1.宁波大学高等技术研究院 红外材料及器件实验室, 浙江 宁波 315211
2.宁波海洋研究院, 浙江 宁波 315211
[ "傅燕青(1996-), 男, 浙江绍兴人, 硕士研究生, 2019年于宁波大学科学技术学院获得学士学位, 主要从事稀土离子掺杂玻璃发光及能量传递方面的研究。E-mail:fyq574934655@163.com" ]
[ "康世亮(1990-), 男, 河北张家口人, 博士, 2020年于华南理工大学获得博士学位, 主要从事光功能玻璃和光纤器件的研究。E-mail:ksl0118@126.com" ]
[ "林常规(1984-), 男, 浙江温州人, 博士, 研究员, 2010年于武汉理工大学获得博士学位, 主要从事特种玻璃材料光功能开发及其器件化(包括玻璃晶化机理、光功能玻璃陶瓷材料、红外玻璃材料、基于硫系玻璃的红外光学系统等)的研究。E-mail:linchanggui@nbu.edu.cn" ]
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傅燕青, 康世亮, 关尚升, 等. Tm3+/Ho3+共掺含BaF2纳米晶氟硅酸盐玻璃陶瓷2 μm发光性能[J]. 发光学报, 2021,42(1):37-43.
Yan-qing FU, Shi-liang KANG, Shang-sheng GUAN, et al. Luminescence Properties of Tm3+/Ho3+ Doped BaF2 Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm[J]. Chinese Journal of Luminescence, 2021,42(1):37-43.
傅燕青, 康世亮, 关尚升, 等. Tm3+/Ho3+共掺含BaF2纳米晶氟硅酸盐玻璃陶瓷2 μm发光性能[J]. 发光学报, 2021,42(1):37-43. DOI: 10.37188/CJL.20200310.
Yan-qing FU, Shi-liang KANG, Shang-sheng GUAN, et al. Luminescence Properties of Tm3+/Ho3+ Doped BaF2 Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm[J]. Chinese Journal of Luminescence, 2021,42(1):37-43. DOI: 10.37188/CJL.20200310.
由于在人眼安全、光电探测、中红外超连续谱产生等方面的应用,2.0 μm波段中红外激光器引起了人们越来越广泛的关注。本文采用熔融-淬冷法制备了含BaF,2,纳米晶、Tm,3+,离子单掺及Ho,3+,/Tm,3+,共掺的85SiO,2,-7.5KF-7.5BaF,2,(SKB)玻璃陶瓷,表征了样品的拉曼光谱、吸收光谱、808 nm泵浦下在2.0 μm处的发光性能,得到了实验过程中Ho,3+,/Tm,3+,的最佳掺杂浓度。结果发现,Ho,2,O,3,、Tm,2,O,3,掺杂浓度均为1.0%时,2.0 μm处Ho,3+,:,5,I,7,→,5,I,8,发射峰强度达到最大,并对Ho,3+,和Tm,3+,之间的能量转移机制进行了详细分析和讨论。研究表明,Tm,3+,/Ho,3+,共掺的BaF,2,纳米晶SiO,2,-KF-BaF,2,玻璃陶瓷有望成为2.0 μm波段中红外固体激光器的增益基质。
2.0 μm band mid-infrared lasers have attracted more and more attention due to their applications in human eye safety, photoelectric detection, and generation of mid-infrared supercontinuum. In this paper, Tm,3+, ion doped and Ho,3+,/Tm,3+, co-doped 85SiO,2,-7.5KF-7.5BaF,2,(SKB) glass containing BaF,2, nanocrystalline were prepared by melt-quenching method. The Raman spectrum, absorption spectrum and mid-infrared fluorescence performances of the samples at 2.0 μm exited by 808 nm laser diode were studied. The optimal doping concentration of Ho,3+,/Tm,3+, was obtained during the experiment. The measured fluorescence spectra manifest that the maximal emission intensity of Ho,3+,:,5,I,7,→,5,I,8, at 2.0 μm can be achieved at the concentration of 1.0% Ho,2,O,3, and 1.0% Tm,2,O,3, in this component glass. Besides, the energy transfer mechanisms between Ho,3+, and Tm,3+, were also analyzed and discussed in detail. The results show that Tm,3+,/Ho,3+, co-doped SiO,2,-KF-BaF,2, glass ceramics can be used as the gain matrix for 2.0 μm band mid-infrared solid-state laser.
硅酸盐玻璃稀土离子掺杂2.0 μm发光BaF2中红外发光
silicate glassrare earth ion doped2.0 μm fluorescenceBaF2mid-infrared emission
SOBON' G, MARTYNKIEN T, TARNOWSKI K, et al.. Generation of sub-100 fs pulses tunable from 1700 to 2100 nm from a compact frequency-shifted Er-fiber laser[J].Photonics Res., 2017, 5(3):151-155.
CHEN Y P, ZHAI J P, XU X T, et al.. Mode-lockedthulium-doped fiber laser based on 0.3 nm diameter single-walled carbon nanotubes at 1.95μm[J].Chin. Opt. Lett., 2017, 15(4):041403-1-4.
DING B L, ZHOU X, ZHANG J L, et al.. Ho3+ doped Na5Y9F32 single crystals doubly sensitized by Er3+ and Yb3+ for efficient 2.0μm emission[J].J. Lumin., 2020, 223:117254-1-9.
PAN J J, XU R R, TIAN Y, et al.. 2.0μm emission properties of transparent oxyfluoride glass ceramics doped with Yb3+-Ho3+ ions[J].Opt. Mater., 2010, 32(11):1451-1455.
PERCIVAL R M, SZEBESTA D, DAVEY S T, et al.. Thulium sensitised holmium-doped CW fluoride fibre laser of high efficiency[J].Electron. Lett., 1992, 28(24):2231-2232.
