部分阳离子取代优化铜锌锡硫硒薄膜太阳能电池性能研究进展

米亚金; 杨艳春; 王晓宁; 朱成军

doi:10.37188/CJL.20210340

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部分阳离子取代优化铜锌锡硫硒薄膜太阳能电池性能研究进展

器件制备及器件物理 | 更新时间：2022-02-25

- 部分阳离子取代优化铜锌锡硫硒薄膜太阳能电池性能研究进展
  增强出版
- Research Progress on Optimizing Performance of Cu₂ZnSn(S,Se)₄Thin-film Solar Cells by Partial Cation Substitutions
- 发光学报 2022年43卷第2期页码：255-267
- 作者机构：
  
  1.内蒙古师范大学物理与电子信息学院　内蒙古自治区功能材料物理与化学重点实验室，内蒙古　呼和浩特　010020
  2.内蒙古自治区稀土功能和新能源储能材料工程研究中心，内蒙古　呼和浩特　010020
  3.内蒙古大学　物理科学与技术学院，内蒙古　呼和浩特　010021
- 作者简介：
  
  [ "米亚金(1998-)，男，内蒙古二连浩特人，硕士研究生，2020年于内蒙古师范大学获得学士学位，主要从事阳离子掺杂优化铜锌锡硫硒薄膜太阳能电池性能的研究。E-mail: 1787938204@qq.com" ]
  [ "杨艳春(1989-)，女，山西应县人，博士，副教授、硕士生导师，2017年于中国科学院长春应用化学研究所获得博士学位，主要从事溶液法制备铜基薄膜太阳能电池及其性能优化的研究。E-mail: 20170020@imnu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(61804085;62164010;62064010);内蒙古自治区自然科学基金(2020LH6008);中央引导地方科技发展资金(2020ZY0009);中国博士后科学基金(2019M653806XB);内蒙古师范大学校级研究生科研创新基金(CXJJS21130);内蒙古师范大学校级大学生创新创业训练计划(XCY-2140)
- DOI：10.37188/CJL.20210340
  中图分类号： TM914.4⁺2
- 纸质出版日期：2022-02，
  
  收稿日期：2021-11-03，
  
  修回日期：2021-11-22，
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米亚金, 杨艳春, 王晓宁, 等. 部分阳离子取代优化铜锌锡硫硒薄膜太阳能电池性能研究进展[J]. 发光学报, 2022,43(2):255-267.

Ya-jin MI, Yan-chun YANG, Xiao-ning WANG, et al. Research Progress on Optimizing Performance of Cu₂ZnSn(S,Se)₄Thin-film Solar Cells by Partial Cation Substitutions[J]. Chinese Journal of Luminescence, 2022,43(2):255-267.
米亚金, 杨艳春, 王晓宁, 等. 部分阳离子取代优化铜锌锡硫硒薄膜太阳能电池性能研究进展[J]. 发光学报, 2022,43(2):255-267. DOI： 10.37188/CJL.20210340.

Ya-jin MI, Yan-chun YANG, Xiao-ning WANG, et al. Research Progress on Optimizing Performance of Cu₂ZnSn(S,Se)₄Thin-film Solar Cells by Partial Cation Substitutions[J]. Chinese Journal of Luminescence, 2022,43(2):255-267. DOI： 10.37188/CJL.20210340.

摘要

作为无机化合物薄膜太阳能电池中具有代表性的一类电池，铜锌锡硫硒(Cu

ZnSn(S

Se)

，简称CZTSSe)薄膜太阳能电池因其组成元素地壳含量丰富、低毒等优点受到广泛关注。目前，吸收层的高缺陷密度和器件的低开路电压被认为是限制该类电池效率的两个关键因素。为了突破这两大困境，科研人员发展了阳离子取代方法，即通过引入其他阳离子取代CZTSSe晶格中的铜离子(Cu

)/锌离子(Zn

)/锡离子(Sn

)，改善薄膜中的有害缺陷、晶体结构、能带结构等性质，从而优化电池器件的性能。为了详细阐述阳离子取代措施在铜锌锡硫硒薄膜电池中的研究进展，本文从等价阳离子取代和不等价阳离子取代两方面进行分类介绍，并总结了各种阳离子取代措施在优化电池性能方面的优缺点。

Abstract

As a representative of inorganic thin film solar cells

ZnSn(S

Se)

(CZTSSe) thin film solar cells have attracted much extensive attention

since the constituent elements are rich in earth

low toxic

etc

. At present

high defect density of the absorber layer and low open circuit voltage of device are both considered as two key factors limiting the efficiency of device. In order to break though the two difficulties

the researchers developed the substitutions of Cu

/Zn

/Sn

by another cation. This can optimize the film properties of the harmful defects

crystal structure

and band structure

improving the performance of devices. Here

we classify by equivalent and inequivalent cation substitutions to elaborate current research development of CZTSSe thin film solar cells by cation substitution

and summarize their advantage and disadvantage in optimizing performance of devices.

关键词

薄膜太阳能电池铜锌锡硫硒阳离子取代

Keywords

thin film solar cellCu2ZnSn(SSe)4cation substitutions

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