Tm3+/Ho3+共掺含BaF2纳米晶氟硅酸盐玻璃陶瓷2 μm发光性能

傅燕青; 康世亮; 关尚升; 郭跃琪; 陈旦; 刘雪云; 徐铁峰; 林常规

doi:10.37188/CJL.20200310

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Tm³⁺/Ho³⁺共掺含BaF₂纳米晶氟硅酸盐玻璃陶瓷2 μm发光性能

材料合成及性能 | 更新时间：2021-01-12

- Tm³⁺/Ho³⁺共掺含BaF₂纳米晶氟硅酸盐玻璃陶瓷2 μm发光性能
- Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm
- 发光学报 2021年42卷第1期页码：37-43
- 作者机构：
  
  1.宁波大学高等技术研究院红外材料及器件实验室, 浙江宁波 315211
  2.宁波海洋研究院, 浙江宁波 315211
- 作者简介：
  
  [ "傅燕青(1996-), 男, 浙江绍兴人, 硕士研究生, 2019年于宁波大学科学技术学院获得学士学位, 主要从事稀土离子掺杂玻璃发光及能量传递方面的研究。E-mail:fyq574934655@163.com" ]
  [ "康世亮(1990-), 男, 河北张家口人, 博士, 2020年于华南理工大学获得博士学位, 主要从事光功能玻璃和光纤器件的研究。E-mail:ksl0118@126.com" ]
  [ "林常规(1984-), 男, 浙江温州人, 博士, 研究员, 2010年于武汉理工大学获得博士学位, 主要从事特种玻璃材料光功能开发及其器件化(包括玻璃晶化机理、光功能玻璃陶瓷材料、红外玻璃材料、基于硫系玻璃的红外光学系统等)的研究。E-mail:linchanggui@nbu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(61775110);国家自然科学基金(51802299);国家重点研究开发计划(2016YFB0303802);国家重点研究开发计划(2016YFB0303803)
- DOI：10.37188/CJL.20200310
  中图分类号： O482.31
- 纸质出版日期：2021-1，
  
  收稿日期：2020-10-18，
  
  录用日期：2020-11-30
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傅燕青, 康世亮, 关尚升, 等. Tm³⁺/Ho³⁺共掺含BaF₂纳米晶氟硅酸盐玻璃陶瓷2 μm发光性能[J]. 发光学报, 2021,42(1):37-43.

Yan-qing FU, Shi-liang KANG, Shang-sheng GUAN, et al. Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm[J]. Chinese Journal of Luminescence, 2021,42(1):37-43.
傅燕青, 康世亮, 关尚升, 等. Tm³⁺/Ho³⁺共掺含BaF₂纳米晶氟硅酸盐玻璃陶瓷2 μm发光性能[J]. 发光学报, 2021,42(1):37-43. DOI： 10.37188/CJL.20200310.

Yan-qing FU, Shi-liang KANG, Shang-sheng GUAN, et al. Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm[J]. Chinese Journal of Luminescence, 2021,42(1):37-43. DOI： 10.37188/CJL.20200310.

摘要

由于在人眼安全、光电探测、中红外超连续谱产生等方面的应用，2.0 μm波段中红外激光器引起了人们越来越广泛的关注。本文采用熔融-淬冷法制备了含BaF

纳米晶、Tm

离子单掺及Ho

/Tm

共掺的85SiO

-7.5KF-7.5BaF

（SKB）玻璃陶瓷，表征了样品的拉曼光谱、吸收光谱、808 nm泵浦下在2.0 μm处的发光性能，得到了实验过程中Ho

/Tm

的最佳掺杂浓度。结果发现，Ho

、Tm

掺杂浓度均为1.0%时，2.0 μm处Ho

：

→

发射峰强度达到最大，并对Ho

和Tm

之间的能量转移机制进行了详细分析和讨论。研究表明，Tm

/Ho

共掺的BaF

纳米晶SiO

-KF-BaF

玻璃陶瓷有望成为2.0 μm波段中红外固体激光器的增益基质。

Abstract

2.0 μm band mid-infrared lasers have attracted more and more attention due to their applications in human eye safety

photoelectric detection

and generation of mid-infrared supercontinuum. In this paper

ion doped and Ho

/Tm

co-doped 85SiO

-7.5KF-7.5BaF

(SKB) glass containing BaF

nanocrystalline were prepared by melt-quenching method. The Raman spectrum

absorption spectrum and mid-infrared fluorescence performances of the samples at 2.0 μm exited by 808 nm laser diode were studied. The optimal doping concentration of Ho

/Tm

was obtained during the experiment. The measured fluorescence spectra manifest that the maximal emission intensity of Ho

→

at 2.0 μm can be achieved at the concentration of 1.0% Ho

and 1.0% Tm

in this component glass. Besides

the energy transfer mechanisms between Ho

and Tm

were also analyzed and discussed in detail. The results show that Tm

/Ho

co-doped SiO

-KF-BaF

glass ceramics can be used as the gain matrix for 2.0 μm band mid-infrared solid-state laser.

关键词

硅酸盐玻璃稀土离子掺杂2.0 μm发光BaF2中红外发光

Keywords

silicate glassrare earth ion doped2.0 μm fluorescenceBaF2mid-infrared emission

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