Tm3+/Yb3+共掺LuYO3上转换荧光温度传感特性

张志宏; 周慧丽; 吴锋; 张雁; 叶林华

doi:10.37188/CJL.20210276

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Tm³⁺/Yb³⁺共掺LuYO₃上转换荧光温度传感特性

材料合成及性能 | 更新时间：2021-12-17

- Tm³⁺/Yb³⁺共掺LuYO₃上转换荧光温度传感特性
  增强出版
- Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor
- 发光学报 2021年42卷第12期页码：1872-1881
- 作者机构：
  
  1.中国航发四川燃气涡轮研究院，四川　成都　610500
  2.浙江大学　物理系，浙江　杭州　310027
- 作者简介：
  
  张志宏(1976-)，女，辽宁沈阳人，硕士，高级工程师，2017年于西北工业大学获得硕士学位，主要从事航空发动机试验温度、压力等参数测试技术的研究。E-mail: jyz_18@163.com
  周慧丽(1996-)，女，浙江金华人，博士研究生，2017年于浙江外国语学院获得学士学位，主要从事稀土离子掺杂荧光材料温度传感特性的研究。E-mail: 21836046@zju.edu.cn
  张雁(1994-)，女，四川绵阳人，硕士，助理工程师，2020年于南京航空航天大学获得硕士学位，主要从事航空发动机整机试验技术的研究。E-mail: 1015329361@qq.com
  叶林华(1965-)，男，浙江宁海人，博士，副教授，2006年于浙江大学获得博士学位，主要从事高温氧化物单晶光纤材料制备及其应用的研究。E-mail: lhye@zju.edu.cn
- 基金信息：
  
  国家自然科学基金(11674284);先进航空动力创新工作站（依托中国航空发动机研究院设立）(HKCX2019-01-017)
- DOI：10.37188/CJL.20210276
  中图分类号： O433.1
- 收稿：2021-08-20，
  
  修回：2021-09-07，
  
  纸质出版：2021-12
- 稿件说明：
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张志宏, 周慧丽, 吴锋, 等. Tm³⁺/Yb³⁺共掺LuYO₃上转换荧光温度传感特性[J]. 发光学报, 2021,42(12):1872-1881. DOI: 10.37188/CJL.20210276.

Zhi-hong ZHANG, Hui-li ZHOU, Feng WU, et al. Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor[J]. Chinese Journal of Luminescence, 2021, 42(12): 1872-1881. DOI: 10.37188/CJL.20210276.
张志宏, 周慧丽, 吴锋, 等. Tm³⁺/Yb³⁺共掺LuYO₃上转换荧光温度传感特性[J]. 发光学报, 2021,42(12):1872-1881. DOI: 10.37188/CJL.20210276. DOI：

Zhi-hong ZHANG, Hui-li ZHOU, Feng WU, et al. Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor[J]. Chinese Journal of Luminescence, 2021, 42(12): 1872-1881. DOI: 10.37188/CJL.20210276. DOI：

摘要

采用CO

激光区熔法制备了LuYO

∶Tm

(0.3%)-Yb

(5%)荧光材料。在980 nm激光激发下测量了样品在可见光波段的上转换(UC)荧光光谱，其中

→

跃迁产生的蓝色上转换荧光发生明显的Stark劈裂。利用荧光强度比(FIR)方法对样品的Stark劈裂能级

4(a)

与

4(b)

和

与

两对热耦合能级的荧光温度传感特性进行研究。结果表明，两

对热耦合能级的测温范围为223~723 K。

4(a)

与

4(b)

能级在低温下灵敏度较高，在223 K处有最大绝对灵敏度5.62×10

-3

-1

和最大相对灵敏度28.2×10

-3

-1

;

与

能级比较适合高温下的温度传感，最大绝对灵敏度为1.44×10

-3

-1

(723 K)，最大相对灵敏度为4.61×10

-3

-1

(516.3 K)，表明所制备荧光材料非常适合用于荧光温度传感。

Abstract

LuYO

∶Tm

(0.3%)-Yb

(5%) phosphor was prepared by CO

laser zone melting method. Under the excitation of 980 nm laser

the sample exhibits up-conversion luminescence(UCL) corresponding to

→

transition in the visible light region

among which obvious Stark splits of luminescence are observed in the blue UCL corresponding to

