pr

离子的分散性、杂质含量以及Pr

离子引入引起的热、光学性质变化。通过玻璃的吸收和发射光谱并结合Judd-Ofelt理论，计算了Judd-Ofelt强度参数、辐射跃迁几率、荧光寿命、荧光分支比和受激发射截面。这种硒化硫系玻璃具有较高的Pr

离子溶解度和中红外发光特性、良好的热稳定性和成纤性能，表明其具有作为中红外激光工作介质的潜力。

Abstract

In order to develop a high gain medium for fiber lasers operating at 3-5 μm waveband， 0-0.4%（in weight） Pr

ions doped Ge

20.8

63.2

selenide chalcogenide glasses were prepared and the 0.2%（in weight） Pr

ions doped one was successfully drawn into step-index double-cladding fiber with the lowest loss of 2.95 dB/m@6.58 μm by a multistage rod-in-tube method. The electron-probe measure microanalysis（EPMA）， X-ray diffraction（XRD）， differential scanning calorimeter（DSC）， field emission transmission electron microscope（FE-TEM）， transmission and mid-infrared fluorescence spectra were carried out to analyze the dispersion of Pr

ions in glass， the impurity contents，thermal and optical changes caused by the Pr

ions’ introduction. By analyzing the absorption and emission measurements of the serial glasses with the Judd-Ofelt theory， the Judd-Ofelt strength parameters， transition probabilities， exited state lifetime， branching ratios， and emission cross-sections were also calculated. This selenide chalcogenide glass has high Pr

ions’ solubility and emission characteristic， good thermal stability and fiber forming performance， indicating that it has potential to be used as mid-infrared laser working medium.

关键词

硫系玻璃稀土离子光谱学中红外荧光红外光纤

Keywords

chalcogenide glassrare-earth ionsspectroscopymid-infrared fluorescenceinfrared fiber

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用于中红外光纤激光器的高Pr3+掺杂硒化物硫系玻璃和光纤制备及其光谱特性

Fabrication and Spectroscopic Properties of Heavily Pr3+ Doped Selenide Chalcogenide Glass and Fiber for Mid-infrared Fiber Laser

DOI：10.37188/CJL.20220088

摘要

Abstract

关键词

Keywords

references

用于中红外光纤激光器的高Pr³⁺掺杂硒化物硫系玻璃和光纤制备及其光谱特性

Fabrication and Spectroscopic Properties of Heavily Pr³⁺ Doped Selenide Chalcogenide Glass and Fiber for Mid-infrared Fiber Laser