MA Y Y, HUANG F F, HU L L, et al.. Efficient 2.05μm emission of Ho3+/Yb3+/Er3+ triply doped fluorotellurite glasses[J].Spectrochim. Acta A Mol. Biomol. Spectrosc., 2014, 122:711-714.
邓声玉, 厉宇翔, 范亚蕾, 等. Ho3+和Tm3+共掺铋硅酸盐玻璃发光性能的研究[J].中国稀土学报, 2017, 35(3):329-336.
DENG S Y, LI Y X, FAN Y L, et al.. Investigation of luminescence properties in Ho3+-Tm3+co-doped bismuth-silicate glasses[J].J. Chin. Soc. Rare Earths., 2017, 35(3):329-336. (in Chinese)
ZHANG C M, FU W B, LI Z W, et al.. Improving 2.0μm fluorescence properties of Er3+/Ho3+ co-doped oxyfluoride silicate glass-ceramics containing YF3 nanocrystals by introducing Li+ ions for mid-infrared lasers[J].J. Lumin., 2020, 227: 117568-1-8.
WANG Y H, OHWAKI J. New transparent vitroceramics codoped with Er3+ and Yb3+ for efficient frequency upconversion[J].Appl. Phys. Lett., 1993, 63(24):3268-3270.
CHEN D Q, WANG Y S, BAO F, et al.. Broadband near-infrared emission from Tm3+/Er3+ co-doped nanostructured glass ceramics[J].J. Appl. Phys., 2007, 101(11):113511-1-5.
LI C X, XU S Q, YE R G, et al.. Upconversion luminescence of BaF2: Yb3+/Tm3+ nanocrystals[C]. 2009Conference on Lasers & Electro Optics & The Pacific Rim Conference on Lasers and Electro-optics, Shanghai, China, 2009.
HU Y B, QIU J B, ZHOU D C, et al.. Spectroscopic properties and mechanism of Tm3+/Er3+/Yb3+ co-doped oxyfluorogermanate glass ceramics containing BaF2 nanocrystals[J].Chin. Phys. B, 2014, 23(3):024205-1-6.
HUANG L H, JIA S J, LI Y, et al.. Enhanced emissions in Tb3+-doped oxyfluoride scintillating glass ceramics containing BaF2 nanocrystals[J].Nucl. Instrum. Methods Phys. Res. Sect. A, 2015, 788:111-115.
ZHAO Z Y, AI B, LIU C, et al.. Er3+ ions-doped germano-gallate oxyfluoride glass-ceramics containing BaF2 nanocrystals[J].J. Am. Ceram. Soc., 2015, 98(7):2117-2121.
ZHANG W J, ZHANG Q Y, CHEN Q J, et al.. Enhanced 2.0μm emission and gain coefficient of transparent glass ceramic containing BaF2:Ho3+, Tm3+ nanocrystals[J].Opt. Express, 2009, 17(23):20952-20958.
OHLBERG S M, STRICKLER D W. Determination of percent crystallinity of partly devitrified glass by X-ray diffraction[J].J. Am. Ceram. Soc., 1962, 45(4):170-171.
YADAV A K, SINGH P. A review of the structures of oxide glasses by Raman spectroscopy[J].RSC Adv., 2015, 5(83):67583-67609.
KAMINSKⅡ A A, RHEE H, EICHLER H J, et al.. Wide-band Raman Stokes and anti-Stokes comb lasing in a BaF2 single crystal under picosecond pumping[J].Laser Phys. Lett., 2008, 5(4):304-310.
KADLEC F, SIMON P, RAIMBOUX N. Vibrational spectra of superionic crystals (BaF2)1-x(LaF3)x[J].J. Phys. Chem. Solids, 1999, 60(7):861-866.
ZHANG W J, CHEN Q J, ZHANG Q Y, et al.. Enhanced 2.0μm emission in oxyfluoride glass-ceramics containing nanocrystals MF2(MF3):Ho3+, Tm3+(M=Ca, Ba, and La)[J].J. Non-Cryst. Solids, 2011, 357(11-13):2278-2281.
TIAN Y, ZHANG L Y, XU R R, et al.. 2μm emission properties in Tm3+/Ho3+ codoped fluorophosphate glasses[J].Appl. Phys. B, 2010, 101(4):861-867.
王震, 谢文青, 豆奥举, 等.掺铥钬离子碲锗酸盐玻璃2μm发光性能研究[J].中国激光, 2020, 47(10):1003004-1-7.
WANG Z, XIE W Q, DOU A J, et al.. 2μm fluorescence properties of Tm3+ and Ho3+ ions doped tellurite-germanate glass[J].Chin. J. Lasers, 2020, 47(10):1003004-1-7. (in Chinese)
ZOU X L, TORATANI H. Spectroscopic properties and energy transfers in Tm3+ singly-and Tm3+ Ho3+ doubly-doped glasses[J].J. Non-Cryst. Solids, 1996, 195(1-2):113-124.
CAO R J, CAI M Z, LU Y, et al.. Ho3+/Yb3+ codoped silicate glasses for 2μm emission performances[J].Appl. Opt., 2016, 55(8):2065-2070.
徐星辰, 周亚训, 戴世勋, 等. Tm3+/Ho3+共掺碲酸盐玻璃的中红外发光及能量传递机理[J].中国激光, 2012, 39(10):1006002-1-8.
XU X C, ZHOU Y X, DAI S X, et al.. Mid-infrared luminescence and energy transfer mechanism of Tm3+/Ho3+ co-doped tellurite glasses[J].Chin. J. Lasers, 2012, 39(10):1006002-1-8. (in Chinese)
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