→

transition. The temperature sensing characteristics of

4(a)

4(b)

and

thermally coupled levels(TCLs) are investigated by fluorescence intensity ratio(FIR) method. The results show that the temperature measurement range of the two pairs of TCLs is 223~723 K. The Stark sub-levels

4(a)

and

4(b)

have higher sensitivity at low temperatures with maximum absolute sensitivity 5.62×10

-3

-1

and maximum relative sensitivity 28.2×10

-3

-1

at 223 K

the

and

TCLs are more suitable for high temperature measurement with maximum absolute sensitivity 1.44×10

-3

-1

(723 K) and maximum relative sensitivity 4.61×10

-3

-1

(516.3 K)

indicating that the prepared fluorescent material

is very suitable for fluorescent temperature sensing.

关键词

Keywords

references

金叶 , 李坤 , 罗旭 , 等 . Sc2(WO4)3∶Er3+/Yb3+的上转换发光及其温度传感特性 [J ] . 发光学报 , 2021 , 42 ( 1 ): 91 - 97 .

JIN Y , LI K , LUO X , et al . Upconversion luminescence and temperature sensing properties for Sc2(WO4)3∶Er3+/Yb3+ [J ] . Chin. J. Lumin. , 2021 , 42 ( 1 ): 91 - 97 . (in Chinese)

张焕君 , 董兴邦 , 李海宁 , 等 . 六方相LaOF∶Er,Yb的上转换发光及温度传感特性 [J ] . 发光学报 , 2020 , 41 ( 5 ): 536 - 541 .

ZHANG H J , DONG X B , LI H N , et al . Upconversion emission and temperature sensing of R-LaOF∶Er,Yb [J ] . Chin. J. Lumin. , 2020 , 41 ( 5 ): 536 - 541 . (in Chinese)

陈静 , 王友法 . 溶剂热法制备NaBiF4∶Yb3+/Er3+及掺杂Rb+离子增强其上转换荧光 [J ] . 硅酸盐学报 , 2020 , 48 ( 1 ): 35 - 43 .

CHEN J , WANG Y F . Preparation of NaBiF4∶Yb3+/Er3+ particles via solvothermal method and enhancement of upconversion luminescence by Rb+ ion doping [J ] . J. Chin. Ceram. Soc. , 2020 , 48 ( 1 ): 35 - 43 . (in Chinese)

赵玉慈 , 赵雄燕 , 王鑫 . 稀土上转换纳米发光材料的研究进展 [J ] . 现代化工 , 2016 , 36 ( 7 ): 21 - 24 .

ZHAO Y C , ZHAO X Y , WANG X . Research progress of rare-earth up-conversion luminescent material [J ] . Modern Chem. Ind. , 2016 , 36 ( 7 ): 21 - 24 . (in Chinese)

WADE S A , COLLINS S F , BAXTER G W . Fluorescence intensity ratio technique for optical fiber point temperature sensing [J ] . J. Appl. Phys. , 2003 , 94 ( 8 ): 4743 - 4756 .

WANG X F , LIU Q , BU Y Y , et al . Optical temperature sensing of rare-earth ion doped phosphors [J ] . RSC Adv. , 2015 , 5 ( 105 ): 86219 - 86236 .

XING L L , XU Y L , WANG R , et al . Highly sensitive optical thermometry based on upconversion emissions in Tm3+/Yb3+ codoped LiNbO3 single crystal [J ] . Opt. Lett. , 2014 , 39 ( 3 ): 454 - 457 .

ZHOU H L , AN N , ZHU K S , et al . Optical temperature sensing properties of Tm3+/Yb3+ co-doped LuAG polycrystalline phosphor based on up-conversion luminescence [J ] . J. Lumin. , 2021 , 229 : 117656 .

YU L , YE L H , BAO R J , et al . Sensitivity-enhanced Tm3+/Yb3+ co-doped YAG single crystal optical fiber thermometry based on upconversion emissions [J ] . Opt. Commun. , 2018 , 410 : 632 - 636 .

郑龙江 , 高晓阳 , 徐伟 , 等 . Tm3+,Yb3+共掺微晶玻璃蓝色上转换荧光的温度特性 [J ] . 发光学报 , 2012 , 33 ( 9 ): 944 - 948 .

