Tm3+/Yb3+共掺LuYO3上转换荧光温度传感特性

张志宏; 周慧丽; 吴锋; 张雁; 叶林华

doi:10.37188/CJL.20210276

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Tm³⁺/Yb³⁺共掺LuYO₃上转换荧光温度传感特性

材料合成及性能 | 更新时间：2021-12-17

- Tm³⁺/Yb³⁺共掺LuYO₃上转换荧光温度传感特性
  增强出版
- Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor
- 发光学报 2021年42卷第12期页码：1872-1881
- 作者机构：
  
  1.中国航发四川燃气涡轮研究院，四川　成都　610500
  2.浙江大学　物理系，浙江　杭州　310027
- 作者简介：
  
  [ "张志宏(1976-)，女，辽宁沈阳人，硕士，高级工程师，2017年于西北工业大学获得硕士学位，主要从事航空发动机试验温度、压力等参数测试技术的研究。E-mail: jyz_18@163.com" ]
  [ "周慧丽(1996-)，女，浙江金华人，博士研究生，2017年于浙江外国语学院获得学士学位，主要从事稀土离子掺杂荧光材料温度传感特性的研究。E-mail: 21836046@zju.edu.cn" ]
  [ "张雁(1994-)，女，四川绵阳人，硕士，助理工程师，2020年于南京航空航天大学获得硕士学位，主要从事航空发动机整机试验技术的研究。E-mail: 1015329361@qq.com" ]
  [ "叶林华(1965-)，男，浙江宁海人，博士，副教授，2006年于浙江大学获得博士学位，主要从事高温氧化物单晶光纤材料制备及其应用的研究。E-mail: lhye@zju.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(11674284);先进航空动力创新工作站（依托中国航空发动机研究院设立）(HKCX2019-01-017)
- DOI：10.37188/CJL.20210276
  中图分类号：
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张志宏, 周慧丽, 吴锋, 等. Tm³⁺/Yb³⁺共掺LuYO₃上转换荧光温度传感特性[J]. 发光学报, 2021,42(12):1872-1881.

Zhi-hong ZHANG, Hui-li ZHOU, Feng WU, et al. Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor[J]. Chinese Journal of Luminescence, 2021,42(12):1872-1881.
张志宏, 周慧丽, 吴锋, 等. Tm³⁺/Yb³⁺共掺LuYO₃上转换荧光温度传感特性[J]. 发光学报, 2021,42(12):1872-1881. DOI： 10.37188/CJL.20210276.

Zhi-hong ZHANG, Hui-li ZHOU, Feng WU, et al. Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor[J]. Chinese Journal of Luminescence, 2021,42(12):1872-1881. DOI： 10.37188/CJL.20210276.

摘要

采用CO,2,激光区熔法制备了LuYO,3,∶Tm,3+,(0.3%)-Yb,3+,(5%)荧光材料。在980 nm激光激发下测量了样品在可见光波段的上转换(UC)荧光光谱，其中,1,G,4,→,3,H,6,跃迁产生的蓝色上转换荧光发生明显的Stark劈裂。利用荧光强度比(FIR)方法对样品的Stark劈裂能级,1,G,4(a),与,1,G,4(b),和,3,F,2,3,与,3,H,4,两对热耦合能级的荧光温度传感特性进行研究。结果表明，两对热耦合能级的测温范围为223~723 K。 ,1,G,4(a),与,1,G,4(b),能级在低温下灵敏度较高，在223 K处有最大绝对灵敏度5.62×10,-3, K,-1,和最大相对灵敏度28.2×10,-3, K,-1,;,3,F,2,3,与,3,H,4,能级比较适合高温下的温度传感，最大绝对灵敏度为1.44×10,-3, K,-1,(723 K)，最大相对灵敏度为4.61×10,-3, K,-1,(516.3 K)，表明所制备荧光材料非常适合用于荧光温度传感。

Abstract

LuYO,3,∶Tm,3+,(0.3%)-Yb,3+,(5%) phosphor was prepared by CO,2, laser zone melting method. Under the excitation of 980 nm laser, the sample exhibits up-conversion luminescence(UCL) corresponding to ,1,G,4,→,3,H,6,1,G,4,→,3,F,4,3,F,2,3,→,3,H,6,3,H,4,→,3,H,6, transition in the visible light region, among which obvious Stark splits of luminescence are observed in the blue UCL corresponding to ,1,G,4,→,3,H,6, transition. The temperature sensing characteristics of ,1,G,4(a),1,G,4(b), and ,3,F,2,3,3,H,4, thermally coupled levels(TCLs) are investigated by fluorescence intensity ratio(FIR) method. The results show that the temperature measurement range of the two pairs of TCLs is 223~723 K. The Stark sub-levels ,1,G,4(a), and ,1,G,4(b), have higher sensitivity at low temperatures with maximum absolute sensitivity 5.62×10,-3, K,-1, and maximum relative sensitivity 28.2×10,-3, K,-1, at 223 K, the ,3,F,2,3, and ,3,H,4, TCLs are more suitable for high temperature measurement with maximum absolute sensitivity 1.44×10,-3, K,-1,(723 K) and maximum relative sensitivity 4.61×10,-3, K,-1,(516.3 K), indicating that the prepared fluorescent material is very suitable for fluorescent temperature sensing.

关键词

Tm3+/Yb3+∶LuYO3上转换发光荧光强度比(FIR)荧光温度传感

Keywords

Tm3+/Yb3+∶LuYO3upconversion luminescencefluorescence intensity ratio(FIR)optical temperature sensing

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