ZHENG L J , GAO X Y , XU W , et al . Temperature characteristic of blue up-conversion emission in Tm3+,Yb3+ codoped oxyfluoride glass ceramic [J ] . Chin. J. Lumin. , 2012 , 33 ( 9 ): 944 - 948 . (in Chinese)

吴中立 , 吴红梅 , 唐立丹 , 等 . Tm3+/Yb3+共掺氟氧化物碲酸盐玻璃的上转换发光及光学温度传感 [J ] . 光子学报 , 2017 , 46 ( 9 ): 0916003-1-7 .

WU Z L , WU H M , TANG L D , et al . Up-conversion light-emitting and optical temperature sensing for Tm3+/Yb3+ codoped oxyfluoride tellurite glass [J ] . Acta Photon. Sinica , 2017 , 46 ( 9 ): 0916003-1-7 . (in Chinese)

宗玲博 . 钇氧化物基质材料的微结构调控及其对发光性能的增强效应研究 [D ] . 北京 : 北京科技大学 , 2017 .

ZONG L B . Microstructure Control of Yttrium-based Oxides Host Materials and Their Enhanced Effect on Luminescence Properties [D ] . Beijing : University of Science and Technology Beijing , 2017 . (in Chinese)

PETERMANN K , HUBER G , FORNASIERO L , et al . Rare-earth-doped sesquioxides [J ] . J. Lumin. , 2000 , 87-89 : 973 - 975 .

CHEN G Z , LI S M , ZHANG L H , et al . Growth and spectra of Tm3+ doped LuYO3 single crystal for 2 μm lasers [J ] . Infrared Phys. Technol. , 2020 , 109 : 103431 .

ZHOU Z Y , GUAN X F , HUANG X X , et al . Tm3+-doped LuYO3 mixed sesquioxide ceramic laser: effective 2.05 μm source operating in continuous-wave and passive Q-switching regimes [J ] . Opt. Lett. , 2017 , 42 ( 19 ): 3781 - 3784 .

YE L H , ZHANG J F , SHI Y . Growth and characteristics of Cr3+∶YAG crystal fiber for fluorescence decay temperature sensor [J ] . Rev. Sci. Instrum. , 2006 , 77 ( 5 ): 054901-1-4 .

BAO R J , YU L , YE L H , et al . Compact and sensitive Er3+/Yb3+ co-doped YAG single crystal optical fiber thermometry based on up-conversion luminescence [J ] . Sens. Actuators A Phys. , 2018 , 269 : 182 - 187 .

HOU X R , ZHOU S M , LIN H , et al . Violet and blue upconversion luminescence in Tm3+/Yb3+ codoped Y2O3 transparent ceramic [J ] . J. Appl. Phys. , 2010 , 107 ( 8 ): 083101-1-4 .

LI D Y , WANG Y X , ZHANG X R , et al . Optical temperature sensor through infrared excited blue upconversion emission in Tm3+/Yb3+ codoped Y2O3 [J ] . Opt. Commun. , 2012 , 285 ( 7 ): 1925 - 1928 .

POLLNAU M , GAMELIN D R , LÜTHI S R , et al . Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems [J ] . Phys. Rev. B , 2000 , 61 ( 5 ): 3337 - 3346 .

DONG H , SUN L D , YAN C H . Energy transfer in lanthanide upconversion studies for extended optical applications [J ] . Chem. Soc. Rev. , 2015 , 44 ( 6 ): 1608 - 1634 .

李瑞琴 , 邱建备 , 杨正文 , 等 . Yb3+/Tm3+共掺杂Sb2O4荧光粉的制备及上转换发光性质研究 [J ] . 光谱学与光谱分析 , 2014 , 34 ( 3 ): 630 - 633 .

LI R Q , QIU J B , YANG Z W , et al . Preparation and up-conversion luminescence properties of Yb3+/Tm3+ co-doped Sb2O4 powder [J ] . Spectrosc. Spect. Anal. , 2014 , 34 ( 3 ): 630 - 633 . (in Chinese)

ZHANG Z H , LOUCHET-CHAUVET A , MORVAN L , et al . Tailoring the 3F4 level lifetime in Tm3+∶Y3Al5O12 by Eu3+ co-doping for signal processing application [J ] . J. Lumin. , 2020 , 222 : 117107 .

李路 , 娄朝刚 , 谢宇飞 . Ce3+-Yb3+共掺YAG荧光粉量子剪裁发光的浓度及温度特性 [J ] . 发光学报 , 2016 , 37 ( 12 ): 1445 - 1450 .

LI L , LOU C G , XIE Y F . Concentration and temperature characteristics of quantum cutting luminescence in Ce3+-Yb3+ co-doped YAG phosphor [J ] . Chin. J. Lumin. , 2016 , 37 ( 12 ): 1445 - 1450 . (in Chinese)

林燕金 , 黄衍堂 , 吴锦树 , 等 . 稀土荧光特性与温度关系 [J ] . 光子学报 , 2016 , 45 ( 1 ): 0116002-1-6 .

LIN Y J , HUANG Y T , WU J S , et al . Relationship between rare earth fluorescence characteristic and temperature [J ] . Acta Photon. Sinica , 2016 , 45 ( 1 ): 0116002-1-6 . (in Chinese)

芦泓宇 . 基于稀土掺杂上转换材料荧光峰值比的温度传感 [D ] . 哈尔滨 : 哈尔滨工业大学 , 2017 .

LU H Y . Temperature Sensing of Rare Earth Doped Upconversion Materials based on Fluorescence Intensity Ratio Technique [D ] . Harbin : Harbin Institute of Technology , 2017 . (in Chinese)

赵旺 , 平兆艳 , 郑庆华 , 等 . 白光发光二极管用SrGdLiTeO6∶Eu3+红色荧光粉的浓度猝灭和温度猝灭行为 [J ] . 物理学报 , 2018 , 67 ( 24 ): 247801-1-10 .

ZHAO W , PING Z Y , ZHENG Q H , et al . Concentration and thermal quenching of SrGdLiTeO6∶Eu3+ red-emitting phosphor for white light-emitting diode [J ] . Acta Phys. Sinica , 2018 , 67 ( 24 ): 247801-1-10 . (in Chinese)

MIN Q H , BIAN W J , QI Y S , et al . Temperature sensing based on the up-conversion emission of Tm3+ in a single KLuF4 microcrystal [J ] . J. Alloys Compd. , 2017 , 728 : 1037 - 1042 .

TONG L L , LI X P , HUA R N , et al . Optical temperature sensing properties of Yb3+/Tm3+ co-doped NaLuF4 crystals [J ] . Curr. Appl. Phys. , 2017 , 17 ( 7 ): 999 - 1004 .

LIU Z H , LONG S W , ZHU Y Z , et al . Optical thermometry based on thermolabile intrinsic polarons in Tm3+ and Yb3+ co-doped congruent lithium niobate single crystal [J ] . J. Alloys Compd. , 2021 , 867 : 158986 .

GE W Y , XU M M , SHI J D , et al . Highly temperature-sensitive and blue upconversion luminescence properties of Bi2Ti2O7∶Tm3+/Yb3+ nanofibers by electrospinning [J ] . Chem. Eng. J. , 2020 , 391 : 123546 .

ZHANG N , ZHOU H L , YIN Y R , et al . Exploring promising up-conversion luminescence single crystal fiber in sesquioxide family for high temperature optical thermometry application [J ] . J. Alloys Compd. , 2021 , 889 : 161348 .

SUO H , GUO C F , YANG Z , et al . Thermometric and optical heating bi-functional properties of upconversion phosphor Ba5Gd8Zn4O21∶Yb3+/Tm3+ [J ] . J. Mater. Chem. C , 2015 , 3 ( 28 ): 7379 - 7385 .

SUO H , HU F F , ZHAO X Q , et al . All-in-one thermometer-heater up-converting platform YF3∶Yb3+,Tm3+ operating in the first biological window [J ] . J. Mater. Chem. C , 2017 , 5 ( 6 ): 1501 - 1507 .

ZHOU S S , JIANG G C , LI X Y , et al . Strategy for thermometry via Tm3+-doped NaYF4 core-shell nanoparticles [J ] . Opt. Lett. , 2014 , 39 ( 23 ): 6687 - 6690 .

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